Apically Linked Small Metallacarborane Clusters. Directed Synthesis and Structural Characterization of 7,7′-[Cp*Co2,3-Et2C2B4H 3]2 and [Cp*Co(2,3-Et2C2B4H3-7)] 2X Complexes (X = MeCH, HC=CH, C≡C)

Inorganic Chemistry

Volumn 36, Issue 17, 1997, Pages 3602-3608

  Curtis, Michael A ^a   Müller, Thomas ^b   Beez, Volker ^b   Pritzkow, Hans ^b   Siebert, Walter ^b   Grimes, Russell N ^a  

^a UNIVERSITY OF VIRGINIA   (United States)

^b UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000087399     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970221e     Document Type: Article

References (19)

1. (a) Organotransition-Metal Metallacarboranes. 48.
2. (b) For Part 47, see: Curtis, M. E.; Sabat, M; Grimes, R. N. Inorg. Chem. 1996, 35, 6703.
3. For a recent overview, see: Manners, I. Angew. Chem., Int. Ed. Engl. 1996, 35, 1602.
4. Siebert, W. In Current Topics in the Chemistry of Boron; Kabalka, G. W., Ed.; Royal Society of Chemistry: London, 1994; p 275.
5. Grimes, R. N. Chem. Rev. 1992, 92, 251.
6. (a) Stephan, M.; Müller, P.; Zenneck, U.; Pritzkow, H.; Siebert, W.; Grimes, R. N. Inorg. Chem. 1995, 34, 2058.
7. (b) Stephan, M.; Hauss, J.; Zenneck, U.; Siebert, W.; Grimes, R. N. Inorg. Chem. 1994, 33, 4211, and references therein.
8. Siebert, W. Pure Appl. Chem. 1988, 60, 1345.
9. Grimes, R. N. Appl. Organomet. Chem. 1996, 10, 209, and references therein.
10. Wang, X.; Sabat, M.; Grimes, R. N. Organometallics 1995, 14, 4668.
11. Davis, J. H., Jr.; Sinn, E.; Grimes, R. N. J. Am. Chem. Soc. 1989, 111, 4776.
12. The characteristic electron donor properties of these metallacarboranes and related polyhedral boron clusters underline the fact that they are not (as still sometimes erroneously labeled) "electron deficient".
13. See, for example: Mebel, A. M.; Musaev, D. G.; Koga, N.; Morokuma, K. Bull. Chem. Soc. Jpn. 1993, 66, 3259.
14. (a) Soundarajan, R.; Matteson, D. S. J. Org. Chem. 1990, 55, 2274.
15. (b) Siebert, W.; Hildenbrand, M.; Hornbach, P.; Karger, G.; Pritzkow, H. Z. Naturforsch. 1989, 44B, 1179.
16. Schulz, H.; Gabbert, G.; Pritzkow, H.; Siebert, W. Chem. Ber. 1993, 126, 1593.
17. Welch, C. N.; Shore, S. G. Inorg. Chem. 1968, 7, 225.
18. SHELXS-86: Sheldrick, G. M., University of Göttingen, Göttingen, Germany, 1986.
19. SHELXS-93: Sheldrick, G. M., University of Göttingen, Götingen, Germany, 1993.