"Recapitation" of nido-Metallacarboranes as a Synthetic Tool: Preparation of Apically Substituted CoC2B4 Clusters via Boron Insertion

Inorganic Chemistry

Volumn 35, Issue 23, 1996, Pages 6703-6707

  Curtis, Michael A ^a   Sabat, Michal ^a   Grimes, Russell N ^a  

^a UNIVERSITY OF VIRGINIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001289090     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960691t     Document Type: Article

References (40)

1. Organotransition-Metal Metallacarboranes. 47. Part 46: Franz, D. A.; Houser, E. J.; Sabat, M.; Grimes, R. N. Inorg. Chem., in press.
2. Representative recent reviews: (a) Harwell, D. E.; Nabakka, J.; Knobler, C. B.; Hawthorne, M. F. Can. J. Chem. 1995, 73, 1044 (Venus flytrap complexes). (b) Jelliss, P. A.; Stone, F. G. A. J. Organomet, Chem. 1995, 500, 307 (nonspectator carborane ligands in icosahedral complexes), (c) Saxena, A. K.; Hosmane, N. S. Chem. Rev. 1993, 93, 1081 (metallacarboranes of d- and f-block metals). For comprehensive reviews of transition-metal metallacarborane chemistry, see: (d) Grimes, R. N. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 9, pp 373-430 (literature 1982-1995, metallacarboranes). (e) Grimes, R. N. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press, Oxford, England, 1982; Vol. 1, Chapter 5.5, pp 459-542 (literature to 1982, including metallaboranes).
3. Representative recent reviews: (a) Harwell, D. E.; Nabakka, J.; Knobler, C. B.; Hawthorne, M. F. Can. J. Chem. 1995, 73, 1044 (Venus flytrap complexes). (b) Jelliss, P. A.; Stone, F. G. A. J. Organomet, Chem. 1995, 500, 307 (nonspectator carborane ligands in icosahedral complexes), (c) Saxena, A. K.; Hosmane, N. S. Chem. Rev. 1993, 93, 1081 (metallacarboranes of d- and f-block metals). For comprehensive reviews of transition-metal metallacarborane chemistry, see: (d) Grimes, R. N. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 9, pp 373-430 (literature 1982-1995, metallacarboranes). (e) Grimes, R. N. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press, Oxford, England, 1982; Vol. 1, Chapter 5.5, pp 459-542 (literature to 1982, including metallaboranes).
4. Representative recent reviews: (a) Harwell, D. E.; Nabakka, J.; Knobler, C. B.; Hawthorne, M. F. Can. J. Chem. 1995, 73, 1044 (Venus flytrap complexes). (b) Jelliss, P. A.; Stone, F. G. A. J. Organomet, Chem. 1995, 500, 307 (nonspectator carborane ligands in icosahedral complexes), (c) Saxena, A. K.; Hosmane, N. S. Chem. Rev. 1993, 93, 1081 (metallacarboranes of d- and f-block metals). For comprehensive reviews of transition-metal metallacarborane chemistry, see: (d) Grimes, R. N. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 9, pp 373-430 (literature 1982-1995, metallacarboranes). (e) Grimes, R. N. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press, Oxford, England, 1982; Vol. 1, Chapter 5.5, pp 459-542 (literature to 1982, including metallaboranes).
5. Representative recent reviews: (a) Harwell, D. E.; Nabakka, J.; Knobler, C. B.; Hawthorne, M. F. Can. J. Chem. 1995, 73, 1044 (Venus flytrap complexes). (b) Jelliss, P. A.; Stone, F. G. A. J. Organomet, Chem. 1995, 500, 307 (nonspectator carborane ligands in icosahedral complexes), (c) Saxena, A. K.; Hosmane, N. S. Chem. Rev. 1993, 93, 1081 (metallacarboranes of d- and f-block metals). For comprehensive reviews of transition-metal metallacarborane chemistry, see: (d) Grimes, R. N. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 9, pp 373-430 (literature 1982-1995, metallacarboranes). (e) Grimes, R. N. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press, Oxford, England, 1982; Vol. 1, Chapter 5.5, pp 459-542 (literature to 1982, including metallaboranes).
6. Representative recent reviews: (a) Harwell, D. E.; Nabakka, J.; Knobler, C. B.; Hawthorne, M. F. Can. J. Chem. 1995, 73, 1044 (Venus flytrap complexes). (b) Jelliss, P. A.; Stone, F. G. A. J. Organomet, Chem. 1995, 500, 307 (nonspectator carborane ligands in icosahedral complexes), (c) Saxena, A. K.; Hosmane, N. S. Chem. Rev. 1993, 93, 1081 (metallacarboranes of d- and f-block metals). For comprehensive reviews of transition-metal metallacarborane chemistry, see: (d) Grimes, R. N. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 9, pp 373-430 (literature 1982-1995, metallacarboranes). (e) Grimes, R. N. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press, Oxford, England, 1982; Vol. 1, Chapter 5.5, pp 459-542 (literature to 1982, including metallaboranes).
7. (a) Hosmane, N. S.; Maguire, J. A. J. Cluster Sci. 1993, 4, 297.
8. (b) Grimes, R. N. Chem. Rev. 1992, 92, 251.
9. (c) Grimes, R. N. Appl. Organomet. Chem. 1996, 10, 209.
10. (a) Davis, J. H., Jr.; Attwood, M. D.; Grimes, R. N. Organometallics 1990, 9, 1171.
11. (b) Piepgrass, K. W.; Grimes, R. N. Organometallics 1992. 11, 2397.
12. (c) Piepgrass, K. W.; Stockman, K. E.; Sabat, M.; Grimes, R. N. Organometallics 1992, 11, 2404.
13. (a) Benvenuto, M. A.; Grimes, R. N. Inorg. Chem. 1992, 31, 3897.
14. (b) Benvenuto, M. A.; Sabat, M.; Grimes, R. N. Inorg. Chem. 1992, 37, 3904.
15. (a) Houseknecht, K. L.; Stockman, K. E.; Sabat, M.; Finn, M. G.; Grimes, R. N. J. Am. Chem. Soc. 1995, 117, 1163.
16. (b) Stockman, K. E.; Houseknecht, K. L.; Boring, E. A.; Sabat, M.; Finn, M. G.; Grimes, R. N. Organometallics 1995, 14, 3014.
17. Wang, X.; Sabat, M.; Grimes, R. N. Organometallics 1995, 14, 4668.
18. Stockman, K. E., Garrett, D. L.; Grimes, R. N. Organometallics 1995, 14, 4661.
19. Hawthorne, M. F.; Wegner, P. A. J. Am. Chem. Soc. 1968, 90, 896.
20. Mair, F. S.; Morris, J. H.; Gaines, D. F.; Powell, D. J. Chem. Soc., Dalton Trans. 1993, 135.
21. Beck, J. S.; Sneddon, L. G. Inorg. Chem. 1990, 29, 295.
22. Reviews: (a) Fehlner, T. P. New J. Chem. 1988, 12, 307. (b) Barton, L.; Srivastava, D. K. In Comprehensive Organometallic Chemistry II, Abel. E., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 8, pp 275-372. Some leading references: (c) Grebenik, P. D.; Leach, J. B.; Green, M. L. H.; Walker, N. M. J. Organomet. Chem. 1988, 345, C31. (d) Feilong, J.; Fehlner, T. P.; Rheingold, A. L. Angew. Chem., Int. Ed. Engl. 1988, 27, 424. (e) Grebenik, P. D.; Green, M. L. H.; Kelland, M. A.; Leach, J. B.; Mountford, P.; Stringer, G.; Walker, N. M.; Wong, L. L. J. Chem. Soc., Chem. Commun. 1988, 799. (f) Hong, F.-E.; McCarthy, D. A.; White, J. P., III; Cottrell, C. E.; Shore, S. G. Inorg. Chem. 1990, 29, 2874.
23. Reviews: (a) Fehlner, T. P. New J. Chem. 1988, 12, 307. (b) Barton, L.; Srivastava, D. K. In Comprehensive Organometallic Chemistry II, Abel. E., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 8, pp 275-372. Some leading references: (c) Grebenik, P. D.; Leach, J. B.; Green, M. L. H.; Walker, N. M. J. Organomet. Chem. 1988, 345, C31. (d) Feilong, J.; Fehlner, T. P.; Rheingold, A. L. Angew. Chem., Int. Ed. Engl. 1988, 27, 424. (e) Grebenik, P. D.; Green, M. L. H.; Kelland, M. A.; Leach, J. B.; Mountford, P.; Stringer, G.; Walker, N. M.; Wong, L. L. J. Chem. Soc., Chem. Commun. 1988, 799. (f) Hong, F.-E.; McCarthy, D. A.; White, J. P., III; Cottrell, C. E.; Shore, S. G. Inorg. Chem. 1990, 29, 2874.
24. Reviews: (a) Fehlner, T. P. New J. Chem. 1988, 12, 307. (b) Barton, L.; Srivastava, D. K. In Comprehensive Organometallic Chemistry II, Abel. E., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 8, pp 275-372. Some leading references: (c) Grebenik, P. D.; Leach, J. B.; Green, M. L. H.; Walker, N. M. J. Organomet. Chem. 1988, 345, C31. (d) Feilong, J.; Fehlner, T. P.; Rheingold, A. L. Angew. Chem., Int. Ed. Engl. 1988, 27, 424. (e) Grebenik, P. D.; Green, M. L. H.; Kelland, M. A.; Leach, J. B.; Mountford, P.; Stringer, G.; Walker, N. M.; Wong, L. L. J. Chem. Soc., Chem. Commun. 1988, 799. (f) Hong, F.-E.; McCarthy, D. A.; White, J. P., III; Cottrell, C. E.; Shore, S. G. Inorg. Chem. 1990, 29, 2874.
25. Reviews: (a) Fehlner, T. P. New J. Chem. 1988, 12, 307. (b) Barton, L.; Srivastava, D. K. In Comprehensive Organometallic Chemistry II, Abel. E., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 8, pp 275-372. Some leading references: (c) Grebenik, P. D.; Leach, J. B.; Green, M. L. H.; Walker, N. M. J. Organomet. Chem. 1988, 345, C31. (d) Feilong, J.; Fehlner, T. P.; Rheingold, A. L. Angew. Chem., Int. Ed. Engl. 1988, 27, 424. (e) Grebenik, P. D.; Green, M. L. H.; Kelland, M. A.; Leach, J. B.; Mountford, P.; Stringer, G.; Walker, N. M.; Wong, L. L. J. Chem. Soc., Chem. Commun. 1988, 799. (f) Hong, F.-E.; McCarthy, D. A.; White, J. P., III; Cottrell, C. E.; Shore, S. G. Inorg. Chem. 1990, 29, 2874.
26. Reviews: (a) Fehlner, T. P. New J. Chem. 1988, 12, 307. (b) Barton, L.; Srivastava, D. K. In Comprehensive Organometallic Chemistry II, Abel. E., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 8, pp 275-372. Some leading references: (c) Grebenik, P. D.; Leach, J. B.; Green, M. L. H.; Walker, N. M. J. Organomet. Chem. 1988, 345, C31. (d) Feilong, J.; Fehlner, T. P.; Rheingold, A. L. Angew. Chem., Int. Ed. Engl. 1988, 27, 424. (e) Grebenik, P. D.; Green, M. L. H.; Kelland, M. A.; Leach, J. B.; Mountford, P.; Stringer, G.; Walker, N. M.; Wong, L. L. J. Chem. Soc., Chem. Commun. 1988, 799. (f) Hong, F.-E.; McCarthy, D. A.; White, J. P., III; Cottrell, C. E.; Shore, S. G. Inorg. Chem. 1990, 29, 2874.
27. Reviews: (a) Fehlner, T. P. New J. Chem. 1988, 12, 307. (b) Barton, L.; Srivastava, D. K. In Comprehensive Organometallic Chemistry II, Abel. E., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon Press: Oxford, England, 1995; Vol. 1, Chapter 8, pp 275-372. Some leading references: (c) Grebenik, P. D.; Leach, J. B.; Green, M. L. H.; Walker, N. M. J. Organomet. Chem. 1988, 345, C31. (d) Feilong, J.; Fehlner, T. P.; Rheingold, A. L. Angew. Chem., Int. Ed. Engl. 1988, 27, 424. (e) Grebenik, P. D.; Green, M. L. H.; Kelland, M. A.; Leach, J. B.; Mountford, P.; Stringer, G.; Walker, N. M.; Wong, L. L. J. Chem. Soc., Chem. Commun. 1988, 799. (f) Hong, F.-E.; McCarthy, D. A.; White, J. P., III; Cottrell, C. E.; Shore, S. G. Inorg. Chem. 1990, 29, 2874.
28. Francis, J. N.; Hawthorne, M. F. Inorg. Chem. 1971, 10, 863.
29. Davis, J. H., Jr.; Sinn, E.; Grimes, R. N. J. Am. Chem. Soc. 1989, 111, 4776.
30. Hermanek, S. Chem. Rev. 1992, 92, 325.
31. (a) Huttner, G.; Gartzke, W. Chem. Ber. 1974, 107, 3786.
32. (b) Herberich, G. E.; Raabe, E. J. Organomet. Chem. 1986, 309, 143.
33. Bould, J.; Crook, J. E.; Greenwood, N. N.; Kennedy, J. D. J. Chem. Soc., Dalton Trans. 1991, 185.
34. Meng, X.; Waterworth, S.; Sabat, M.; Grimes, R. N. Inorg. Chem. 1993, 32, 3188.
35. Haubold, W.; Herdtle, J.; Gollinger, W.; Einholz, W. J. Organomet. Chem. 1986, 315, 1.
36. TEXSAN 5.0: Single Crystal Structure Analysis Software (1989), Molecular Structure Corp., The Woodlands, TX 77381.
37. teXsan 1.7: Single Crystal Structure Analysis Software (1995). Molecular Structure Corp., The Woodlands, TX 77381.
38. Walker, N.; Stuart, D. Acta Crystallogr. 1983, A39, 158.
39. SIR88: Burla, M. C.; Camalli, M.; Cascarano, G.; Giacovazzo, C.; Polidori, G.; Spagna, R.; Viterbo, D. J. Appl. Crystallogr. 1989, 22, 389.
40. 2, and CC: Curtis, M. A.; Pritzkow, H.; Siebert, W.; Grimes, R. N. To be published.