Synthesis, structures, and reactivities of rhodium and ruthenium complexes with a novel chiral cyclopentadienyl-ferrocenyldiphenylphosphine bidentate ligand

Organometallics

Volumn 16, Issue 14, 1997, Pages 3091-3093

  Nishibayashi, Yoshiaki ^a   Takei, Izuru ^a   Hidai, Masanobu ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000042251     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9702385     Document Type: Article

References (47)

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35. w = 0.023 for 4109 unique reflections (I > 3σ(I)).
36. 2Ru·2EtOH: C, 64.34; H, 5.61. Found: C, 64.10; H, 5.28.
37. w = 0.084 for 3960 unique reflections (I > 3σ(I)).
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40. 3Ru: C, 61.58; H, 4.51. Found: C, 61.19; H, 4.89.
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46. The low yield of 7 for both the stoichiometric and catalytic reactions was due to the formation of unidentified side products.
47. The preliminary results of a few catalytic reactions using 5 are as follows: 1-octyne and 1-buten-3-ol (20%, 34% ee), 1-octyne and 4-methyl-1-penten-3-ol (10%, 27% ee). The results will be reported in due course.