Organometallic Molybdenum(V) Complexes with Primary Phosphane Ligands - Syntheses, Spectroscopic Properties, and Crystal Structures of [Cp′MoCl4(PH2R)] (R = 2,4,6-Pr3iC6H2, Cyclohexyl, Cp′ = C5H4Me)

Chemische Berichte

Volumn 130, Issue 6, 1997, Pages 807-812

  Felsberg, Reinhard ^a   Blaurock, Steffen ^a   Jelonek, Svea ^a   Gelbrich, Thomas ^a   Kirmse, Reinhard ^a   Voigt, Andreas ^a   Hey Hawkins, Evamarie ^a  

^a UNIVERSITY OF LEIPZIG   (Germany)

Author keywords

EPR spectroscopy; Methylcyclopentadienyl molybdenum(V) tetrachloride; Molybdenum; Primary phosphane ligands

Indexed keywords

EID: 0000039868     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19971300621     Document Type: Article

References (45)

1. Comprehensive Organometallic Chemistry II, Eds. E. W. Abel, F. G. A. Stone, G. Wilkinson, Volumes 4 and 5, Pergamon Press 1995.
2. [2a] E. Hey-Hawkins, Chem. Rev. 1994, 94, 1661;
3. [2bl J. Ho, R. Rousseau, D. W. Stephan, Organometallics 1994, 13, 1918; (and references therein).
4. [3a] G. A. A. Haldi, K. Fromm, S. Blaurock, S. Jelonek, E. Hey-Hawkins, Polyhedron 1997, 16, 721;
5. [3b] G. A. A. Hadi, E. Hey-Hawkins, et al. (in preparation).
6. K. Fromm, E. Hey-Hawkins, Z. Anorg. Allg. Chem. 1993, 619, 261.
7. E. Hey-Hawkins, K. Fromm, Polyhedron 1995, 14, 2825.
8. 2: H. Ranaivonjatovo, J. Escudié, C. Couret, J. Satgé, J. Organomet. Chein. 1991, 415, 327; Y. van den Winkel, H. M. M. Bastiaans, F. Bickelhaupt, J. Organomet. Chem. 1991, 405, 183; P. Kölle, G. Linti, H. Nöth, G. L. Wood, C. K. Narula, R. T. Paine, Chem. Ber. 1988, 121, 871;H. Schindlbauer, E. Steininger, Monatsh. Chem. 1961, 92, 868; F. Pan, E. Steininger, E. Zorn, Monatsh. Chem. 1962, 93, 230.
9. [6b] R = Cy: G. Becker, O. Mundt, M. Rössler, E. Schneider, Z. anorg. allg. Chem. 1978, 443, 41; H. Schindlbauer, E. Steininger, Monatsh. Chem. 1961, 92, 868; F. Pan, E. Steininger, E. Zorn, Monatsh. Chem. 1962, 93, 230.
10. [7a] M. Scheer, T. T. Nam, K. Schenzel, E. Herrmann, P. G. Jones, V. P. Fedin, V. N. Ikorski, V. E. Fedorov, Z. anorg. allg. Chem. 1990, 591, 221;
11. [7b] K. Fromm, E. Hey-Hawkins, Z. anorg. allg. Chem. 1993, 619, 261.
12. K. Köhler, H. W. Roesky, A. Herzog, H. Gornitzka, A. Steiner, I. Usón, Inorg. Chem. 1996, 35, 1773.
13. E. A. Allen, B. J. Brisdon, G. W. A. Fowles, J. Chem. Soc. 1964, 4531.
14. J. R. Dilworth, R. L. Richards, Inorg. Syn. 1980, 20, 121.
15. Comprehensive Inorganic Chemistry, 1. Aufl., Vol. 3, Pergamon Press, 1973, p. 721 ff.
16. E. Hey- Hawkins, H. G. von Schnering, Z. Naturforsch. 1991, 46B, 307.
17. B. E. Owens, R. Poli, Inorg. Chim. Acta 1991, 179, 229.
18. K. Stärker, M. D. Curtis, Inorg. Chem. 1985, 24, 3006.
19. R. Poli, M. A. Kelland, J. Organomet. Chem. 1991, 419, 127.
20. F. Abugideiri, J. C. Gordon, R. Poli, B. E. Owens-Waltermire, A. L. Rheingold, Organoinetallics 1993, 12, 1575.
21. S. T. Krueger, B. E. Owens, R. Poli, Inorg. Chem. 1990, 29, 2001.
22. M. L. H. Green, A. Izguierdo, J. J. Martin-Polo, V. S. B. Mtetwa, K. Prout, J. Chem. Soc., Chem. Commun. 1983, 538.
23. J. C. Fettinger, D. W. Keogh, R. Poli, J. Am. Chem. Soc. 1996, 118, 3617.
24. M. W. Anker, J. Chatt, G. J. Leigh, A. G. Wedd, J. Chem. Soc. Dalton Trans. 1975, 2639.
25. P. M. Treichel, W. K. Dean, W. M. Douglas, J. Organomet. Chem. 1972, 42, 145.
26. A. J. Deeming, S. Doherty, Polyhedron 1996, 15, 1175 (and references therein).
27. G. Johannsen, O. Stelzer, Chem. Ber. 1977, 110, 3438.
28. F. A. Cotton, L. M. Daniels, G. L. Powell, A. J. Kahaian, T. J. Smith, E. F. Vogel, Inorg. Chim. Acta 1988, 144, 109.
29. B. E. Bursten, W. F. Schneider, Inorg. Chem. 1989, 28, 3292.
30. J. Weidlein, U. Müller, K. Dehnicke, Schwingungsspektroskopie, G. Thieme Verlag, 2. Aufl., Stuttgart, 1988.
31. E. Hey-Hawkins, S. Kurz, G. Baum, Z. Naturforsch. 1995, 50B, 239.
32. E. Hey-Hawkins, S. Kurz, Phosphorus, Sulfur 1994, 90, 281.
33. E. C. Alyea, G. Ferguson, S. Kannan, Ada Cryst. 1996, 52C, 765 (and references therein).
34. G. Hogarth, T. Norman, J. Chem. Soc. Dalton Trans. 1996, 1077.
35. F. A. Cotton, L. M. Daniels, S. C. Haefner, E. N. Walke, Inorg. Cliim. Ada 1996, 247, 105 (and references therein).
36. R. C. Murray, L. Blum, A. H. Liu, R. R. Schrock, Organometallics 1985, 4, 953.
37. A. Abraeam, M. H. L. Pryce, Proc. Roy. Soc. London, 1951, 205 A, 135.
38. R. Kirmse, J. Stach, ESR-Spektroskopie-Anwendungen in der Chemie, Akademie-Verlag Berlin 1985, p. 86-95.
39. J. R. Morton, K. F. Preston, J. Magn. Reson. 1978, 30, 577.
40. C. P. Keijzers, E. de Boer, J. Chem. Phys. 1972, 57, 1277.
41. C. P. Keijzers, E. de Boer, Molec. Pliys. 1975, 29, 1007.
42. L. K. White, R. L. Beiford, J. Am. Cliem. Soc. 1976, 98, 4428; A modified version by K. Köhler and R. Böttcher (University Leipzig, 1991) was used for the simulation.
43. Further details of the structure determination may be obtained upon request from the Fachinformationszentrurn Karlsruhe, D-76344 Egeenstein-Leopoldshafen, Germany, giving reference to the depository numbers CSD 406296 (for 1) and CSD 406350 (for 2), and citing the authors and this paper.
44. R. H. Blessing, Acta Cryst. 1995, 51A, 33.
45. SHELXTL PLUS, Siemens Analyt. X-ray Inst. Inc., 1990, XS: Program for Crystal Structure Solution, XL: Program for Crystal Structure Determination, XP: Interactiv Molecular Graphics.