Unusual 1,1-2,2-isomers of Mo2Cl4(PR3)2(R′CN) 2. Compounds with R = CH2CH2CN and R′ = CH3, CH3CH2 and CH(CH3)2

Inorganica Chimica Acta

Volumn 247, Issue 1, 1996, Pages 105-112

  Cotton, F Albert ^a   Daniels, Lee M ^a   Haefner, Steven C ^a   Walke, Erik N ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

Crystal structures; Cyanoethyl phosphine complexes; Metal metal bond complexes; Molybdenum complexes; Nitrile complexes

Indexed keywords

BINARY ALLOYS; CHEMICAL BONDS; CHLORINE COMPOUNDS; COMPLEXATION; CRYSTAL ATOMIC STRUCTURE; CRYSTAL STRUCTURE; CRYSTALS; CYANIDES; LIGANDS; MOLECULAR STRUCTURE; NANOCRYSTALLINE MATERIALS; PHOSPHORUS COMPOUNDS; SYNTHESIS (CHEMICAL);

CRYSTAL AND MOLECULAR STRUCTURE; CRYSTALLINE COMPLEXES; DIPOLE DIPOLE INTERACTIONS; METAL-METAL BONDS; MOLYBDENUM COMPLEX; NITRILE COMPLEXES; PHOSPHINE COMPLEX; VISIBLE SPECTROSCOPY;

MOLYBDENUM COMPOUNDS;

EID: 0008052854     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/0020-1693(95)04950-9     Document Type: Article

References (29)

1. F.A. Cotton and R. A. Walton, Multiple Bonds Between Metal Atoms, Oxford University Press, 2nd edn., 1993,
2. (a) pp. 181-183;
3. (b) p. 188;
4. (c) p. 143, and Refs. therein.
5. R.N. McGinnis, T.R. Ryan and R.E. McCarley, J. Am. Chem. Soc., 100 (1978) 7900.
6. C.A. Streuli, Anal. Chem., 32 (1960) 985.
7. F.A. Cotton, D.J. Darensbourg and W.H. Ilsley, Inorg. Chem., 20 (1981) 578.
8. A.B. Brignole and F.A. Cotton, Inorg. Synth., 13 (1972) 81.
9. J.V. Brencic and F.A. Cotton, Inorg. Chem., 9 (1970) 346.
10. J. San Filippo, Jr., Inorg. Chem., 11 (1972) 3140.
11. (a) A. Bino, F.A. Cotton and P.E. Fanwick, Inorg. Chem., 18 (1979) 3558;
12. (b) F.A. Cotton, B.A. Frenz, G. Deganello and A.J. Shaver, J. Organomet. Chem., 50 (1973) 227;
13. (c) A.C.T. North, D.C. Phillips and F.S. Mathews, Acta Crystallogr., Sect. A, 24 (1968) 351.
14. G.M. Sheldrick, Cristallographic Computing 3, Oxford University Press, 1985, p. 175.
15. G.M. Sheldrick, SHELXL-93, Institut für Anorganische Chemie, Tammannstrasse 4, D-37077 Göttingen, Germany.
16. F.A. Cotton, D.J. Darensbourg, M.F. Fredrich, W.H. Ilsley and J.M. Troup, Inorg. Chem., 20 (1981) 1869.
17. M.M. Rauhut, I. Hechenbleikner, H.A. Currier, F.C. Schaefer and V.P. Wystrach, J. Am. Chem. Soc., 81 (1959) 1103.
18. M.G.B. Drew, D.F. Lewis and R.A. Walton, Chem. Commun., (1969) 326; K. Chengand B.M. Foxman, J. Am. Chem. Soc., 99 (1977) 8102.
19. M.G.B. Drew, D.F. Lewis and R.A. Walton, Chem. Commun., (1969) 326; K. Chengand B.M. Foxman, J. Am. Chem. Soc., 99 (1977) 8102.
20. (a) N.A. Bell, L.A. March and I.W. Nowell, Inorg. Chim. Acta, 156 (1989) 195, and Refs. therein;
21. (b) M.N.I. Khan,C. King, J.P. Fackler, Jr. and R.E. Winpenny, Inorg. Chem., 32 (1993) 2502.
22. J. San Filippo, H.J. Sniadoch and R.L. Grayson, Inorg. Chem., 13 (1974) 2121.
23. J.R. Winkler, D.G. Nocera and T.J. Netzel, J. Am. Chem. Soc., 108 (1986) 4451.
24. F.A. Cotton and K.J. Wiesinger, Inorg. Chem., 30 (1991) 871.
25. F.A. Cotton, M.W. Extine, T.R. Felthouse, B.W.S. Kolthammer and D.G. Lay, J. Am. Chem. Soc., 103 (1981) 4040.
26. F.A. Cotton, L.M. Daniels, G.L. Powell, A.J. Kahaian, T.J. Smith and E.F. Vogel, Inorg. Chim. Acta, 144 (1988) 109.
27. T.R. Ryan, Ph.D. Dissertation, Iowa State University, Ames, IA, 1981, p. 18.
28. C.A. Tolman, Chem. Rev., 77 (1977) 313.
29. C.-W. Liu and J.P. Fackler, J. Chem. Soc., Dalton Trans., in press.