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14
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0041496919
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Shorter reaction times led to higher 16:biphenyl ratios, demonstrating that the presence of biphenyl was due to a palladium-mediated decarbonylation of 16. Further, heating 16 with a catalytic amount of palladium acetate led to catalytic decarbonylation giving biphenyl.
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Shorter reaction times led to higher 16:biphenyl ratios, demonstrating that the presence of biphenyl was due to a palladium-mediated decarbonylation of 16. Further, heating 16 with a catalytic amount of palladium acetate led to catalytic decarbonylation giving biphenyl.
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15
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0041496918
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This step is usually, misleadingly described as 'trans-metallation'.
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This step is usually, misleadingly described as 'trans-metallation'.
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16
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0041997888
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Removal of all the water from the silica without destruction of the supported complex is not possible. In addition, substantial quantities of water are introduced during washing after each catalytic run.
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Removal of all the water from the silica without destruction of the supported complex is not possible. In addition, substantial quantities of water are introduced during washing after each catalytic run.
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18
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