Partial molar heat capacities and partial molar volumes of all of the isomeric (C3 to C5) alkanols at infinite dilution in water at 298.15 K

Journal of Chemical and Engineering Data

Volumn 49, Issue 6, 2004, Pages 1833-1838

  Fenclová, Dana ^a   Perez Casas, Silvia ^b   Costas, Miguel ^b   Dohnal, Vladimír ^a  

^a INSTITUTE OF CHEMICAL TECHNOLOGY   (Czech Republic)

^b UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

CALORIMETERS; HEAT TRANSFER; HYDRATION; HYDROCARBONS; ISOMERS; ORGANIC SOLVENTS; PURIFICATION; SPECIFIC HEAT; THERMODYNAMIC PROPERTIES; THERMOSTATS;

DENSIMETER; DIFFERENTIAL FLOW MICROCALORIMETER; MOLAR VOLUMES; PARTIAL MOLAR PROPERTIES;

ORGANIC COMPOUNDS;

EID: 9744261036     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je049738c     Document Type: Article

References (28)

1. Hovorka, Š.; Dohnal, V.; Roux, A. H.; Roux-Desgranges, G. Determination of Temperature Dependence of Limiting Activity Coefficients for a Group of Moderately Hydrophobic Organic Solutes in Water. Fluid Phase Equilib. 2002, 201, 135-164.
2. Vrbka, P.; Hovorka, Š.; Dohnal, V.; Arlt, W. Excess Thermo-dynamic Properties of Highly Dilute Solutions of 1-Alkanols (C1 C4) in Water. In Proceedings of the 15th International Conference on Chemical Thermodynamics, Porto, Portugal, July 26-August 1, 1998; pp C1-15.
3. Makhatadze, G. I; Privalov, P. L. Heat Capacity of Alcohols in Aqueous Solutions in the Temperature Range from 5 to 125 °C. J. Solution Chem. 1989, 18, 927-936.
4. Jolicoeur, C.; Lacroix, G. Thermodynamic Properties of Aqueous Organic Solutes in Relation to Their Structure. Part III. Apparent Molal Volumes and Heat Capacities of Low Molecular Weight Alcohols and Polyols at 25 C. Can. J. Chem. 1976, 54, 624-631.
5. Origlia, M. L.; Woolley, E. M. Apparent Molar Volumes and Apparent Molar Heat Capacities of Aqueous Solutions of Isomeric Butanols at Temperatures from 278.15 K to 393.15 K and at the Pressure 0.35 MPa. J. Chem. Thermodyn. 2001, 33, 451-469.
6. Origlia-Luster, M. L.; Woolley, E. M. Apparent Molar Volumes and Apparent Molar Heat Capacities of Dilute Aqueous Solutions of Ethanol, 1-Propanol, and 2-Propanol at Temperatures from 278.15 K to 393.15 K and at the Pressure 0.35 MPa. J. Chem. Thermodyn. 2003, 35, 1101-1118.
7. Cabani, S.; Gianni, P.; Mollica, V.; Lepori, L. Group Contribution to the Thermodynamic Properties of Non-Ionic Organic Solutes in Dilute Aqueous Solution. J. Solution Chem. 1981, 10, 563595.
8. Plyasunov, A. V.; Shock, E. L. Thermodynamic Functions of Hydration of Hydrocarbons at 298.15 K and 0.1 MPa. Geochim. Cosmochim. Acta 2000, 64, 439-468.
9. Fortier, J.-L.; Benson, G. C. Excess Heat Capacities of Binary Liquid Mixtures Determined with a Picker Flow Microcalorimeter. J. Chem. Thermodyn. 1976, 8, 411-423.
10. Picker, P.; Leduc, P. A.; Philip, P. R.; Desnoyers, J. E. Heat Capacity of Solutions by Flow Microcalorimetry. J. Chem. Thermodyn. 1971, 3, 631-642.
11. Zábranský, M.; Růžička, V.; Majer, V.; Domalski, E. S. Heat Capacity of Liquids: Volume I: Critical Review and Recommended Values. J. Phys. Chem. Ref. Data, Monogr. 1996, 6, 1-810.
12. Zábranský, M.; Růžička, V.; Domalski, E. S. Heat Capacity of Liquids: Critical Review and Recommended Values. Supplement I. J. Phys. Chem. Ref. Data 2001, 30, 1199-1689.
13. Hales, J. L.; Ellender, J. H. Liquid Densities from 293 to 490 K of Nine Aliphatic Alcohols. J. Chem. Thermodyn. 1976, 8, 11771184.
14. CDATA: Database of Thermodynamic and Transport Properties for Chemistry and Engineering; Department of Physical Chemistry, Institute of Chemical Technology; Distributed by FIZ Chemie GmbH, Berlin: Prague, 1991.
15. Riddick, J. A.; Bunger, W. B. Sakano, T. K. Organic Solvents; Wiley-Interscience: New York, 1986.
16. Domalski, E. S.; Hearing, E. D. Estimation of the Thermodynamic Properties of C-H-N-O-S-Halogen Compounds at 298.15 K. J. Phys. Chem. Ref. Data 1993, 22, 805-1159.
17. Sakurai, M.; Nakamura, K.; Nitta, K. Volumetric Properties of Dilute Aqueous Alcohol Solutions at Different Temperatures. Bull. Chem. Soc. Jpn. 1994, 67, 1580-1587.
18. Hoiland, H.; Vikingstad, E. Partial Molal Volumes and Additivity of Group Partial Molal Volumes of Alcohols in Aqueous Solution at 25 and 35 °C. Acta Chem. Scand., Ser. A 1976, 30, 182-186.
19. Alexander, D. M. Apparent Molar Volumes of Alcohols in Dilute Aqueous Solution. J. Chem. Eng. Data 1959, 4, 252-254.
20. Roux, G.; Roberts, D.; Perron, G.; Desnoyers, J. E. Microheterogeneity in Aqueous-Organic Solutions: Heat Capacities, Volumes and Expansibilities of Some Alcohols, Aminoalcohol and Tertiary Amines in Water. J. Solution Chem. 1980, 9, 629-647.
21. Hovorka, Š.; Roux, A. H.; Roux-Desgranges, G.; Dohnal, V. Limiting Partial Molar Excess Heat Capacities and Volumes of Selected Organic Compounds in Water at 25 °C. J. Solution Chem. 1999, 28, 1289-1305.
22. Franks, F.; Smith, H. T. Precision Densities of Dilute Aqueous Solutions of the Isomeric Butanols. J. Chem. Eng. Data 1968, 13, 538-541.
23. Cabani, S.; Conti, G.; Lepori, L. Volumetric Properties of Aqueous Solutions of Organic Compounds. III. Aliphatic Secondary Alcohols, Cyclic Alcohols, Primary, Secondary, and Tertiary Amines. J. Phys. Chem. 1974, 78, 1030-1034.
24. de Visser, C.; Perron, G.; Desnoyers, J. E. The Heat Capacities, Volumes, and Expansibilities of tert-Butyl Alcohol - Water Mixtures from 6 to 65 °C. Can. J. Chem. 1977, 55, 856-862.
25. Edward, J. T.; Farrel, P. G.; Shahidi, F. Partial Molar Volumes of Organic Compounds in Carbon Tetrachloride. IV. Ketones, Alcohols, and Ethers. Can. J. Chem. 1979, 57, 2585-2592.
26. Sakurai, M. Partial Molar Volumes in Aqueous Mixtures of Nonelectrolytes. III. t-Pentyl Alcohol. J. Solution Chem. 1989, 18, 37-44.
27. 2O. J. Chem. Thermodyn. 1986, 18, 429-442.
28. Sköld, R.; Suurkuusk, J.; Wadsö, I. Thermochemistry of Solutions of Biochemical Model Compounds. 7. Aqueous Solutions of Some Amides, t-Butanol and Pentanol. J. Chem. Thermodyn. 1976, 8, 1075-1080.