Pseudo-rotation mechanism for fast olefin exchange and substitution processes at orthometalated C,N-complexes of platinum(II)†

Dalton Transactions

Volumn , Issue 21, 2004, Pages 3662-3668

  Otto, Stefanus ^a,d   Samuleev, Pavel V ^a   Polyakov, Vladimir A ^b   Ryabov, Alexander D ^c   Elding, Lars I ^a  

^a LUND UNIVERSITY   (Sweden)

^b D I Mendeleev Moscow Univ CT   (Russian Federation)

^c CARNEGIE MELLON UNIVERSITY   (United States)

^d SASOL TECHNOLOGY PTY LTD   (South Africa)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; CATALYSIS; ISOMERIZATION; METALS; REACTION KINETICS; SUBSTITUTION REACTIONS; THERMODYNAMIC STABILITY; X RAY CRYSTALLOGRAPHY;

BRIDGE SPLITTING REACTIONS; CYCLOPLATINATED COMPOUNDS; PHOSPHINE; STERIC HINDRANCE;

OLEFINS;

EID: 9644291408     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b409887k     Document Type: Article

References (40)

1. J. Dehand and M. Pfeffer, Coord. Chem. Rev., 1976, 18(3), 327-52.
2. I. Omae, Organometallic Intramolecular Coordination Compounds, Elsevier Science Publ., Amsterdam, 1986.
3. I. Omae, Chem. Rev., 1979, 79(4), 287-321.
4. A. D. Ryabov, S. Otto, P. V. Samuleev, V. A. Polyakov, L. Alexandrova, G. M. Kazankov, S. Shova, M. Revenco, J. Lipkowski and M. H. Johansson, Inorg. Chem., 2002,41(16), 4286-4294.
5. A. D. Ryabov, L. Kuz'mina, V. A. Polyakov, G. M. Kazankov, E. S. Ryabova, M. Pfeffer and R. van Eldik, J. Chem. Soc., Dalton Trans., 1995, 999-1006.
6. A. D. Ryabov, Chem. Rev., 1990, 90(2), 403-424.
7. G. M. Kazankov, V. S. Sergeeva, E. N. Efremenko, L. Alexandrova, S. D. Varfolomeev and A. D. Ryabov, Angew. Chem., Int. Ed., 2000, 39(17), 3117-3119.
8. L. Alexandrova, O. G. D'Yachenko, G. M. Kazankov, V. A. Polyakov, P. V. Samuleev, E. Sansores and A. D. Ryabov, J. Am. Chem. Soc., 2000, 122(21), 5189-5200.
9. R. Romeo, M. R. Plutino, L. M. Scolaro, S. Stoccoro and G. Minghetti, Inorg. Chem., 2000, 39(21), 4149-4155.
10. M. R. Plutino, L. M. Scolaro, R. Romeo and A. Grassi, Inorg. Chem., 2000, 39(13), 2712-2720.
11. R. Romeo, M. R. Plutino, L. M. Scolaro and S. Stoccoro, Inorg. Chim. Acta, 1997, 265(1-2), 225-233.
12. M. Albrecht, M. Lutz, A. L. Spek and G. van Koten, Nature, 2000, 406(6799), 970-974.
13. R. G. Pearson and M. M. Muir, J. Am. Chem. Soc., 1966, 88(10), 2163-2166.
14. M. M. Muir and E. M. Cancio, Inorg. Chim. Acta, 1970, 4(4), 565-567.
15. M. M. Muir and E. M. Cancio, Inorg. Chim. Acta, 1970, 4(4), 568-570.
16. L.I. Elding and L. F. Olsson, Inorg. Chem., 1977, 16(11), 2789-2794.
17. S. Otto, A. Roodt and L. I. Elding, Dalton Trans., 2003, 2519-2525.
18. P. S. Pregosin, F. Wombacher, A. Albinati and F. Lianza, J. Organomet. Chem., 1991, 418(2), 249-267.
19. M. R. Plutino, S. Otto, A. Roodt and L. I. Elding, Inorg. Chem., 1999, 38(6), 1233-1238.
20. A. D. Ryabov, L. G. Kuz'mina, N. V. Dvortsova, D. J. Stufkens and R. van Eldik, Inorg. Chem., 1993, 32(14), 3166-3174.
21. J. Terheijden, G. van Koten, F. Muller, D. M. Grove, K. Vrieze, E. Nielsen and C. H. Stam, J. Organomet. Chem., 1986, 315(3), 401-17.
22. S. Otto and L. I. Elding, J. Chem. Soc., Dalton Trans., 2002, 2354-2360.
23. SCIENTIST, Program for Least-squares Parameter Optimization, MicroMath Scientific Software, Utah, USA.
24. KinetAsyst2, Version 2.2, Hi-Tech Limited, Salisbury, UK, 1999.
25. P. H. M. Budzelaar, gNMR, V4.0.1., Cherwell Scientific Publishing, Oxford, UK, 1998.
26. SAINT, Siemens Analytical X-ray Instruments Inc., Madison, WI, USA, 1995.
27. G. M. Sheldrick, SADABS, University of Göttingen, Germany.
28. G. M. Sheldrick, SHELXL97, University of Göttingen, Germany.
29. K. Brandenburg and M. Berndt, DIAMOND, Version 2.1, Crystal Impact, GGR, Bonn, Germany, 1999.
30. A. Albinati, S. Affolter and P. S. Pregosin, Organometallics., 1990, 9(2), 379-387.
31. M. L. Tobe and J. Burgess, Inorganic Reaction Mechanisms, Addison Wesley Longman Ltd., Harlow, UK, 1999, p. 93.
32. R. Cramer, Inorg. Chem., 1965, 4(4), 445-447.
33. R. Cramer, J. Am. Chem. Soc., 1964, 86(2), 217-222.
34. A. Olsson and P. Kofod, Inorg. Chem., 1992, 31(2), 183-186.
35. G. Natile, L. Maresca and L. Cattalini, J. Chem. Soc., Dalton Trans., 1977, 651-655.
36. L. I. Elding and A. B. Gröning, Inorg. Chim. Acta, 1980, 38(1), 59-66.
37. L. I. Elding and Ö. Gröning, Inorg. Chem., 1978, 17(7), 1872-1880.
38. M. L. Tobe, Comprehensive Coordination Chemistry, ed. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Pergamon, Oxford, UK, 1987, p. 318.
39. M. L. Tobe and J. Burgess, Inorganic Reaction Mechanisms, Addison Wesley Longman Ltd., Harlow, UK, 1999, p. 217.
40. G. K. Anderson and R. J. Cross, Chem. Soc. Rev., 1980, 9(2), 185-215.