Novel hypervalent complexes of main-group metals by intramolecular ligand→metal electron transfer

Chemistry - A European Journal

Volumn 10, Issue 23, 2004, Pages 5971-5976

  Driess, Matthias ^a   Dona, Nicoleta ^a   Merz, Klaus ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

Carbene homologues; Charge transfer complexes; Hypervalent compounds; Lithium enolates; N,O ligands

Indexed keywords

AMINES; CHARACTERIZATION; CHELATION; GERMANIUM COMPOUNDS; HALIDE MINERALS; LITHIUM;

CHELATE LIGANDS; ELECTRON TRANSFERS; MONOMERIC STANNYLENE; REDOX REACTION;

OXIDATION;

1,2 DIKETOIMINE ENOLATE; AMIDO DIENOLATE; AMINE; DIKETOAMINE; GERMANIUM DERIVATIVE; IMINE; LEAD; LIGAND; LITHIUM DERIVATIVE; LITHIUM ION; METAL COMPLEX; TIN; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; ELECTROCHEMICAL ANALYSIS; ELECTRON TRANSPORT; MOLECULAR STABILITY; OXIDATION; REACTION ANALYSIS; REDUCTION; SOLID STATE;

EID: 9644289641     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400807     Document Type: Article

References (27)

1. a) R. Robsen, Inorg. Nucl. Chem. Lett. 1970, 6, 125;
2. b) A. Y. Girgis, A. L. Balch, Inorg. Chem. 1975, 14, 2724;
3. c) D. G. Tuck, Coord. Chem. Rev. 1992, 112, 215;
4. d) S. Bruni, A. Caneschi, F. Cariati, C. Delfs, A. Dei, D. Gatteschi, J. Am. Chem. Soc. 1994, 116, 1388-1394;
5. e) P. Chaudhuri, M. Hess, K. Hildenbrand, E. Bill, T. Weyhermüller, K. Wieghardt, Inorg. Chem. 1999, 38, 2781-2790;
6. f) K. Ohkata, T. Yano, T. Kuwaki, K. Akiba, Chem. Lett. 1990, 1721-1724;
7. g) C. Camacho-Camacho, G. Merino, F. J. Martinez-Martinez, H. Nöth, R. Contreras, Eur. J. Inorg. Chem. 1999, 1021-1027;
8. h) K. S. Min, T. Weyhermüller, K. Wieghardt, Dalton Trans. 2004, 178-186, and references therein.
9. For example: a) R. Siefert, T. Weyhermüller, P. Chaudhuri, Dalton Trans. 2000, 4656-4663;
10. b) U. Beckmann, E. Bill, T. Weyhermüller, K. Wieghardt, Eur. J. Inorg. Chem. 2003, 1768-1777;
11. c) T. K. Paine, E. Rentschler, T. Weyhermüller, P. Chaudhuri, Eur. J. Inorg. Chem. 2003, 3167-3178, and references therein.
12. For example: a) Y. Wang, J. L. DuBois, B. Hedman, K. O. Hodgson, T. D. P. Stack, Science 1998, 279, 537;
13. b) P. Chaudhuri, M. Hess, U Flörke, K. Wieghardt, Angew. Chem. 1998, 770, 2340; Angew. Chem. Int. Ed. 1998, 37, 2217.
14. b) P. Chaudhuri, M. Hess, U Flörke, K. Wieghardt, Angew. Chem. 1998, 770, 2340; Angew. Chem. Int. Ed. 1998, 37, 2217.
15. D. J. Cram, F. A. Abd Elhafez, J. Am. Chem. Soc. 1952, 74, 5828.
16. Reviews: a) A. J. Arduengo III, C. A. Steward, Chem. Rev. 1994, 94, 1215-1237;
17. b) V. I. Minkin, R. M. Minyaev, Chem. Rev. 2001, 101, 1247-1265.
18. G. Bettermann, A. J. Arduengo III, J. Am. Chem. Soc. 1988, 110, 877-879.
19. I. I. Seifullina, N. V. Shmatkova, Z. A. Starikova, Russ. J. Inorg. Chem. 2001, 46, 1150-1155.
20. G. Aullón, D. Bellamy, L. Brammer, E. Bruton, A. G. Orpen, Chem. Commun. 1998, 653-654, and references therein.
21. Review: K. W. Klinkhammer, "Recent advances in structural chemistry of organic germanium, tin and lead compounds" in The Chemistry of Organic Germanium, Tin and Lead Compounds, Vol. 2 (Ed.: Z. Rappoport), Wiley, 2002, pp. 304-313, and references therein.
22. a) N. A. Khanjin, F. M. Menger, J. Org. Chem. 1997, 62, 8923-8927;
23. b) P. A. Schaaf, J. T. B. H. Jastrzebski, M. P. Hogerheide, W. J. J. Smeets, A. L. Spek, J. Boersma, G. van Koten, Inorg. Chem. 1993, 32, 4111.
24. Reviews: a) D. Seebach, Angew. Chem. 1988, 700, 1685-1715; Angew. Chem. Int. Ed. Engl. 1988, 27, 1624;
25. Reviews: a) D. Seebach, Angew. Chem. 1988, 700, 1685-1715; Angew. Chem. Int. Ed. Engl. 1988, 27, 1624;
26. b) F. Pauer, P. P. Power, "Structures of Lithium Salts of Heteroatom Compounds" in Lithium Chemistry - A Theoretical and Experimental Overview (Eds.: A.-M. Sapse, P. von R. Schleyer), Wiley, New York, 1995, pp. 295-311.
27. G. M. Sheldrick, SHELXTL-97, University of Göttingen, 1997.