Novel stereoselective synthesis of (E)-cinnamonitriles via Heck arylation of acrylonitrile catalysed by a silica-supported bidentate arsine palladium(0) complex

Journal of Chemical Research

Volumn , Issue 9, 2004, Pages 622-623

  Cai, Mingzhong ^a   Tong, Xiaokai ^a   Chen, Junmin ^a   Huang, Yizheng ^a  

^a JIANGXI NORMAL UNIVERSITY   (China)

Author keywords

(E) cinnamonitrile; Bidentate palladium(0) complex; Heck arylation; Stereoselective synthesis; Supported palladium catalyst

Indexed keywords

ACRYLONITRILE; ARSINE; CINNAMONITRILE DERIVATIVE; NITRILE; PALLADIUM COMPLEX; SILICON DIOXIDE; UNCLASSIFIED DRUG;

ARTICLE; ARYLATION; CATALYSIS; FILTRATION; HECK REACTION; HORNER REACTION; STEREOCHEMISTRY; SYNTHESIS;

EID: 9644274245     PISSN: 03082342     EISSN: None     Source Type: Journal    
DOI: 10.3184/0308234042430359     Document Type: Article

References (11)

1. G.I. Georg and S.A. Pfeifer, Tetrahedron Lett., 1985, 26, 2739.
2. T.B. Francoise and F. Andre, Synthesis, 1979, 884.
3. A. Hulkenberg and J.J. Troost, Tetrahedron Lett., 1982, 23, 1505.
4. X. Huang, J.H. Pi and Z.Z. Huang, Phosphorus Sulfur Silicon Relat. Elem., 1992, 67, 177.
5. H. Guo and Y. Zhang, J. Chem. Res., 1999, 342.
6. C.B. Ziegler and R.F. Heck, J. Org. Chem., 1978, 43, 2941.
7. R.F. Heck, Acc. Chem. Res., 1979, 12, 146.
8. R.F. Heck, Pure Appl. Chem., 1978, 50, 691.
9. M. Cai, Y. Huang, H. Zhao and C. Song, J. Organomet. Chem., 2003, 682, 20.
10. N.O. Pastushak, N.F. Stadniichuk and A.V. Dombrovskii, Zh. Ohshch. Khim., 1963, 33, 2950.
11. H. Zhao, M.Z. Cai and C.Y. Peng, Synth. Commun., 2002, 32, 3419.