Intermetallics as cathode materials in the electrolytic hydrogen production

International Journal of Hydrogen Energy

Volumn 30, Issue 1, 2005, Pages 21-28

  Stojić, Dragica Lj ^a   Cekić, Božidar D ^a   Maksić, Aleksandar D ^a   Kaninski, Milica P Marčeta ^a   Miljanić, Šćepan S ^b  

^a UNIVERSITY OF BELGRADE   (Serbia)

^b UNIVERSITY OF BELGRADE   (Serbia)

Author keywords

Electrolysis; Hydrogen production; Intermetallic phases; Ionic activators

Indexed keywords

CATALYSIS; CATHODES; ELECTROLYSIS; ELECTROLYTES; ELECTROLYTIC ANALYSIS; GAS GENERATORS; HYDROGEN; ION SOURCES; SOLUTIONS; TRANSITION METALS;

CATHODE MATERIALS; ELECTROLYTIC EFFICIENCY; HYDROGEN PRODUCTION; INTERMETALLIC PHASES; IONIC ACTIVATORS;

INTERMETALLICS;

EID: 9544226467     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2004.05.005     Document Type: Article

References (21)

1. Tromp TK, Shia RL, Allen M, Eiler JM, Yung YL. Potential environmental impact of a hydrogen economy on the stratosphere. Science 2003;300(5626):1740-2.
2. Stojić DLj, Marčeta MP, Sovilj SP, Miljanić ŠS. Hydrogen generation from water electrolysis-possibilities of energy saving. J Power Sources 2003;118:315-9.
3. Thomas JM, Thomas WJ. Principles and practice of heterogeneous catalysis. Weinheim: Wiley-VCH; 1997.
4. Jakšić MM, Komnenić V, Atanasoski R, Adžić R. Elektrokataliz pri videlenii vodoroda na titane, ego splavah i grafite. Elektrokhim 1977;13:1355-60.
5. Jakšic MM, Lačnjevac ČM. Synergetic electrocalalytic effects of d-metals on the hydrogen evolution reaction in industrially important electrochemical processes. Chem Tech 1985;37(6):257-9.
6. Kita H. Periodic variation of exchange current density of hydrogen electrode reaction with atomic number and reaction mechanism. J Electrochem Soc 1966;113(11):1095-111.
7. Gschneider KA. Physical properties and interrelations of metallic and semimetallic elements. In: Seitz F, Turnbull D, editors. Solid state physics. New York: Academic Press; 1964. p. 275-427.
8. Brewer L. Prediction of high temperature metallic phase diagrams. In: Zackay VF, editor. High-strength materials. New York: Wiley; 1965. p. 12-103.
9. Jakšić MM. The Brewer intermetallic bonding theory and electrocatalysis for hydrogen evolution. High Temperature Sci 1990;30:19-49.
10. Brewer L. Chemical bonding theory applied to metals. In: Walter JL, Jackson MR, Sims CT, editors. Alloying. New York: ASM International; 1988. p. p1-.
11. Brewer L, Wengert PR. Transition metal alloys of extraordinary stability; An example of generalized Lewis-acid-base interactions in metallic systems. Metall Trans 1973;4:83-103.
12. Brewer L. Bonding and structures of transition metals. Science 1968;161:115-22.
13. Jakšić MM, Lačnjevac CM, Grgur BN, Krstajić NV. Volcano plots along intermetallic hypo-hyper-d-electronic phase diagrams and electrocatalysis for hydrogen electrode reactions. J New Mat Electrochem Systems 2000;3: 169-82.
14. Krstajić NV, Grgur BN, Mladenović NS, Vojnovic MV, Jakšić MM. The determination of kinetics parameters of the hydrogen evolution on Ti-Ni alloys by ac impedance. Electrochim Acta 1997;42(2):323-30.
15. Jakšić JM, Krstajić NV, Grgur BN, Jakšić MM. Hydridic and electrocatalytic properties of hypo-hyper-d-electronic combinations of transition metal intermetallic phases. Int J Hydrogen Energy 1998;23(8):667-81.
16. Jakšić MM. Brewer intermetallic phases as synergetic electrocatalysts for hydrogen evolution. Materials Chem Phys 1989;22(1-2):1-26.
17. 30 bulk alloy electrode. J Phys Chem B 1998;102:2494-501.
18. 2 evolution reactions and the characterization of participating adsorbed intermediates. Int J Hydrogen Energy 1987;12(9):607-21.
19. 2 due to hydrogenation. Intermetallics 1999;7(2):207-11.
20. Miljanić ŠS, et al. Unpublished results.
21. x (x = 0-5). J Less-Common Metals 1987;29:87-195.