Competition of aminolysis and alcoholysis in nucleophilic cleavage of a model compound for polysiloxane networks

Polymer Degradation and Stability

Volumn 87, Issue 1, 2005, Pages 207-211

  Chang, C L ^a   Lin, Y K ^a  

^a TAMKANG UNIVERSITY   (Taiwan)

Author keywords

Alcoholysis; Aminolysis; Base catalyst; Model compound; Poly (dimethylsiloxane) network

Indexed keywords

ACTIVATION ENERGY; AMINES; CATALYSTS; ETHANOL; GAS CHROMATOGRAPHY; SUBSTITUTION REACTIONS; VULCANIZATION;

ALCOHOLYSIS; AMINOLYSIS; BASE CATALYSTS; MODEL COMPOUNDS; POLY(DIEMETHYLSILOXANE) NETWORK;

SILICONES;

EID: 9444271653     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2004.07.022     Document Type: Article

References (7)

1. Hsiao YC, Hill LW, Pappas SP. J Appl Polym Sci 1975;19:2817.
2. Pappas SP, Just RL. J Polym Sci Polym Chem Ed 1980;18:527.
3. Schimmel KH. Acta Polymerica 1987;38:495.
4. Schimmel KH, Schulz J. Acta Polymerica 1987;38:536.
5. Schimmel KH, Schroder E, Schulz J, Souvimonh J. Acta Polymerica 1988;39:310.
6. Chang CL, Lee HS, Chen CK. Polym Degrad Stab 1999;65:1.
7. Voronkov MG, Basenk SV, editors. Heterolytic cleavage reactions of the siloxane bond, Sov Sci Rev B, Chem Rev 1990; 15.