The discovery of ExxonMobil's M41S family of mesoporous molecular sieves

Studies in Surface Science and Catalysis

Volumn 148, Issue , 2004, Pages 53-72

  Kresge, Charles T ^a   Vartuli, James C ^b   Roth, Wieslaw J ^b   Leonowicz, Michael E ^c  

^a DOW CHEMICAL COMPANY   (United States)

^b EXXONMOBIL UPSTREAM RESEARCH COMPANY   (United States)

^c NONE

Author keywords

ExxonMobil; M41S; MCM 41; Mesoporous; Mobil; Molecular Sieves

Indexed keywords

CETRIMIDE; ZEOLITE;

CHEMICAL STRUCTURE; CONFERENCE PAPER; NANOTECHNOLOGY; POROSITY; SIEVE TUBE; STRUCTURE ANALYSIS; SYNTHESIS; TRANSMISSION ELECTRON MICROSCOPY; X RAY DIFFRACTION;

EID: 9344267137     PISSN: 01672991     EISSN: None     Source Type: Book Series    
DOI: 10.1016/s0167-2991(04)80193-9     Document Type: Conference Paper

References (45)

1. Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; and J. C. Vartuli, "Synthetic Mesoporous Crystalline Material" US Patent 5,098,684, March 24, 1992 (assigned to ExxonMobil)
2. Kresge, C. T., Leonowicz, M. E.; Roth, W. J.; and J. C. Vartuli, "of Synthetic Porous Crystalline Material, Its Synthesis" US Patent 5,102,643, April 7, 1992 (assigned to ExxonMobil)
3. Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., and J. S. Beck, "Ordered Mesoporous Molecular Sieves Synthesized by a Liquid-Crystal Template Mechanism," Nature, 1992, 359, 710-712.
4. Beck, J. S. Vartuli, J. C., Roth, W. J., Leonowicz, M. E., Kresge, C. T., Schmitt, K. D., Chu, C. T-W., Olson, D. H., Sheppard, E. W., McCullen, S. B., Higgins, J. B., and J. L. Schlenker, "A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates." J. Am. Chem. Soc. 1992, 114, 10834-10843.
5. J.C. Vartuli, K.D. Schmitt, C.T. Kresge, W.J. Roth, M.E. Leonowicz, S.B. McCullen, S.D. Hellring, J.S. Beck, J.L. Schlenker, D.H. Olson, and E.W. Sheppard, "Development of a Formation Mechanism for M41S Materials", Zeolites and Related Microporous Materials: State of the Art1994 (Proceedings of the 10th International Zeolite Conference, Garmisch-Partenkirchen, Germany, 7/17-22/94), J. Weitkamp, H.G. Karge, H. Pfeifer, and W. Hölderich, (eds.), Elsevier Science, 53(1994).
6. J.S. Beck, J.C. Vartuli, G.D. Kennedy, C.T. Kresge, W.J. Roth, and S.E. Schramm, "Molecular or Supramolecular Templating: Defining the Role of Surfactant Chemistry in the Formation of Microporous and Mesoporous Molecular Sieves", Chemistry of Materials, 6(10), 1816-21 (1994).
7. J.C. Vartuli, C.T. Kresge, M.E. Leonowicz, A.S. Chu, S.B. McCullen, I.D. Johnson, and E.W. Sheppard, "Synthesis of Mesoporous Materials: Liquid Crystal Templating versus Intercalation of Layered Silicates", Chemistry of Materials, 6(11), 2070-77(1994).
8. J.C. Vartuli, K.D. Schmitt, C.T. Kresge, W.J. Roth, M.E. Leonowicz, S.B. McCullen, S.D. Hellring, J.S. Beck, J.L. Schlenker, D.H. Olson, and E.W. Sheppard, "Effect of Surfactant:Silica Ratios on the Formation of Mesoporous Molecular Sieves: Inorganic Mimicry of Surfactant Liquid Crystal Phases and Mechanistic Implications", Chemistry of Materials, 6(12), 2317-26 (1994).
9. C.T. Kresge, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, J.S. Beck, K.D. Schmitt, C. T-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J.L. Schlenker, "M41S: A New Family of Mesoporous Molecular Sieves Prepared with Liquid Crystal Templates", Science and Technology in Catalysis 1994, Y. Izumi, H. Arai, M. Iwamoto (eds.), Elsevier Science, 11 (1994).
10. J.S. Beck, J.C. Vartuli, G.D. Kennedy, C.T. Kresge, W.J. Roth, and S.E. Schrammn, "Molecular or Supramolecular Templating: Defining the Role of Surfactant Chemistry in the Formation of Microporous and Mesoporous Molecular Sieves", Catalysis by Microporous Materials, Studies in Surface Science and Catalysis, Vol. 98, H. K. Beyer, H. G. Karge, I. Kiricsi, and J. B. Nagy (eds.), Elsevier Science, 15-16 (1995).
11. S.B. McCullen, J.C. Vartuli, C.T. Kresge, W.J. Roth, J.S. Beck, K.D. Schmitt, M.E. Leonowicz, J.L. Schlenker, S.S. Shih, and J.D. Lutner, "A New Family of Mesopore Molecular Sieves", Proceedings of the Nanomaterials Symposium at Mich. State Univ. in May, 1995, Access in Nanoporous Materials, T. J. Pinnavaia and M. F. Thorpe (eds.), Plenum Press, 1-10 (1995).
12. C.T. Kresge, S.B. McCullen, J.C. Vartuli, W.J. Roth, J.S. Beck, K.D. Schmitt, M.E. Leonowicz, J.L. Schlenker, J.D. Lutner, "Molecular Sieves as Hosts for Nanophases - Design, Preparation, and Properties", Proc. Robert A. Welch Found. Conf. Chem. Res. 1995, 39th (Nanophase Chemistry), 139-48 (1995).
13. J.S. Beck and J.C. Vartuli, "Recent advances in the synthesis, characterization, and applications of mesoporous molecular sieves", Current Opinion in Solid State and Materials Science, 1, 76-87 (1996).
14. J.C Vartuli, C.T. Kresge, W.J. Roth, S.B. McCullen, J.S. Beck, K.D. Schmitt, M.E. Leonowicz, J.D. Lutner, and E.W. Sheppard, "Designed Synthesis of Mesopore Molecular Sieve Systems using Surfactant Directing Agents" Div. Pet. Chem. 1995, 40(1), 21-5 and Advanced Catalysis and Nanostructured Materials, W. Moser (ed.), Academic Press, 1-19 (1996).
15. J.C Vartuli, C.T. Kresge, W.J. Roth, S.B. McCullen, J.S. Beck, K.D. Schmitt, M.E. Leonowicz, J.D. Lutner, and E.W. Sheppard, "Designed Synthesis of Mesopore Molecular Sieve Systems using Surfactant Directing Agents" Div. Pet. Chem. 1995, 40(1), 21-5 and Advanced Catalysis and Nanostructured Materials, W. Moser (ed.), Academic Press, 1-19 (1996).
16. J.S. Beck, S.D. Hellring and J.C. Vartuli, "Micellar Solubilization in the Synthesis of M41S Materials: To Swell or not to Swell, What are the Considerations?", Book of Abstracts, 213th ACS National Meeting, San Francisco, April 13-17 (1997), COLL-311.
17. J.C. Vartuli, W.J. Roth, J.S. Beck, S.B. McCullen, C.T. Kresge, "The Synthesis and Properties of M41S and Related Mesoporous Materials", Molecular Sieves - Science and Technology Volume 1 Synthesis, eds. H. G. Karge and J. Weitkamp, 97-121 (1998).
18. J.C. Vartuli, S.S. Shih, C.T. Kresge, J.S. Beck, "Potential Applications for M41S Type Mesoporous Molecular Sieves" Mesoporous Molecular Sieves 1998, Studies in Surface Science and Catalysis Volume 117, eds. L. Bonneviot, F. Beland, C. Danumah, S. Giasson, S. Kaliaguine, 13-23 (1998).
19. Chitnis, G. K., Vartuli, J. C., Kresge, C. T., and Johnson, I. D., "Latest Trends in M41S type Mesoporous Molecular Sieves and Their Novel Applications", Proceedings of the International Symposium on Frontiers in Catalysis in the 21st Century, India, 1999.
20. Roth, W. J., Vartuli, J. C., and Kresge, C. T. "Characterization of mesoporous molecular sieves: Differences between M41S and pillared layered zeolites", Stud. Surf. Sci. Catal. 129 Nanoporous Materials II. Proceedings of the Conference on Access in Nanoporous Materials, 2000, 501-08.
21. Landis, M. E., Aufdembrink, B. A., Chu, P., Johnson, I. D., Kirker, G. W., and M. K. Rubin, Preparation of Molecular Sieves from Dense Layered Metal Oxides," J. Am. Chem. Soc, 1991, 113, 3189-3192.
22. Leonowicz, M. E.; Lawton, J. A.; Lawton, S. L.; Rubin, M. K., MCM-22: A Molecular Sieve with Two Independent Multidimensional Channel Systems, Science, 1994, 264, 1910-1915.
23. Kresge, C. T.; Roth, W. J.; Simmons, K. G.; Vartuli, J. C., Crystalline Oxide Material. US Patent 5,229,341, July 20, 1993, Mobil Oil Corporation.
24. Roth, W. J.; Kresge, C. T.; Vartuli, J. C.; Leonowicz, M. E.; Fung, A. S.; McCullen, S. B., MCM-36. The First Pillared Molecular Sieve with Zeolite Properties", Catalysis by Microporous Materials, Studies in Surface Science and Catalysis, Vol. 94, H. K. Beyer, H. G. Karge, I. Kiricsi, and J. B. Nagy (eds.), Elsevier Science. 1995, 94, 301.
25. Roth, W. J.; Vartuli, J. C., The Effect of Stoichiometry and Synthesis Conditions on the Properties of Mesoporous M41S Family Silicates. Stud. Surf. Sci. Catal. 2002, 141, 273.
26. Smith, J. V.; Dydrich, W. J., Nets With Channels of Unlimited Diameter, Nature. 1984, 309, 607-08.
27. Beck, J. S., Method for Synthesizing Mesoporous Crystalline Material. US Patent 5,057,296, October 15, 1991, Mobil Oil Corporation.
28. Beck, J. S.; Vartuli, J. C.; Kennedy, G. J.; Kresge, C. T.; Roth, W. J.; Schramm, S. E., Molecular or Supramolecular Templating: Defining the Role of Surfactant Chemistry in the Formation of Microporous and Mesoporous Molecular Sieves. Chem. Mater. 1994, 6(10), 1816-1821.
29. Vartuli, J. C.; Schmitt, K. D; Kresge, C. T.; Roth, W. J.; Leonowicz, M. E.; McCullen, S. B.; Hellring, S. D.; Beck, J. S.; Schlenker, J. L.; Olsen, D. H.; Sheppard, E. W., Effects of Surfactant/Silica Molar Ratios on the Formation of Mesoporous Molecular Sieves: Inorganic Mimicry of Surfactant Liquid-Crystal Phases and Mechanistic Implications. Chem. Mater. 1994, 6, 2317-2326.
30. Stucky, G. D.; Monnier, A.; Schueth, F.; Huo, Q.; Firouzi, D. I.; Janicke, M.; Chmelka, B. F., Molecular and Atomic Arrays in Nano- and Mesoporous Materials Synthesis. Mol. Crysta. Liq. Cryst. 1994, 240, 187-196.
31. Firouzi, A.; Kumar, D.; Bull, L. M.; Besier, T.; Siegar, P.; Huo, Q.; Walker, S. A.; Zasadzinski, J.; Glinka, A. G.; Nicol, J.; Marogloese, D.; Stucky, G. D.; Chmelka, B. F., Cooperative Organization of Inorganic Surfactant and Biomimetic Assemblies. Science 1995, 267, 1138-1143.
32. Tanev, P. T.; Chibwe, M.; Pinnavaia, T. J., Titanium-Containing Mesoporous Molecular Sieves for Catalytic Oxidation of Aromatic Compounds. Nature, 1994, 368, 321-324.
33. Pinnavaia, T. J.; Zhang, W., Catalytic properties of mesoporous molecular sieves prepared by neutral surfactant assembly, Mesoporous Molecular Sieves 1998, Studies in Surface Science and Catalysis, Vol. 117, L. Bonneviot, F. Beland, C. Danumah, S. Giasson, S. Kaliaguine (eds.), Elsevier Science, 1998, 117, 23-36.
34. Attard, G. S.; Glyde, J. C.; Goltner, C. G., Liquid-Crystalline Phases as Templates for the Synthesis of Mesoporous Silica. Nature. 1995, 378, 366 (1995).
35. Attard, G. S.; Leclerc, S. A. A.; Maniquet, S.; Russell, A. E.; Nandakumer, I.; Gollas, B. R.; Bartlett, P. N., Ordered Mesoporous Silicas Prepared from Both Micellar Solutions and Liquid Crystal Phases. Micro. and Meso. Mater. 2001, 44-45, 159-163.
36. Roth, W. J.; Vartuli, J. C., The effect of stoichiometry and synthesis conditions on the properties of mesoporous M41S family silicates, Zeolites and Mesoporous Materials at The Dawn of 21st Century, Studies in Surface Science and Catalysis, Vol. 135, A. Galarneau, F. di Renzo, F. Fajula, J. Vedrine (eds.), Elsevier Science, 2001, 135, 134.
37. Beck, J. S.; Calabro, D. C.; McCullen S. B.; Pelrine, B. P.; Schmitt, K. D.; Vartuli, J. C., Method for Functionalizing Mesoporous Crystalline Material, US Patent 5,145,816, September 8, 1992.
38. idem, Catalytic Conversion over Modified Synthetic Mesoporous Crystalline Material, US Patent 5,200,058, April 6, 1993.
39. idem, Sorption/separation over Modified Synthetic Mesoporous Crystalline Material, US Patent 5,220,101, June 15, 1993.
40. Kresge, C. T.; Leonowicz, M. E.; Roth, W. J.; Vartuli, J. C., Use of Amphiphilic Compounds to Produce Novel Classes of Crystalline Materials, US. Patent 5,250,282, October 5, 1993.
41. Olson, D. H.; Stucky, G. D.; Vartuli, J. C., Sensor Device Containing Mesoporous Crystalline Material, US Patent 5,348,687, Nov. 15, 1994.
42. Beck, J. S.; Kuehl, G. H.; Olsen, D. H.; Schlenker, J. L.; G. D. Stucky, G. D.; Vartuli, J. C., US Patent 5,364,797, Sept. 20, 1994.
43. Herbst, J. A.; Kresge, C. T.; Olson, D. H.; Schmitt, K. D.; Vartuli, J. C.; Wang, D. L. C., US Patent 5,378,440, Jan. 3, 1995.
44. Yanagisawa, T.; Shimizu, T.; Kazuyuki, K, Kato, K., Bull. Chem. Soc. Japan, 63,1990, 988-992.
45. Inagaki, S.; Fukushima, Y.; Okada, A.; Kurauchi, T.; Kuroda, K.; Kato, C., New silica-alumina with nano-scale pores prepared from Kanemite, Proceedings from the Ninth International Zeolite Conference, R. von Ballmos, J. B. Higgins, M.M.J. Treacy, (eds.), 1994, 305.