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Volumn 33, Issue 9, 2004, Pages 1180-1181

Tetrakis(trimethylsilylbutadiynyl)ethene, C18(SiMe 3)4: An extended two-dimensional π-conjugated system consisting of eighteen carbon atoms

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; SILANE DERIVATIVE; TETRAKIS(TRIMETHYLSILYLBUTADIYNYL)ETHENE; UNCLASSIFIED DRUG;

EID: 9344222755     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2004.1180     Document Type: Article
Times cited : (6)

References (22)
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    • M. I. Bruce and P. J. Low, Adv. Organomet. Chem., 50, 180 (2004); F. Paul and C. Lapinte, Coord. Chem. Rev., 178, 431 (1998); D. Touchard and P. H. Dixneuf, Coord. Chem. Rev., 178, 409 (1998); N. J. Long and C. K. Williams, Angew. Chem., Int. Ed., 42, 2586 (2003); U. H. F. Bunz, J. Organomet. Chem., 683, 269 (2003).
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    • note
    • 3), to prevent base-catalyzed desilylation leading to explosive unprotected tetraethynylethene derivatives. But addition of HCl aq. to 1 caused its deterioration.
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    • note
    • 2) for 3493 data (I > 2σ(I)) and 329 parameters. The disordered olefinic part was refined taking into account a minor component [C(01,02):C(01a, 02a) = 0.753 : 0.247].
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    • Twisting of 1-D polyyne linkage was noted. A. Sakurai, M. Akita, and Y. Moro-oka, Organometallics, 18, 3241 (1999); S. Szafert and J. A. Gladysz, Chem. Rev., 103, 4175 (2003).
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.