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Volumn 43, Issue 44, 2004, Pages 5922-5925

Supramolecular, bifurcated N-H⋯OC-M bonding explains unusually low vco frequencies in metal carbonyl compounds: A case study

Author keywords

Carbonyl ligands; Hydrogen bonds; IR spectroscopy; Structure elucidation; Supramolecular chemistry

Indexed keywords

CHEMICAL BONDS; CRYSTAL STRUCTURE; PROTONS; STRUCTURE (COMPOSITION); SUPRAMOLECULAR CHEMISTRY; X RAY ANALYSIS;

EID: 9244259063     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461175     Document Type: Article
Times cited : (17)

References (43)
  • 6
    • 9244240362 scopus 로고    scopus 로고
    • note
    • See the Supporting Information for a listing of relevant references.
  • 8
    • 9244246368 scopus 로고    scopus 로고
    • German Patent 498578, 1965
    • b) W. Strohmeier, German Patent 498578, 1965;
    • Strohmeier, W.1
  • 13
    • 0038263047 scopus 로고    scopus 로고
    • (Ed.: J. D. Woollins), Wiley-VCH, Weinheim
    • g) M. A. Beckett, in Inorganic Experiments, 2nd ed. (Ed.: J. D. Woollins), Wiley-VCH, Weinheim, 2003, p. 143;
    • (2003) Inorganic Experiments, 2nd Ed. , pp. 143
    • Beckett, M.A.1
  • 16
    • 9244242144 scopus 로고    scopus 로고
    • note
    • 1, have not been assigned.
  • 17
    • 9244265616 scopus 로고    scopus 로고
    • note
    • 2] but with no mention of such IR data.
  • 34
    • 9244233921 scopus 로고    scopus 로고
    • note
    • 2] but omitted to include the N-H protons in the empirical formula and consequently did not locate them. It is therefore impossible to draw strict comparisons with our compound. However, using their data we find intermolecular N⋯O distances of 3.164 and 3.279 Å, similar to the values found in our study. These values, together with the similarity of the unit cell parameters, suggests that a similar H-bonded network is present in both derivatives.
  • 37
    • 9244238796 scopus 로고    scopus 로고
    • P. M. Pihko, Angew. Chem. 2004, 116, 2110; Angew. Chem. Int. Ed. 2004, 43, 2062.
    • (2004) Angew. Chem. , vol.116 , pp. 2110
    • Pihko, P.M.1
  • 38
    • 4544221552 scopus 로고    scopus 로고
    • P. M. Pihko, Angew. Chem. 2004, 116, 2110; Angew. Chem. Int. Ed. 2004, 43, 2062.
    • (2004) Angew. Chem. Int. Ed. , vol.43 , pp. 2062


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.