[Yb3N(dpa)6][Yb(dpa)3]: A molecular nitride of a rare-earth metal with a Yb3N unit

Angewandte Chemie - International Edition

Volumn 43, Issue 44, 2004, Pages 5994-5996

  Quitmann, Catharina C ^a   Müller Buschbaum, Klaus ^a  

^a UNIVERSITY OF COLOGNE   (Germany)

Author keywords

Coordination chemistry; Lanthanoids; N ligands; Nitrides; Ytterbium

Indexed keywords

AMMONIA; LOW TEMPERATURE EFFECTS; MOLECULAR STRUCTURE; NITRIDES; OXIDATION; POLYAMIDES;

DEPROTONATION; LIQUID AMMONIA; LOW TEMPERATURE YIELDS;

YTTERBIUM COMPOUNDS;

HALIDE; METAL COMPLEX; NITRIDE; UNCLASSIFIED DRUG; YTTERBIUM;

ARTICLE; CHEMICAL REACTION; LOW TEMPERATURE PROCEDURES; OXIDATION; PROTON TRANSPORT; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

CRYSTALLOGRAPHY, X-RAY; LANTHANOID SERIES ELEMENTS; MODELS, MOLECULAR; NITROGEN; ORGANOMETALLIC COMPOUNDS; YTTERBIUM;

EID: 9244235972     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460478     Document Type: Article

References (46)

1. A. Simon, H. Mattausch, G. J. Miller, W. Bauhofer, R. K. Kremer in Handbook on the Physics and Chemistry of Rare Earth, Vol. 15 (Eds.: K. A. Gschneider, L. Eyring), Elsevier, Amsterdam, 1991.
2. a) A. Simon, T. Koehler, J. Less-Common Met. 1986, 116, 279;
3. b) U. Schwanitz-Schueller, A. Simon, Z. Naturforsch. B 1985, 40, 705-709;
4. c) H.-J. Meyer, N. L. Jones, J. D. Corbett, Inorg. Chem. 1989, 28, 2635-2637.
5. H. Mattausch, R. K. Kremer, A. Simon, Z. Anorg. Allg. Chem. 1996, 622, 649-654.
6. a) E. O. Fischer, H. Fischer, Angew. Chem. 1964, 76, 52; Angew. Chem. Int. Ed. Engl. 1964, 3, 132;
7. a) E. O. Fischer, H. Fischer, Angew. Chem. 1964, 76, 52; Angew. Chem. Int. Ed. Engl. 1964, 3, 132;
8. b) R. G. Hayes, J. L. Thomas, J. Am. Chem. Soc. 1969, 91, 6876;
9. c) W. J. Evans, Coord. Chem. Rev. 2000, 263-283.
10. a) N. Korber, F. Richter, Angew. Chem. 1997, 109, 1575-1577; Angew. Chem. Int. Ed. Engl. 1997, 36, 1512 -1514;
11. a) N. Korber, F. Richter, Angew. Chem. 1997, 109, 1575-1577; Angew. Chem. Int. Ed. Engl. 1997, 36, 1512 -1514;
12. b) M. Grothe, N. Korber, Z. Anorg. Allg. Chem. 2003, 629, 399-402.
13. a) H. Schumann, Angew. Chem. 1984, 96, 475-493; Angew. Chem. Int. Ed. Engl. 1984, 23, 474-492;
14. a) H. Schumann, Angew. Chem. 1984, 96, 475-493; Angew. Chem. Int. Ed. Engl. 1984, 23, 474-492;
15. b) W. J. Evans, B. L. Davis, Chem. Rev. 2002, 102, 2119-2136;
16. c) H. Schumann, J. A. Meese-Marktscheffel, L. Esser, Chem. Rev. 1995, 95, 865-986;
17. d) Cambridge Crystallographic Data Centre. 12 Union Road, Cambridge CB21EZ; Fax: (+44)1223-336-033; or deposit@ ccdc.cam.ac.uk.
18. a) W. Weyl, Pogg. Ann. 1864, 121, 601;
19. b) M. C. R. Symons, Chem. Soc. Rev. 1976, 5, 337-358.
20. a) D. S. Thompson, E. E. Hazen, J. S. Waugh, J. Chem. Phys. 1966, 44, 2954-2958;
21. b) R. Navaneethakrishnan, J. C. Warf, Inorg. Chem. 1976, 15, 2849-2852.
22. K. Müller-Buschbaum, Z. Anorg. Allg. Chem. 2004, 630, 895-899.
23. a) G. B. Deacon, A. Gitlits, P. W. Roesky, M. R. Bürgstein, K. C. Lim, B. W. Skelton, A. H. White, Chem. Eur. J. 2001, 7, 127-138;
24. b) K. Müller-Buschbaum, Z. Anorg. Allg. Chem. 2002, 628, 2731-2737;
25. c) K. Müller-Buschbaum, C. C. Quitmann, Inorg. Chem. 2003, 42, 2742-2751;
26. d) K. Müller-Buschbaum, C. C. Quitmann, Z. Anorg. Allg. Chem. 2003, 629, 1610-1616.
27. a) D. S. Thompson, M. J. Stone, J. S. Waugh, J. Phys. Chem. 1966, 70, 934-935;
28. b) H. Oesterreicher, M. Mammano, M. J. Sienko, J. Solid State Chem. 1969, 1, 10-18.
29. a) K. Müller-Buschbaum, Z. Anorg. Allg. Chem. 2003, 629, 2127-2132;
30. b) C. C. Quitmann, K. Müller-Buschbaum, unpublished results.
31. a) N. Ray, B. Hathaway, J. Chem. Soc. Dalton Trans. 1980, 1105-1111;
32. b) M.-W. Suen, Y.-Y. Wu, J.-D. Chen, T.-C. Keng, J.-C. Wang, Inorg. Chim. Acta 1999, 288, 82-89;
33. c) S. Youngme, K. Poopasit, K. Chinnakali, S. Chantrapromma, H.-K. Fun, Inorg. Chim. Acta 1999, 292, 57-63;
34. d) F. A. Cotton, L. M. Daniels, C. A. Murillo, H.-C. Zhou, Inorg. Chim. Acta 2000, 305, 69-74.
35. a) R. Kempe, H. Noss, T. Irrgang, J. Organomet. Chem. 2002, 647, 12-20;
36. b) A. Spangenberg, P. Arndt, R. Kempe, Angew. Chem. 1998, 110, 824-827; Angew. Chem. Int. Ed. Engl. 1998, 37, 832-835.
37. b) A. Spangenberg, P. Arndt, R. Kempe, Angew. Chem. 1998, 110, 824-827; Angew. Chem. Int. Ed. Engl. 1998, 37, 832-835.
38. a) T. Araki, Z Kristallogr. 1991, 194, 161-191;
39. A. L. Spek, PLATON-99, A Multipurpose Crystallographic Tool, Utrecht, 1999.
40. 3] units were disordered, with each occupying two positions, which made the use of "rigid bond" models necessary to refine the ligand positions.[21b] All non-hydrogen atoms were anisotropically refined by least-square techniques. There was no indication of a possible non-centrosymmetry of the structure or hemihedral twinning.[15] Because 1 exhibits a pseudo-hexagonal metric, powder diffraction was used to exclude the possibility that the metrics was falsely determined due to twinning. CCDC-232899 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
41. G. Meyer, M. S. Wickleder in Handbook on the Physics and Chemistry of Rare Earth, Vol. 28 (Eds.: K. A. Gschneider, L. Eyring), Elsevier, Amsterdam, 2000, chap. 177.
42. D. M. M. Freckmann, T. Dube, C. D. Berube, S. Gambarotta, G. P. A. Yap, Organometallics 2002, 21, 1240-1246.
43. 3- ion would not result in a neutral charge for this trivalent ytterbium compound (see also the Supporting Information).
44. N. Korber, personal communication.
45. a) G. M. Sheldrick, SHELXS-97, program for the determination of crystal structures, Universität Göttingen, 1997;
46. b) G. M. Sheldrick, SHELXL-97, program for the refinement of crystal structures, Universität Göttingen, 1997.