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+ which resonate at δ = -292 and +97 ppm and thus far from where they are expected without relativistic contribution.
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33
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9244244373
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3) groups of the anion (#2) had to be split over two positions and the disordered atoms were included isotropically in the refinement. Their position was fixed with restraints (SADI command). All other atoms were refined anisotropically. CCDC-228671 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.uk).
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- ion: range 145.29(19)°-149.4(2)°, 148.4(2)° (#1) and 147.2(2)° (#2) on average.
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0002874311
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z orbital at the carbenium center. The electron deficiency at S can then be removed in part by a further donation of electrons from the Br lone pair orbital to the (now only partially filled) S lone pair orbital. A similar interaction is responsible for resonance structure G, for which also no sulfur d orbital participation has to be assumed. (Diagram preseanted).
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