Bicyclo[10.10.10]dotriacontanes: The largest bicyclo[n.n.n]alkane ever known

Chemistry Letters

Volumn 33, Issue 8, 2004, Pages 1018-1019

  Kurata, Hiroyuki ^a   Rikitake, Nobuo ^a   Okumura, Akio ^a   Oda, Masaji ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANE DERIVATIVE; METHANE; NICKEL;

ARTICLE; CHEMICAL ANALYSIS; CRYSTAL STRUCTURE; REDUCTION KINETICS; STRUCTURE ANALYSIS; X RAY CRYSTALLOGRAPHY;

EID: 8844238410     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2004.1018     Document Type: Article

References (11)

1. C. H. Park and H. E. Simmons, J. Am. Chem. Soc., 94, 7184 (1972).
2. 29,32] dotriaconta-2,4,6,8,10,13,15,17,19,21,23,25,27,29,31-pentadecaene.
3. H. Kurata, H. Nakaminami, K. Matsumoto, T. Kawase, and M. Oda, J. Chem. Soc., Chem. Commun., 2001, 529.
4. H. Kurata, K. Haruki, H. Nakaminami, T. Kawase, and M. Oda, Chem. Lett., 32, 422 (2003).
5. G. R. Pettit and E. E. van Tamelen, Org. React., 12, 356 (1962).
6. H. Hauptmann and W. F. Walter, Chem. Rev., 62, 347 (1962).
7. Y. Miyahara, T. Inazu, and T. Yoshino, J. Org. Chem., 49, 1177 (1984).
8. -1.
9. 3) δ 6.73 (d, J = 3.7Hz, 6H), 6.71 (d, J = 3.7Hz, 6H), 6.49 (s, 6H), 6.28 (t, J = 2.2Hz, 2H), 6.12 (d, J = 2.2Hz, 4H), 3.74 (s, 4H), 3.59 (s, 12H).
10. 6) δ 158.42, 141.90, 109.67, 100.92, 60.39, 43.27, 39.30, 36.52, 28.69, 28.07, 22.39.
11. int = 0.139) used in refinement, R = 0.151[I > 2σ(I)], wR = 0.461, GOF =1.03.