Synthesis and crystal structure of a new microporous silicate with a mixed octahedral-tetrahedral framework: Cs3ScSi8 O19

Mineralogical Magazine

Volumn 68, Issue 4, 2004, Pages 677-686

  Kolitsch, U ^a   Tillmanns, E ^a  

^a UNIVERSITY OF VIENNA   (Austria)

Author keywords

Caesium scandium silicate (Cs3ScSi8O19); Crystal structure; Disorder; Eight membered rings; Microporous

Indexed keywords

CATALYSIS; CHARGE COUPLED DEVICES; MICROPOROUS MATERIALS; PLATES (STRUCTURAL COMPONENTS); SILICATE MINERALS; SYNTHESIS (CHEMICAL);

CATIONIC CONDUCTIVITY; EIGHT-MEMBERED RINGS; MICROPOROUS SILICATE;

CRYSTAL STRUCTURE;

CESIUM; CRYSTAL STRUCTURE; MINERAL SYNTHESIS; NEW MINERAL; SCANDIUM; SILICATE;

EID: 8744285551     PISSN: 0026461X     EISSN: None     Source Type: Journal    
DOI: 10.1180/0026461046840212     Document Type: Article

References (42)

1. 9, a new infrared emitter. Chemistry of Materials, 14, 1767-1772.
2. Anderson, M.W. and Rocha, J. (2002) Synthesis of titanosilicates and related materials. Pp. 876-903 in: Handbook of Porous Solids, Vol. 2 (F. Schüth, K.S.W. Sing and J. Weitkamp, editors), John Wiley & Sons, Ltd, New York.
3. Baur, W.H. (1981) Interatomic distance predictions for computer simulation of crystal structures. Pp. 31-52 in: Structure and Bonding in Crystals, Vol. II (M. O'Keeffe and A. Navrotsky, editors), Academic Press, New York.
4. 2O and its protonated phases. Chemistry of Materials, 12, 294-305.
5. Brese, N.E. and O'Keeffe, M. (1991) Bond-valence parameters for solids. Acta Crystallographica, B47, 192-197.
6. Brown, I.D. (1996) VALENCE: a program for calculating bond valences. Journal of Applied Crystallography, 29, 479-480.
7. 2O-type ion exchangers. Journal of Molecular Structure, 470, 207-213.
8. 2O determined ab initio from powder diffraction data. European Journal of Solid State and Inorganic Chemistry, 34, 381-390.
9. 18). Kristallografiya, 33, 1122-1127 (in Russian).
10. 12. Russian Journal of Coordination Chemistry, 23, 422-431.
11. Fischer, R.X. and Tillmanns, E. (1988) The equivalent isotropic displacement factor. Acta Crystallographica, C44, 775-776.
12. 15. Journal of Solid State Chemistry, 131, 38-42.
13. 2O, from three localities and its relation to other silicates with dreier double layers. Zeitschrift für Kristallographie, 199, 25-48.
14. Huang, J., Wang, X., Liu, L. and Jacobson, A.J. (2002) Synthesis and characterization of an open framework vanadium silicate (VSH-16Na). Solid State Sciences, 4, 1193-1198.
15. 2O). Neorganicheskie Materialy, 29, 971-975 (in Russian).
16. Ilyushin, G.D. and Blatov, V.A. (2002) Crystal chemistry of zirconosilicates and their analogs: topological classification of MT frameworks and suprapolyhedral invariants. Acta Crystallographica, B58, 198-218.
17. 4 tetrahedra. Chemical Communications, 1999, 411-412.
18. 5, an entropy-stabilized pseudobrookite-type compound. Acta Crystallographica, E59, i36-i39.
19. 12. Acta Crystallographica, E59 i43-i46.
20. 3: substitutional disorder on three (Li,Sc sites. Acta Crystallographica, E59, i55-i58.
21. 7 group. Zeitschrift für Kristallographie, Supplement No. 20, 139.
22. 10. European Journal of Mineralogy, 16, 143-149.
23. Liebau, F. (1985) Structural Chemistry of Silicates. Springer, Berlin.
24. Lin, Z., Rocha, J., Brandao, P., Ferreira, A., Esculcas, A.P., Pedrosa de Jesus, J.D., Philippou, A. and Anderson, M.W. (1997) Synthesis and structural characterization of microporous umbite, penkvilksite, and other titanosilicates. Journal of Physical Chemistry, B101, 7114-7120.
25. Lin, Z., Rocha, J., Ferreira, P., Thursfield, A., Agger, J.R. and Anderson, M.W. (1999a) Synthesis and structural characterization of microporous framework zirconium silicates. Journal of Physical Chemistry, B103, 957-963.
26. Lin, Z., Rocha, J. and Valente, A. (1999b) Synthesis and characterisation of a framework microporous stannosilicate. Chemical Communications, 1999, 2489-2490.
27. 13. Doklady Akademii Nauk SSSR, 251, 98-102 (in Russian).
28. 12. Doklady Akademii Nauk SSSR, 240, 81-84 (in Russian).
29. 12. Doklady Akademii Nauk SSSR, 255, 577-582 (in Russian).
30. Nyfeler, D. and Armbruster, T. (1997) Silanol groups in minerals and inorganic compounds. American Mineralogist, 83, 119-125.
31. 15 (SNL-A). Chemistry of Materials, 12, 3449-3458.
32. Nyman, M., Gu, B.X., Wang, L.M., Ewing, R.C. and Nenoff, T.M. (2000b) Synthesis and characterization of a new microporous cesium silicotitanate (SNL-B) molecular sieve. Microporous and Mesoporous Materials, 40, 115-125.
33. 15; A - K, Rb, Cs). Chemistry of Materials, 13, 4603-4611.
34. Otwinowski, Z. and Minor, W. (1997) Processing of X-ray diffraction data collected in oscillation mode. Methods in Enzymology, 276, 307-326.
35. 2O and its ion-exchanged phases with Na and Cs. Inorganic Chemistry, 36 3072-3079.
36. Rocha, J. and Anderson, M.W. (2000) Microporous titanosilicates and other novel mixed octahedral-tetrahedral framework oxides. European Journal of Inorganic Chemistry, 2000, 801-818.
37. Shape Software (1999) ATOMS for Windows and Macintosh V5.0.4. Kingsport, TN 37663, USA.
38. Sheldrick, G.M. (1997a) SHELXS-97, a program for the solution of crystal structures. University of Göttingen, Germany.
39. Sheldrick, G.M. (1997b) SHELXL-97, a program for crystal structure refinement. University of Göttingen, Germany.
40. 2O. Microporous and Mesoporous Materials, 32, 287-296.
41. 7 (RE = Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu). Journal of Solid State Chemistry, 170 203-210.
42. Zhao, Y.-N., Li, Y.-F., Zou, Y.-C., Mai, Z.-H. and Pang, W.-Q. (2002) Synthesis and characterization of titanosilicate with the structure of umbite. Chemical Research in Chinese Universities, 18, 380-384.