Synthesis and crystal structure of two dimeric cadmium(II) complexes bonded with pseudohalides, 1.1 and 1.3 bonding

Zeitschrift fur Kristallographie

Volumn 219, Issue 5, 2004, Pages 295-299

  Ercan, Filiz ^a   Arici, Cengiz ^a   Ülkü, Dinçer ^a   Kurtaran, Raif ^b   Aksu, Mecit ^c   Atakol, Orhan ^d  

^a HACETTEPE UNIVERSITY   (Turkey)

^b BALIKESIR UNIVERSITY   (Turkey)

^c ERCIYES UNIVERSITY   (Turkey)

^d ANKARA UNIVERSITY   (Turkey)

Author keywords

Azide bridge; Cd(II) complex; Cyanate; Dmpp ligand; Single crystal structure analysis; Thiocyanate; X ray diffraction

Indexed keywords

1,1 DIMETHYL 4 PHENYLPIPERAZINIUM; AZIDE; BRIDGED COMPOUND; CADMIUM; CYANIC ACID; DIMER; HALIDE; LIGAND; METAL COMPLEX; PSEUDOHALIDE; SOLVENT; THIOCYANATE; UNCLASSIFIED DRUG;

ARTICLE; BOND DISTANCE; CHEMICAL BOND; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; OCTAHEDRON; QUANTUM CHEMISTRY; SINGLE CRYSTAL STRUCTURE ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 8744250990     PISSN: 00442968     EISSN: None     Source Type: Journal    
DOI: 10.1524/zkri.219.5.295.32745     Document Type: Article

References (25)

1. Jameson, D. L.; Goldsby, K. A.: 2,6-bis(pyrazolyl)pyridines: The convenient Synthesis of a Family of planar Tridentate N3 ligands That are Terpyridine Analogues. J. Org. Chem. 55 (1990) 4992-4994.
2. Bessel, C. A.; See, R. F.; Jameson, D. L.; Churchill, M. R.; Takeuchi, K. J.: Synthesis and Characterization of Ruthenium Complexes which utilize a New Family of Terdentate Ligands based upon 2,6-Bis(pyrazol-1-yl)pyridine. J. Chem. Soc. Dalton Trans. (1993) 1563-1576.
3. Blake, A. J.; Hill, S. J.; Hubberstey, P.: Unique cationic, neutral and anionic copper(II) nitrite species in a single compound. Chem. Commun. (1998) 1587-1588.
4. Catalano, V. J.; Kurtaran, R.; Heck, R. A.; Öhman, A.; Hill, M. G.: Bdmpp complexes of Ru(II) as Structural analogs for, Ru(II)-2,2′: 6″-terpyridine species. Inorg. Chimica Acta 286 (1999) 181-188.
5. Manikandan, P.; Thomas, K. R. J.; Manoharan, P. T: [2,6-bis(3,5- dimethylpyrazol-1-yl-methyl-κN2)pyridine-κkN]bis(thiocyanato-N) copper(II). Acta Cryst. C56 (2000) 308-309.
6. Charlot, M. F.; Kahn, O.; Chaillet, M.; Larriev, C.: Interaction between copper(II) ons through the acido bridge. J. Am. Chem. Soc. 108 (1986) 2574-2581.
7. Goher, M. A. S.; Escuer, A.; Mautner, F. A.; Al-Salem, N. A.: Synthesis, Spectral, Magnetic and Crystal Structural chracterization of two new copper(II) azido complexes. Polyhedron 20 (2001) 2971-2977.
8. 2O. Inorganica Chimica Acta 324 (2001) 117-122.
9. Julve, M.; Verdaguer, M.; De Munno, G.; Real, J. A.; Bruno, G.: Synthesis, Crystal Structure and Magnetic Properties of (μ-Bipyrimidine) (cyanato)copper(II) and thiocyanato copper(II) complexes. Inorg. Chem. 32 (1993) 795-802.
10. n. J. Chem. Soc. Dalton Trans. (2000) 79-84.
11. 3, a Ferromagnetically coupled Dimer. Inorg. Chem. 37 (1988) 5978-5982.
12. Diaz, C.; Ribas, J.; Sanz, N.; Solans, X.; Bardia, M. F.: Synthesis, Crystal Structure and Magnetic Properties of catena-poly [(2,2′- bipyridilcopper)-di-μ-thiocyanato] and bis (2,2′-bipyridil)thiocyanato copper(II) perchlorate. Inorganica Chimica Acta 286 (1999) 169-174.
13. Ribas, J.; Escuer, A.; Monfort, M.; Vicente, R.; Cortes, R.; Lezama, L.; Rojo, T.: Polynuclear NiII and MnII azido bridging complexes, Structural trend and Magnetic Behaviour. Coord. Chem. Rev. 193 (1999) 1027-1068.
14. Mondal, A.; Mostafa, G.; Ghosh, A.; Laskar, I. R.; Chaudhuri, N. R.: Construction of a unique three-dimensional array with cadmium(II). J. Chem. Soc. Dalton Trans. (1999) 9-10.
15. Mostafa, G.; Mondal, A.; Laskar, I. R.; Welch, A. J.; Chaudhuri, N. R.: A three-dimensional network of cadmium. Acta Cryst. C56 (2000) 146-148.
16. Barandika, M. G.; Cortes, R.; Lezama, L.; Urtiga, M. K.; Amtortua, M. I.; Rojo, T.: Synthesis and magnetostructural characterization of two Ferromagnetic nickel(II) dimers. J. Chem. Soc. Dalton Trans. (1999) 2971-2976.
17. Razzak, I. A.; Kun. Fun, H.; Chinnakal, K.; Raj, S. S. S.; Liu, J. C.; You, X. Z.: Di-μ-azido-bis{[2-(2-aminoethyl)pyridine-N,N′]aqua copper(II)} diperchlorate, Acta Cryst. C55 (1999) 1764-1766.
18. Parker, O. J.; Wolther, M. P.; Breneman, G. L.: Di-μ- isocyanatobis[isocyanato(1,10-phenontroline)copper(II)]. Acta Cryst. C52 (1996) 1089-1091.
19. Enraf Nonius: Cad-4 Express Version 1.1. Delft, The Netherlands, 1993.
20. Sheldrick, G. M.: SHELXS97 and SHELXL97. Program for Crystal Structure Solution and Refinement, University of Göttingen. Germany 1997.
21. Farrugia, L. J.: WinGX.Program for Crystallography package. J. Appl. Cryst. 32 (1999) 837.
22. Spek, A. L.: PLATON. Program for Crystal Molecular Drawing. University of Ultrech, The Netherlands 2000.
23. Ercan, F.; Ülkü, D.; Atakol, O.; Dinçer, F. N.: Bis {(μ-acetato)[μ-bis(salicylidene)-1,3-propanediaminato] copper(II)} cadmium(II) Dioxane Solvent. Acta Cryst. C54 (1998) 1787-1790.
24. Atakol, O.; Aksu, M.; Ercan, F.; Arici, C.; Tahir, M. N.; Ülkü, D.: A linear Trinuclear CdII-CdII-CdII complex with a μ-acetato bridge. Acta Cryst. C55 (1999) 1072-1075.
25. Pearson, R. G.: Absolute Electronegativity and Hardness: Application to Inorganic Chemistry. Inorg. Chem. 27 (1988) 734-740.