Determination of masked mycotoxins using HPLC–tandem mass spectrometry

Mycotoxins and phycotoxins: Advances in determination, toxicology and exposure management

Volumn , Issue , 2023, Pages 125-132

  Berthiller, F ^a   Schuhmacher, R ^a   Poppenberger, B ^a   Lucyshyn, D ^a   Lemmens, M ^a   Adam, G ^a   Krska, R ^a  

^a UNIVERSITY OF NATURAL RESOURCES AND LIFE SCIENCES   (Austria)

Author keywords

Conjugated mycotoxins; Deoxynivalenol; Deoxynivalenol 3 D glucopyranoside; Liquid chromatography; Masked mycotoxins; Tandem mass spectrometry; Zearalenone; Zearalenone 4 sulfate; Zearalenone 4 D glucopyranoside

Indexed keywords

EID: 85200312442     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.3920/9789086865857_013     Document Type: Chapter

References (16)

1. Berthiller, F., Schuhmacher, R., Buttinger, G., Freudenschuss, G., Adam, G., and Krska, R., 2003. Synthesis of Deoxynivalenol-glucosides and their Characterization using a QTrap LC-MS/MS. Mycotoxin Research 19: 47-50.
2. Dall’Asta, C., Berthiller, F., Schuhmacher, R., Adam, G., Lemmens, M., and Krska, R., 2004. DON-Glycosides: Characterisation of Synthesis Products and Screening for their Occurrence in DON-treated Wheat Samples. Mycotoxin Research (in press)
3. Engelhardt, G., Ruhland, M., and Wallnöfer, P.R., 1999. Metabolism of mycotoxins in plants. Advanced Food Science 21: 71-78.
4. Engelhardt, G., Zill, G., Wohner, B., and Wallnöfer, P.R., 1988. Transformation of the Fusarium mycotoxin zearalenone in maize cell suspension cultures. Naturwissenschaften 75: 309-310.
5. Gareis, M., 1994. Maskierte Mykotoxine. Übersichten zur Tierernährung 22: 104-113.
6. Gareis, M., Bauer, J., Thiem, J., Plank, G., Grabley, S., and Gedek, B., 1990. Cleavage of zearalenone-glycoside, a „masked“ mycotoxin, during digestion in swine. Journal of Veterinary Medicine B 37:236-240.
7. Grabley, S., Gareis, M., Böckers, W., Thiem, J., 1992. Glycosylation of Mycotoxins. Synthesis 11: 1078-1080
8. Kamimura, H., 1986. Conversion of zearalenone to zearalenone glycoside by Rhizopus sp. Applied and Environmental Microbiology 52: 515-519.
9. Mirocha, C.J., Pathre, S.V., and Robison, T.S., 1981. Comparative metabolism of zearalenone and transmission into bovine milk. Food and cosmetics toxicology 19: 25-30.
10. Plasencia, J., and Mirocha, C.J., 1991. Isolation and characterization of zearalenone sulfate. Applied and Environmental Microbiology 57: 146-150.
11. Poppenberger, B., Berthiller, F., Lucyshyn, D., Sieberer, T., Schuhmacher, R., Krska, R., Kuchler, K., Glössl, J., Luschnig, C., and Adam, G., 2003. Detoxification of the Fusarium Mycotoxin Deoxynivalenol by an UDPglucosyltransferase from Arabidopsis thaliana. Journal of Biological Chemistry 278: 47905-47914.
12. Savard, M.E., 1991. Deoxynivalenol fatty acid and glucoside conjugates. Journal of Agricultural and Food Chemistry 39: 570-574.
13. Scharnhorst, K., 2003. Nachweis von Zearalenon und dem Metaboliten Zearalenon-4-O-β-Glukosid in Mais und Maisprodukten. Diploma Thesis, Universität für Bodenkultur Wien und Technische Universität Wien, pp. 1-62.
14. Schneweis, I., Meyer, K., Engelhardt, G., and Bauer, J., 2002. Occurrence of zearalenone-4-β-D-glucopyranoside in wheat. Journal of Agricultural and Food Chemistry 50: 1736-1738.
15. Sewald, N., Lepschy von Gleissenthall, J., Schuster, M., Müller, G., and Aplin, R.T., 1992. Structure elucidation of a plant metabolite of 4-desoxynivalenol. Tetrahedron 3: 953-960.
16. Young, J.C., Fulcher, R.G., Hayhoe, J.H., Scott, P.M., and Dexter, J.E., 1984. Effect of milling and baking on deoxynivalenol (vomitoxin) content of Eastern Canadian wheats. Journal of Agricultural and Food Chemistry 32: 659-664.