Chemical Properties

The Lipid Handbook with CD-ROM, Third Edition

Volumn , Issue , 2007, Pages 535-590

  Knothe, G ^a   Kenar, J A ^a   Gunstone, Frank D ^b  

^a NATIONAL CENTER FOR AGRICULTURAL UTILIZATION RESEARCH   (United States)

^b UNIVERSITY OF ST ANDREWS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 85128060941     PISSN: None     EISSN: None     Source Type: Book    
DOI: None     Document Type: Chapter

References (25)

1. Bahrmann, H. et al. 2-Ethylhexanol, in Ullmann’s Encyclopedia of Industrial Chemistry, 6th ed., Wiley-VCH, Weinheim, Germany; online version, 2001.
2. Behr, A. and Brehme, V.A., Homogeneous and heterogeneous catalyzed three-step synthesis of 2-ethylheptanoic acid from carbon dioxide, butadiene and hydrogen, J. Molec. Catal. A, 187, 69-80, 2002.
3. Behr, A. and Döring, N., Synthesis of branched fatty acids by catalytic oxidation of alcohols. (Herstellung verzweigter Fettsäuren durch katalytische Oxidation von Alkoholen.), Fat Sci. Technol., 94, 13-18, 1992.
4. Burk, P.L. et al. The rhodium-promoted Guerbet reaction. Part I. Higher alcohols from lower alcohols, J. Mol. Catal., 33, 1-14, 1985a.
5. Burk, PL. et al. The rhodium-promoted Guerbet reaction. Part II. Secondary alcohols and methanol as substrates, J. Mol. Catal., 33, 15-21, 1985b.
6. Carlini, C. et al. Selective synthesis of isobutanol by means of the Guerbet reaction. Part 1. Methanol/n-propanol condensation by using copper based catalytic systems, J. Mol. Catal. A: Chem., 184, 273-280, 2002.
7. Carlini, C. et al. Selective synthesis of isobutanol by means of the Guerbet reaction. Part 3. Methanol/n-propanol condensation by using bifunctional catalytic systems based on nickel, rhodium, and ruthenium species with basic components, J. Molec. Catal. A: Chem., 206, 409-418, 2003a.
8. Carlini, C. et al. Selective synthesis of isobutanol by means of the guerbet condensation of methanol with n-propanol in the presence of heterogeneous and homogeneous palladium-based catalytic systems, J. Molec. Catal. A: Chem., 204-205, 721-728, 2003b.
9. Carlini, C. et al. Selective synthesis of isobutanol by means of the Guerbet reaction. Part 2. Reaction of methanol/ethanol and methanol/ethanol/n-propanol mixtures over copper based/MeONa catalytic systems, J. Molec. Catal. A: Chem., 200, 137-146, 2003c.
10. Carlini, C. et al. Guerbet condensation of methanol with n-propanol to isobutyl alcohol over heterogeneous copper chromite/Mg-Al mixed oxides catalysts, J. Molec. Catal. A: Chem., 220, 215-220, 2004.
11. Carlini, C. et al. Guerbet condensation of methanol with n-propanol to isobutyl alcohol over heterogeneous bifunctional catalysts based on Mg-Al mixed oxides partially substituted by different metal components, J. Molec. Catal. A: Chem., 232, 13-20, 2005.
12. Gast, L.E. et al. Reactions of unsaturated fatty alcohols. VI. Guerbet reaction of soybean and linseed alcohols, J. Am. Oil Chem. Soc., 35, 703-707, 1958.
13. Guerbet, M., Action de l’alcool amylique de fermentation sur dérivé sodé, Comptes rendus, 128, 511-513, 1899.
14. Kenar, J.A. et al. Synthesis and characterization of dialkyl carbonates prepared from mid-, long-chain, and Guerbet alcohols, J. Am. Oil Chem. Soc., 81, 285-291, 2004.
15. Kenar, J.A. et al. Physical properties of oleochemical carbonates, J Am. Oil Chem. Soc., 82, 201-205, 2005.
16. Knothe, G. and Carlson, K.D., Synthesis, mass spectrometry, and nuclear magnetic resonance characterization of di-Guerbet esters, J. Am. Oil Chem. Soc., 75, 1861-1866, 1998.
17. Knothe, G., Characterization of esters of fatty acids and dicar-boxylic acids with Guerbet alcohols, J. Am. Oil Chem. Soc., 78, 537-540, 2001.
18. Knothe, G., Synthesis, applications, and characterization of Guerbet compounds and their derivatives, Lipid Technol., 14, 101-104, 2002.
19. Krause, H.-J. and Syldatk, A., Neue Tenside aus gemischten Guerbet-Alkoholen, Fette, Seifen, Anstrichm., 87, 386-390, 1985.
20. Markownikoff, W. and Zuboff, P., Ueber die Condensation höherer Alkohole: Tricaprylalkohol, Chem. Ber., 34, 3246-3249, 1901.
21. Miller, R.E., The Guerbet reaction. I. The reaction of amines under guerbet conditions, J. Org. Chem., 25, 2126-2128, 1960.
22. O’Lenick, A.J., Guerbet chemistry, J. Surfact. Deterg., 4, 311-315, 2001.
23. Sulzbacher, M., The Guerbet reaction of cetyl alcohol, J. Appl. Chem., 5, 637-641, 1955.
24. Ueda, W et al. A low-pressure Guerbet reaction over magnesium oxide catalyst, J. Chem. Soc., Chem. Commun., 1558-1559, 1990.
25. Veibel, S. and Nielsen, J.I., On the mechanism of the Guerbet reaction, Tetrahedron 23, 1723-1733, 1967