A new coating method for alleviating surface degradation of LiNi0.6Co0.2Mn0.2O2 cathode material: Nanoscale surface treatment of primary particles

Nano Letters

Volumn 15, Issue 3, 2015, Pages 2111-2119

  Kim, Hyejung ^a   Kim, Min Gyu ^b   Jeong, Hu Young ^a   Nam, Haisol ^a   Cho, Jaephil ^a  

^a Ulsan National Institute of Science and Technology   (South Korea)

^b Pohang University of Science and Technology (POSTECH)   (South Korea)

Author keywords

high voltage; LiNi0.6Co0.2Mn0.2O2 cathode; microcrack; primary particles; structural degradation; thermal stability

Indexed keywords

CATHODE MATERIALS; CATHODES; COBALT COMPOUNDS; DETERIORATION; LITHIUM COMPOUNDS; MANGANESE COMPOUNDS; MICROCRACKING; MICROCRACKS; NANOSTRUCTURED MATERIALS; NICKEL COMPOUNDS; OXYGEN; THERMODYNAMIC STABILITY;

ELEVATED TEMPERATURE; HIGH VOLTAGE; NANOSCALE THICKNESS; PRIMARY PARTICLES; SECONDARY PARTICLES; STRUCTURAL DEGRADATION; SURFACE DEGRADATION; THERMAL INSTABILITIES;

SURFACE TREATMENT;

EID: 85103305605     PISSN: 15306984     EISSN: 15306992     Source Type: Journal    
DOI: 10.1021/acs.nanolett.5b00045     Document Type: Article

References (33)

1. Bruno, S.; Jürgen, G. J. Power Sources 2010, 195, 2419-2430
2. Arai, H. Solid State Ionics 1998, 109, 295-302
3. Feng, L.; Isaac, M. M.; Dennis, N.; Tsu-Chien, W.; Mark, D. A.; Huolin, L. X.; Marca, M. D. Nat. Commun. 2014, 5, 3529
4. Jung, S.-K.; Gwon, H.; Hong, J.; Park, K.-Y.; Seo, D.-H.; Kim, H.; Hyun, J.; Yang, W.; Kang, K. Adv. Energy Mater. 2013, 16931-16940
5. Nam, K. W.; Bak, S. M.; Hu, E.; Yu, X.; Zhou, Y.; Wang, X.; Wu, L.; Zhu, Y.; Chung, K. Y.; Yang, X. Q. Adv. Funct. Mater. 2013, 23 (8) 1047-1063
6. Gu, M.; Belharouak, I.; Zheng, J.; Wu, H.; Xiao, J.; Genc, A.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J.-G.; Browning, N. D.; Liu, J.; Wang, C. ACS Nano 2012, 7 (1) 760-767
7. Kaoru, D. Electrochem. Solid-State Lett. 1999, 3, 125-127
8. Kleiner, K.; Dixon, D.; Jakes, P.; Melke, J.; Yavuz, M.; Roth, C.; Nikolowski, K.; Liebau, V.; Ehrenberg, H. J. Power Sources 2015, 273 (0) 70-82
9. Haifeng, W. J. Electrochem. Soc. 1999, 146, 473-480
10. Watanabe, S.; Kinoshita, M.; Hosokawa, T.; Morigaki, K.; Nakura, K. J. Power Sources 2014, 258 (0) 210-217
11. Kim, M. G.; Cho, J. J. Mater. Chem. 2008, 18, 5880-5887
12. Lee, S. M.; Oh, S. H.; Ahn, J. P.; Cho, W. I.; Jang, H. J. Power Sources 2006, 159, 1334-1339
13. Cho, J.; Kim, T.-J.; Kim, Y.-J.; Park, B. Electrochem. Solid-State Lett. 2001, 4, A159-A161
14. Yonghyun, C.; Sanghan, L.; Yongseok, L.; Taeeun, H.; Jaephil, C. Adv. Energy Mater. 2011, 1, 821-828
15. Miller, D. J.; Proff, C.; Wen, J. G.; Abraham, D. P.; Bareño, J. Adv. Energy Mater. 2013, 3 (8) 1098-1103
16. Lee, E.-J.; Chen, Z.; Noh, H.-J.; Nam, S. C.; Kang, S.; Kim, D. H.; Amine, K.; Sun, Y.-K. Nano Lett. 2014, 4873-4880
17. Feng, L.; Dennis, N.; Isaac, M. M.; Tsu-Chien, W.; Huolin, L. X.; Marca, M. D. Energy Environ. Sci. 2014, 7, 3077-3085
18. Lee, H.; Kim, Y.; Hong, Y.-S.; Kim, Y.; Kim, M. G.; Shin, N.-S.; Cho, J. J. Electrochem. Soc. 2006, 153, A781-A786
19. Meng, X.; Yang, X.-Q.; Sun, X. Adv. Mater. 2012, 24 (27) 3589-3615
20. Guo-Rong, H.; Xin-Rong, D.; Zhong-Dong, P.; Ke, D. Electrochim. Acta 2008, 53, 2567-2573
21. Cho, Y.; Oh, P.; Cho, J. Nano Lett. 2013, 13 (3) 1145-52
22. Sun, Y.-K.; Chen, Z.; Noh, H.-J.; Lee, D.-J.; Jung, H.-G.; Ren, Y.; Wang, S.; Yoon, C. S.; Myung, S.-T.; Amine, K. Nat. Mater. 2012, 11 (11) 942-947
23. Rougier, A.; Saadoune, I.; Gravereau, P.; Willmann, P.; Delmas, C. Solid State Ionics 1996, 90, 83-90
24. Laffont, L.; Gibot, P. Mater. Charact. 2010, 61 (11) 1268-1273
25. Rask, J. H.; Miner, B. A.; Buseck, P. R. Ultramicroscopy 1987, 21 (4) 321-326
26. Boulineau, A.; Simonin, L.; Colin, J.-F.; Canévet, E.; Daniel, L.; Patoux, S. Chem. Mater. 2012, 24 (18) 3558-3566
27. Gu, M.; Genc, A.; Belharouak, I.; Wang, D.; Amine, K.; Thevuthasan, S.; Baer, D. R.; Zhang, J. G.; Browning, N. D.; Liu, J.; Wang, C. Chem. Mater. 2013, 25 (11) 2319-2326
28. Shaju, K.; Subba, G.; Chowdari, B. Electrochim. Acta 2002, 145-151
29. Chevrier, V.; Ong, S.; Armiento, R.; Chan, M.; Ceder, G. Phys. Rev. B 2010, 82 (7) 075122
30. Shao-Horn, Y. Understanding Phase Transformations in Lithium Battery Materials by Transmission Electron Microscopy. In Lithium Batteries; Nazri, G.-A.; Pistoia, G., Eds.; Springer: New York, 2003; pp 478-506.
31. Lee, J.; Urban, A.; Li, X.; Su, D.; Hautier, G.; Ceder, G. Science 2014, 343 (6170) 519-522
32. Nam, K.-W.; Bak, S.-M.; Hu, E.; Yu, X.; Zhou, Y.; Wang, X.; Wu, L.; Zhu, Y.; Chung, K.-Y.; Yang, X.-Q. Adv. Funct. Mater. 2013, 23 (8) 1047-1063
33. Noh, M.; Cho, J. J. Electrochem. Soc. 2013, 160 (1) A105-A111