Modeling the viscosity and conversion of in-situ polymerizing PBT using empirical data

ICCM International Conferences on Composite Materials

Volumn , Issue , 2009, Pages

  Steeg, M ^a   Mitschang, P ^a   Chakraborty, P ^a   Hartmann, T ^b  

^a INSTITUT FÜR VERBUNDWERKSTOFFE GMBH   (Germany)

^b Cyclics Europe GmbH   (Germany)

Author keywords

CBT ; Conversion; Cyclic Butylene Terephthalate; Dielectric analysis; GPC; Isothermal modeling; Kinetics; Manufacturing; Modeling; Non isothermal modeling; PBT; Polymer matrix composites; Reactive polymer; Rheology; Thermoplastic FRPC; Viscosity

Indexed keywords

BUTENES; ENZYME KINETICS; FUNCTIONAL POLYMERS; GLASS CERAMICS; ISOTHERMS; MANUFACTURE; MATRIX ALGEBRA; MODELS; REINFORCED PLASTICS; RHEOLOGY; SHIP CONVERSION; VISCOSITY;

CONTINUOUS FIBERS; CYCLE TIME; CYCLIC BUTYLENE TEREPHTHALATES; DIELECTRIC ANALYSIS; EMPIRICAL DATA; ISOTHERMAL MODELING; NON-ISOTHERMAL MODELS; TEXTILE STRUCTURES;

POLYMER MATRIX COMPOSITES;

COMPOSITES; DATA PROCESSING; DIELECTRICS; ISOTHERMAL PROCESS; KINETICS; MATHEMATICAL MODELS; POLYMERS; REINFORCED PLASTIC; RHEOLOGY; TEXTILES; THERMOPLASTICS; VISCOSITY;

EID: 85076868737     PISSN: None     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Conference Paper

References (22)

1. Neitzel M, Mitschang P. Handbuch Verbundwerkstoffe. München/Wien: Carl Hanser Verlag, 2004.
2. Mayer C, Wang X, Neitzel M. Macro-and micro-impregnation phenomena in continuous manufacturing of fabric reinforced thermoplastic composites. Composites Part A: Applied Science and Manufacturing 1998;29(7):783-793.
3. Mayer C, Wang X, Neitzel M. Polymer flow and impregnation in continuous manufacturing of textile reinforced thermoplastic composites. Composites Part A: Applied Science and Manufacturing 1998;29(7):783-793.
4. Ishak ZAM, Leong YW, Steeg M, et al. Mechanical properties of woven glass fabric reinforced in situ polymerized poly(butylene terephthalate) composites. Composites Science and Technology 2007;67(3-4):390-398.
5. Steeg M. Polymer Composites with In Situ Polymerized Cyclic Butylene Terephthalates (CBT™) -Promising Materials for Automotive Applications. In: Proceedings of PMA 2007 & 19th SRC 2007. Bratislava, May, 2007. p.1-12.
6. Mitschang P, Rösch M, Steeg M. New Manufacturing Opportunities of Fiber-Reinforced Thermoplastic Composites by Ultra Liquid Ring-Opening Oligomers. In: Proceedings of the 6th Canadian-International Composite Conference. Winnipeg, August, 2007.
7. Brunelle DJ. Cyclic Oligomer Chemistry. Journal of Applied Polymer Science: Part A: Polymer Chemistry 2008;46:1151-1164.
8. Rosso P, Friedrich K, Wollny A, et al. A novel polyamide 12 polymerization system and its use for a LCM-process to produce CFRP. Journal of Thermoplastic Composite Materials 2005;18(1):77-90.
9. Ishak ZAM, Gatos KG, Karger-Kocsis J. On the in-situ polymerization of cyclic butylene terephthalate oligomers: DSC and rheological studies. Polymer Engineering and Science 2006;46(6):743-750.
10. van Rijswijk K, Bersee HEN. Reactive processing of textile fiber-reinforced thermoplastic composites -An overview. Composites Part A: Applied Science and Manufacturing 2007;38(3):666-681.
11. Luisier A, Bourban PE, Månson JAE. Time-temperature-transformation diagram for reactive processing of polyamide 12. Journal of Applied Polymer Science 2001;81(4):963-972.
12. Parton H. Characterisation of the In-situ Polymerisation Production Process for Continuous Fibre Reinforced Thermoplastics. Leuven: Faculteit Ingenieurswetenschappen, 2006.
13. Miller S. Macrocyclic Polymers from Cyclic Oligomers of Poly(Butylene Terephthalate). Massachusetts: Institute of Polymer Science and Engineering, 1998.
14. Brunelle DJ. Synthesis and Polymerization of Cyclic Polyester Oligomers. In: Scheirs J, Long TE, editor. Modern polyesters: Chemistry and Technology of Polyesters and Copolyesters. Chichester/Hoboken: John Wiley&Sons., Inc., 2003. p. 117-142.
15. Brunelle DJ, Bradt JE, Serth-Guzzo J, et al. Semicrystalline polymers via ringopening polymerization: Preparation and polymerization of alkylene phthalate cyclic oligomers. Macromolecules 1998;31(15):4782-4790.
16. Luisier A. In-situ Polymerisation of Lactam 12 for Liquid Moulding of Thermoplastic Composites. Lausanne: École Polytechnique Fédérale de Lausanne, 2001.
17. Luisier A, Bourban PE, Månson JAE. Reaction injection pultrusion of PA12 composites: Process and modelling. Composites Part A: Applied Science and Manufacturing 2003;34(7):583-595.
18. Ishak ZAM, Shang PP, Karger-Kocsis J. A modulated dsc study on the in situ polymerization of cyclic butylene terephthalate oligomers. Journal of Thermal Analysis and Calorimetry 2006;84(3):637-641.
19. Lehmann B, Karger-Kocsis J. Isothermal and Non-Isothermal Crystallisation Kinetics of pCBT and PBT Polymers. Journal of Thermal Analysis and Calorimetry 2009;95(1):221-227.
20. Harsch M, Karger-Kocsis J, Apostolov AA. Crystallization-Induced Shrinkage and Thermal Properties of In-Situ Polymerized Cyclic Butylene Terephthalate (CBT). Journal of Applied Polymer Science 2008;108(3):1455-1461.
21. Harsch M. Methoden und Ansätze zur spannungsarmen Vernetzung von Epoxidharzen. In: Prof. Dr.-Ing. Alois K.Schlarb (Hrsg.): IVW Schriftenreihe. 76. Kaiserslautern: Institut für Verbundwerkstoffe GmbH, 2008
22. Janus K, Koshets IA, Sworakowski J, et al. An approximate non-isothermal method to study kinetic processes controlled by a distribution of rate constants: the case of a photochromic azobenzene derivative dissolved in a polymer matrix. Journal of Materials Chemistry 2002;12:1657-1663.