Autoignition of dimethyl ether and dimethoxy methane sprays at high pressures

SAE Technical Papers

Volumn , Issue , 1997, Pages

  Edgar, Bradley L ^a   Dibble, Robert W ^a   Naegeli, David W ^b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b SOUTHWEST RESEARCH INSTITUTE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRACKING (CHEMICAL); DIESEL ENGINES; ETHERS; KINETICS; METHANE; METHANOL; RATE CONSTANTS; REACTION INTERMEDIATES;

AUTO-IGNITION DELAY; AUTO-IGNITION DELAY TIME; DETAILED CHEMICAL KINETIC; INDEPENDENT CONTROL; LOWER TEMPERATURES; MOLECULAR REACTIONS; PEROXIDE INTERMEDIATE; SIMULTANEOUS REDUCTION;

FUEL ADDITIVES;

EID: 85072474441     PISSN: 01487191     EISSN: 26883627     Source Type: Journal    
DOI: 10.4271/971677     Document Type: Conference Paper

References (22)

1. Aronowitz, D., and Naegeli, D. W., "High Temperature Pyrolysis of Dimethyl Ether," International Journal of Chemical Kinetics, Vol. 9, pp. 471-479, (1977).
2. Barbieri, G., "Modeling Methane Cool Flames and Ignitions," Combustion Science and Technology, Vol. 106, pp. 83-102, (1995).
3. Benson, S. W., and Jain, D. V., "Further Studies of the Pyrolysis of Dimethyl Ether," The Journal of Chemical Physics, Vol. 31, Number 4, pp. 1008-1016, (1959).
4. Benson, S. W., "Thermochemical Kinetics, 2nd Ed., Methods for the Estimation of Thermochemical Data and Rate Parameters," Wiley Interscience, John Wiley and Sons, New York, (1976).
5. Bone, W. A., and Gardner, J. B., "Comparative Studies of the Slow Combustion of Methane, Methyl Alcohol, Formaldehyde,and Formic Acid," Proceedings of the. Royal Society (London) A154, p. 297, (1936).
6. Dodge, L., and Naegeli, D. W., "Combustion Characterization of DMM in Reciprocating Engines," NREL Report # TP-425-6345, Golden, Colorado, June, (1994).
7. Hay, J. M., and Hessam, K., "The Oxidation of Gaseous Formaldehyde," Combustion and Flame, Vol. 16, pp. 237-242, (1971).
8. Hurn, R. W., and Hughes, K. J., "Combustion Characteristics of Diesel Fuels as Measured in a Constant Volume Bomb," SAE Transactions., Vol. 6, No. 1, p. 24., (1952).
9. Kapus, P. E., and Cartellieri, W. P., "ULEV Potential of a DI/TCI Diesel Passenger Car Engine Operated on Dimethyl Ether," SAE Paper 952754, (1995).
10. Kee, R. J., Rupley, F. M., and Miller, J.A, "CHEMKIN-II: A FORTRAN Chemical Kinetics Package for the Analysis of Gas-Phase Chemical Kinetics," Sandia Report No. SAND898009, (1989).
11. Kubias, O. F., and Woodworth, M. E., "Fire Hazard Properties of Flammable Liquids, Gases, and Volatile Solids," NFPA 325M, p. 130, (1977).
12. Loucks, L. F., and Laidler, K. J., "Mercury-Photosensitized Decomposition of Dimethyl Ether, Patt 11, The Thermal Decomposition of the Methoxymethyl Radical," Canadian Journal of Chemistry, Vol. 45, pp. 2767-2773, (1967).
13. Minetti, R., Carlier, M., Ribaucour, M., Therssen, E., and Sochet, L. R., "Rapid Compression Machine Investigation of Oxidation and AutoIgnition of n-Heptane: Measurements and Modeling," Combustion and Flame, Vol. 102, pp. 298-309, (1995).
14. Naber, J. D., Siebers, D. L., Di Jilio, S. S., and Westbrook, C. K., AEffects of Natural Gas Composition on Ignition Delay under Diesel Conditions," Combustion and Flame, Vol. 99, pp. 192-200, (1994).
15. Naegeli, D. W., "Kinetics of Carboxylic Acid Formation in the Combustion of Alcohols," Interim Report BFLRL No. 254, December, (1987).
16. Ryan, T. W., and Callahan, T. J., "A Correlation of Physical and Chemical lgnition Delay to Cetane Number," SAE Paper 852103, (1985).
17. Ryan, T. W., and Strapper, B., "Diesel Fuel Ignition Quality as Determined in a Constant Volume Combustion Bomb," SAE Paper 870586, February, (1987).
18. Style, D. W., and Summers, D., "Photochemical Reaction between Formaldehyde and Oxygen," Transactions of the Faraday Society, Vol. 42, p. 388, (1946).
19. Warnatz, J., Maas, U., and Dibble, R. W., "Combustion: Physical and Chemical Fundamentals, Modeling and Simulation. Experiments, Pollutant Formation," ISBN 3 540-60730-7, Springer Verlag, (1996).
20. Westbrook, C. K., Creighton, J., and Lund, C., "A Numerical Model of Chemical Kinetics of Combustion in a Turbulent Flow Reactor," Journal of Physical Chemistry, Vol. 81, p. 2542, (1977).
21. Westley, F., Frizzell, D. H., Herron, J. T., Hampson, R. F., and Mallard, W. G., "National Institute of Standards and Technology (NIST) Chemical Kinetics Database, Version 5.0," U. S. Department of Commerce, Standard Reference Data Program, Gaithersburg, MD, (1993).
22. Yu, T. C., Uyehara, O. A., Myers, P. S., Collins, R. N., and Mahadevan, K., "Physical and Chemical Ignition Delay in an Operating Diesel Engine Using the Hot-Motored Technique," SAE Transactions, Vol. 64, p. 690, (1956).