Thermodynamic mixing properties and the structure of silicate melts

Structure, Dynamics, and Properties of Silicate Melts

Volumn 32, Issue , 2019, Pages 145-189

  Hess, Paul C ^a  

^a BROWN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

MIXING PROPERTY; SILICATE MELTS;

SILICATES;

EID: 85061141988     PISSN: None     EISSN: None     Source Type: Book    
DOI: None     Document Type: Chapter

References (79)

1. Allen LC (1989) Electronegativity is the average one-electron energy of the valence-shell electrons in ground state free atoms. J Am Chem Soc 111:9003-9014
2. Allen LC (1993) Chemistry and electronegativity. Inter J Quant Chem 49:253-277
3. Araujo RJ (1983) A statistical mechanical interpretation for chemical disorder in interacting systems: Application to phase separation in alkali silicates, alkaline earth silicates and alkaline earth aluminosilicates. J Non-Cryst Solids 55:257-267
4. Barin I (1993) Thermochemical Data of Pure Substances. VCH, Germany
5. 4 Anorg Allg Chem 589:129-138
6. Blander M, Pelton AD (1987) Thermodynamic analysis of binary liquid silicates and prediction of ternary solution properties by modified quasichemical equations. Geochim Cosmochim Acta 51:85-96
7. Bockris JO'M, Tomlinson JW, White JL (1956) The structure of the liquid silicates: Partial molar volumes and expansivities. Trans Faraday Soc 52:299-311
8. Brawer SA, White WB (1977) Raman spectroscopic study of hexavalent chromium in some silicate and borate glasses. Mat Res Bull 12:281-288
9. 29Si MAS NMR study of binary alkali silicate glasses. Glast Ber 65:18-21
10. Burnett DG, Douglas RW (1970) Liquid-liquid phase separation in the soda-lime-silica system. Phys Chem Glasses 11:125-135
11. Charles RJ (1969) The origin of immiscibility in silicate solutions. Phys Chem Glasses 10:169-178
12. 4. J Non-Cryst Solids 122:10-32
13. Cotton FA, Wilkinson G (1988) Advanced Inorganic Chemistry. John Wiley, New York
14. Dent Glasser LS (1979) Nonexistent silicates. Z Kristallogr 149:291-305
15. 2 (T=Al,Fe,Ga,B). J Am Ceram Soc 73:2068-2072
16. Dickenson MP, Hess PC (1981) Redox equilibira and the structural role of iron in aluminosilicate melts. Contrib Mineral Petrol 78:352-357
17. 3-Feo melts. J Non-cryst Solids 86:303-310
18. Dickinson JE, Hess PC (1985) Rutile solubility and Ti coordination in silicate melts. Geochim Cosmochim Acta 49:2289-2296
19. Douglas RW, Nath P, Paul A (1965) Oxygen ion activity and its influence on the redox equilibrium in glasses. Phys Chem Glasses 6:216-223
20. Dowty E (1987) Vibrational interactions of tetrahedra in silicate glasses and crystals: II Calculations on melilites, pyroxenes, silica polymorphs and feldspars. Phys Chem Minerals 14:122-138
21. Duffy JA (1993) A review of optical basiscity and its application to oxidic systems. Geochim Cosmochim Acta 57:3961-3970
22. Duffy JA (1990) Bonding Energy Levels and Bands in Inorganic Solids. Longmans UK
23. Duffy J A, Ingram MD (1976) An interpretation of glass chemistry in terms of the optical basiscity concept. J Non-cryst Solids 21:373-410
24. Ellison AJ, Hess PC (1986) Solution behavior of +4 cations in high silica melts: Petrologic and geochemical implications. Contrib Mineral Petrol 94:343-351
25. Ellison AJ, Hess PC (1988) Peraluminous and peralkaline effects upon monazite solubility in high silica liquids. EOS, Trans Am Geophys Soc 69:498
26. Ellison AJ, Hess PC (1990) Lanthanides in silicate glasses: A vibrational spectroscopic study. J Geophys Res 95:15717-15,726
27. 3. J Non-crystal Solids 127:247-259
28. +4: Implications for cation solution mechanisms in multicomponent liquids. Geochim Cosmochim Acta 58:1877-1887
29. Felsche J (1973) The crystal chemistry of the rare earth silicates. In: Structure and Bonding. JD Donitz et al. (eds) 13:100-197. Springer-Verlag, New York
30. Gan H, Hess PC (1991) Modelling activity coefficients of high field strength cations: Titanium. EOS, Trans Am Geophys Soc 72:547
31. Gan H, Hess PC (1992) Phosphate speciation in potassium aluminosilicate glasses. Am Mineral 77:495-506
32. 5 glass. Geochim Cosmochim Acta 58:4633-4648
33. Gan H, Hess PC, Homg W-S, (1994b) P, Nb and Ta interactions with anyhdrous haplogranite melts. EOS, Trans Am Geophys Soc 75:369
34. Gibbs JW (1961) The scientific papers of J Willard Gibbs: Vol. I. Thermodynamics. Dover, New York
35. Gibbs GV (1982) Molecules as models for bonding in silicates. Am Mineral 67:421-450
36. Gurman SJ (1990) Bond ordering in silicate glasses: a critique and a re-solution. J Non-Cryst Solids 125:151-160
37. Gwinn R and Hess PC (1993) The role of phosphorus in rhyolitic liquids as determined by homogeneous iron redox equilibria. Contrib Mineral Petrol 113:424-435
38. Gwinn R, Hess PC (1989) Iron and titanium solution properties in peraluminous and peralkaline rhyolitic liquids. Contrib Mineral Petrol 101:326-338
39. 3 systems. Phys Chem Glasses 17:194-198
40. Haller W, Blackburn DH, Simmons JH (1974) Miscibility gaps in alkali-silicate binaries-Data and thermodynamic interpretation. J Am Ceram Soc 57:120-126
41. Hess PC (1971) Polymer model of silicate melts. Geochim Cosmochim Acta 35:289-306
42. Hess PC (1977) Structure of silicate melts. Can Mineral 15:162-178
43. Hess PC (1980) Polymerization model for silicate melts In: Physics of Magmatic Processes RB Hargraves (ed), p 1-48
44. Hess PC (1991) The role of high field strength cations in silicate melts In: Perchuk LL, Kushiro I (eds) Physical Chemistry of Magmas, Adv Geochem 9:152-191 Springer-Verlag
45. Holland, TJB (1989) Dependence of entropy on volume for silicate and oxide minerals: A review and predictive model, Am Mineral 74:5-13
46. Kilinc A, Carmichael ISE, Rivers ML, Sack RO (1983) The ferric-ferrous of natural silicate liquids equilibrated in air. Contrib Mineral Petrol 83:136-140
47. Kushiro I (1975) On the nature of silicate melt and its significance in magma genesis: Regularities in the shift of the liquidus boundaries involving olivine, pyroxene and silica minerals. Am J Sci 275:411-431
48. Levin EM, Robbins CR, McMurdie HF (1964) Phase diagrams for ceramists. Am Ceram Soc (supplement)
49. Liebau F (1985) Structural Chemistry of Silicates. Springer-Verlag, New York
50. Maekawa H, Maekawa T, Kawamura K, Yokokawa T (1991) The structural groups of alkali silicate glasses determined from 2 9Si MAS-NMR. J Non-cryst Solids 127:53-64
51. McGahay V, Tomozawa M (1989) The origin of phase separation in silicate melts and glasses J Non-Cryst Solids 109:27-34
52. 2 glasses J Non-cryst Solids 159:246-252
53. 2o-saturated conditions. Geology 14:659-662
54. Mysen BO, Ryerson FJ, Virgo D (1981) The structural role of phosphorus in silicate melts. Am Mineral 66:106-117
55. 2 solubility: Experimental results in peraluminous and peralkaline high silica glasses. EOS, Trans Am Geophys Soc 66:412
56. +6 equilibrium in binary alkali silicate glasses. Phys Chem Glasses 6:197-202
57. O'Keefe M, Hyde BG (1984) Stoichiometry and the structure and stability of inorganic solids. Nature 309:411-414
58. Paul A, Douglas RW (1965) Ferrous-ferric equilibrium in binary alkali silicate glasses. Phys Chem Glasses 6:207-211
59. Pauling L (1960) Nature of the Chemical Bond (3rd Edn) Cornell University Press, Ithaca, NY
60. Prigogine I, Defay R (1954) Chemical Thermodynamics. John Wiley, New York
61. Robie RA, Hemingway BS, Fisher JR (1979) Thermodynamic properties of minerals and related substances at 298.15 K and 1 bar pressure and at higher temperatures. U S Geol Surv Bull 1452
62. 2(M = Li,Na,K,Rb,Cs,Mg,Ca,Sr,Ba,Pb). J Am Ceram Soc 67:606-610
63. 2. Geochim Cosmochim Acta 49:921-932
64. Ryerson FJ, Hess PC (1980) The role of P2O5 in silicate melts. Geochim Cosmochim Acta 44:611-624
65. Schreiber HD, Kochanowski BK, Schreiber CW, Morgan AB, Coolbaugh MT, Dunlap TG (1994) Compositional dependence of redox equilibria in sodium siliate glasses. J Non-Cryst Solids 177:340-346
66. Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr A32:751-767
67. Shannon RD (1993) Dielectric polarizabilities of ions in oxides and fluorides. J Appl Phys 73:348-366
68. 8. Geochim Cosmochim Acta 43:61-75
69. 2 system. Phys Chem Glasses 20:41-53
70. Tomlinson JW, Heynes MSR, Bockris JO'M (1958) The structure of liquid silicates: Molar volumes and expansivities. Trans Faraday Soc 54:1822-1833
71. Toop GWE, Samis CS (1962) Some new ionic concepts of silicate slags. Can Met Quart 1:129-156
72. Toplis MJ, Dingwell DB, Libourel G (1994) The effect of phosphorous on the iron redox ratio, viscosity and density of an evolved ferrobasalt. Contrib Mineral Petrol 117:293-304
73. Toplis MJ, Libourel G, Carroll MR (1994) The role of phosphorous in crystallization processes of basalt: An experimental study. Geochim Cosmochim Acta 58:797-810
74. Varshal BG (1993) Structural model of the immiscibility of glass-forming silicate melts. Fiz Kbim Stekla 19:149-153
75. Viellard PH, Tardy Y (1988) Estimation of enthalpies of formation of minerals based on their refined crystal structures. Am J Sci 288:997-1040
76. Uchino T, Sakka T, Ogata Y, Iwasaki M (1991) Ab initio molecular orbital calculations on the electronic structure of sodium silicate glasses. J Phys Chem 95:5455-5462
77. Uchino T, Sakka T, Ogata Y, Iwasaki M (1992) Changes in the structure of alkali-metal silicate glasses with the type of network modifier cation: An ab initio molecular orbital study. J Phys Chem 96:2455-2463
78. Watson EB (1979) Zircon saturation in felsic liquids: experimental data and applications to trace element geochemistry. Contrib Mineral Petrol 70:407-419
79. Wells AF (1985) Structural Inorganic Chemistry (5th Edn) Clarendon, Oxford