Direct electrophilic insertion into a twelve-vertex metallacarborane

Angewandte Chemie - International Edition

Volumn 41, Issue 21, 2002, Pages 4112-4114

  Kudinov, Alexander R ^a   Perekalin, Dmitry S ^a   Rynin, Stanislav S ^a   Lyssenko, Konstantin A ^a   Grintselev Knyazev, Gennadii V ^a   Petrovskii, Pavel V ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

Boron; Cluster compounds; Metallacarboranes; Ruthenium

Indexed keywords

ELECTRONS; REACTION KINETICS;

POLYHEDRAL EXPANSION;

RUTHENIUM COMPOUNDS;

CARBORANE DERIVATIVE; METAL COMPLEX; METALLACARBORANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; REACTION ANALYSIS; SYNTHESIS;

EID: 85047699644     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (19)

1. R. N. Grimes in Comprehensive Organometallic Chemistry 1, Vol. 1 (Eds.: G. Wilkinson, F. G. A. Stone, E. W. Abel), Pergamon, New York, 1982, p. 459.
2. V. R. Miller, L. G. Sneddon, D. C. Beer, R. N. Grimes, J. Am. Chem. Soc. 1974, 96, 3090;
3. W. M. Maxwell, E. Sinn, R. N. Grimes, J. Am. Chem. Soc. 1976, 98, 3490;
4. M. Green, J. L. Spencer, F. G. A. Stone, J. Chem. Soc. Daton Trans. 1979, 1679, and references therein;
5. G. K. Barker, M. P. Garcia, M. Green, F. G. A. Stone, A. J. Welch, J. Chem. Soc. Chem. Commun. 1983, 137;
6. M. P. Garcia, M. Green, F. G. A. Stone, R. G. Somerville. A. J. Welch, C. E. Briant, D. N. Cox, D. M. P. Mingos. J. Chem. Soc. Dalton Trans. 1985, 2343.
7. An indirect insertion, based on two-electron reduction of closocarborane or metallacarborane with subsequent treatment of nidoanion formed with a metal electrophile, is well known. For example: a) D. F. Dustin, G. B. Dunks, M. F. Hawthorne, J. Am. Chem. Soc. 1973, 95, 1109;
8. W. J. Evans. M. F. Hawthorne, Inorg. Chem. 1974, 13, 869.
9. A. R. Kudinov, M. I. Rybinskaya, Yu. T. Struchkov, A. I. Yanovskii, P. V. Petrovskii, J. Organomet. Chem. 1987, 336, 187;
10. P. O. Lumme. U. Turpeinen, A. R. Kudinov, M. I. Rybinskaya, Acta Crystallogr. Sect. C 1990, 46, 1410.
11. R. S. Coldicott, J. D. Kennedy, M. Thornton-Pett, J. Chem. Soc. Dalton Trans. 1996, 3819.
12. C. G. Salentine, M. F. Hawthorne, Inorg. Chem. 1978, 17, 1498.
13. 2 = 0.0981 and GOF= 1.040 for all independent reflections (R1 = 0.0414 was calculated against F for 6443 observed reflections with I > 2σ(I)). All calculations were performed using SHELXTL 5.1. CCDC-188268 (PPN-1) and CCDC-188269 (2b) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB2 1EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
14. D. C. Liles, A. Shaver, E. Singleton, M. B. Wiege, J. Organomet. Chem. 1985, 288, C33.
15. R. T. Baker, Inorg. Chem. 1986, 25, 109;
16. R. L. Johnston, D. M. P. Mingos, Inorg. Chem. 1986, 25, 3321;
17. M. L. McKee, Z.-X. Wang, P. v. R. Schleyer, J. Am. Chem. Soc. 2000, 122, 4781, and references therein.
18. K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1.
19. P. W. Fowler, Polyhedron 1985, 4, 2051.