Understanding and overcoming the challenges posed by electrode/electrolyte interfaces in rechargeable magnesium batteries

Frontiers in Energy Research

Volumn 2, Issue NOV, 2014, Pages

  Mizuno, Fuminori ^a   Singh, Nikhilendra ^a   Arthur, Timothy S ^a   Fanson, Paul T ^a   Ramanathan, Mayandi ^b,c   Benmayza, Aadil ^b   Prakash, Jai ^b   Liu, Yi Sheng ^d   Glans, Per Anders ^d   Guo, Jinghua ^d  

^a Toyota Motor North America Inc   (United States)

^b Illinois Institute of Technology   (United States)

^c University of Washington   (United States)

^d LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

Anode; Electrode electrolyte interface; Intermediate species; Magnesium battery; Mg metal; Solvation desolvation process

Indexed keywords

EID: 85042816169     PISSN: None     EISSN: 2296598X     Source Type: Journal    
DOI: 10.3389/fenrg.2014.00046     Document Type: Article

References (35)

1. Armand, M., and Tarascon, J.-M. (2008). Building better batteries. Nature 451, 652-657. doi: 10.1038/451652a
2. x alloys as anodes for Mg-ion batteries. Electrochem. Commun. 16, 103-106. doi:10.1016/j.elecom.2011.12.010
3. Arthur, T. S., Glans, P.-A., Matsui, M., Zhang Ma, B., and Guo, J. (2012b). Mg deposition observed by in situ electrochemical Mg K-edge X-ray absorption spectroscopy. Electrochem. Commun. 24, 43-46. doi:10.1016/j.elecom.2012.08.018
4. 2 for magnesium battery cathode. ACS Appl. Mater. Inter. 6, 7004-7008. doi:10.1021/am5015327
5. Aurbach, D., Lu, Z., Schechter, A., Gofer, Y., Gizbar, H., Turgeman, R., et al. (2000a). Prototype systems for rechargeable magnesium batteries. Nature 407, 724-727. doi:10.1038/35037553
6. Aurbach, D., Moshkovich, M., Schechter, A., and Turgeman, R. (2000b). Magnesium deposition and dissolution processes in ethereal Grignard salt solutions using simultaneous EQCM-EIS and In situ FTIR spectroscopy. Electrochem. Solid State Lett. 3, 31-34. doi:10.1149/1.1390949
7. Aurbach, D., Schechter, A., Moshkovich, M., and Cohen, Y. (2001). On the mechanisms of reversible magnesium deposition process. J. Electrochem. Soc. 148, A1004-A1014. doi:10.1149/1.1387980
8. Aurbach, D., Suresh, G. S., Levi, E., Mitelman, A., Mizrahi, O., Chusid, O., et al. (2007). Progress in rechargeable magnesium battery technology. Adv. Mater. 19, 4260-4267. doi:10.1002/adma.200701495
9. Aurbach, D., Weissman, I., Gofer, Y., and Levi, E. (2003). Nonaqueous magnesium electrochemistry and its application in secondary batteries. Chem. Rec. 3, 61-73. doi:10.1002/tcr.10051
10. Benmayza, A., Ramanathan, M., Arthur, T. S., Matsui, M., Mizuno, F., Guo, J., et al. (2013). Effect of electrolytic properties of a magnesium organohaloaluminate electrolyte on a magnesium deposition. J. Phys. Chem. C 117, 26881-26888. doi:10.1021/jp4077068
11. 2 and Li-S batteries with high energy storage. Nat. Mater. 11, 19-29. doi:10.1038/nmat3191
12. Dunn, B., Kamath, H., and Tarascon, J.-M. (2011). Electrical energy storage for the grid: a battery of choices. Science 334, 928-935. doi:10.1126/science.1212741
13. Gofer, Y., Pour, N., and Aurbach, D. (2013). "Lithium batteries: advanced technologies and applications," in Electrolytic Solutions for Rechargeable Magnesium Batteries. eds B. Scrosati, K. M. Abraham, W. A. van Schalkwijk, and J. Hassoun (Weinheim: Wiley), 328-345.
14. Gregory, T. D., Hoffman, R. J., and Winterton, R. C. (1990). Nonaqueous electrochemistry of magnesium-applications to energy storage. J. Electrochem. Soc. 137, 775-780. doi:10.1149/1.2086553
15. Higashi, S., Miwa, K., Aoki, M., and Takechi, K. (2014). A novel inorganic solid state ion conductor for rechargeable Mg batteries. Chem. Commun. 50, 1320-1322. doi:10.1039/c3cc47097k
16. Ichitsubo, T., Adachi, T., Yagi, S., and Doi, T. (2011). Potential positive electrodes for high-voltage magnesium-ion batteries. J. Mater. Chem. 21, 11764-11772. doi:10.1039/c1jm11793a
17. Khoo, T., Somers, A., Torriero, A. A. J., MacFarlane, D. R., Howlett, P., and Forsyth, M. (2013). Discharge behaviour and interfacial properties of a magnesium battery incorporating trihexyl(tetradecyl) phosphonium based ionic liquid electrolytes. Electrochim. Acta 87, 701-708. doi:10.1016/j.electacta.2012.09.072
18. Kim, H. S., Arthur, T. S., Allred, G. D., Zajicek, J., Newman, J. G., Rodnyansky, A. E., et al. (2011). Structure and compatibility of a magnesium electrolyte with a sulphur cathode. Nat. Commun. 2, 427-432. doi:10.1038/ncomms1435
19. 2 cathode and ultrasmall Mg nanoparticle anode. Adv. Mater. 23, 640-643. doi:10.1002/adma.201003560
20. Linden, D., and Reddy, T. B. (2011). Linden's Handbook of Batteries, 4th Edn. New York: McGraw-Hill.
21. 2 : insights from first principles. Chem. Mater. 24, 3943-3951. doi:10.1021/cm302347j
22. 4 (A = Li, Na, or Mg) and its application as a rechargeable battery cathode. Chem. Mater. 25, 3062-3071. doi:10.1021/cm401250c
23. Matsui, M. (2011). Study on electrochemically deposited Mg metal. J. Power Sources 196, 7048-7055. doi:10.1016/j.jpowsour.2010.11.141
24. Mohtadi, R., Matsui, M., Arthur, T. S., and Hwang, S. J. (2012). Magnesium borohydride: from hydrogen storage to magnesium battery. Angew. Chem. Int. 51, 9780-9783. doi:10.1002/anie.201204913
25. Muldoon, J., Bucur, C. B., Oliver, A. G., Sugimoto, T., Matsui, M., Kim, H. S., et al. (2012). Electrolyte roadblocks to a magnesium rechargeable battery. Energy Environ. Sci. 5, 5941-5950. doi:10.1039/c2ee03029b
26. Novak, P., Imhof, R., and Hass, O. (1999). Magnesium insertion electrodes for rechargeable nonaqueous batteries-a competitive alternative to lithium? Electrochim. Acta 45, 351-367. doi:10.1016/S0013-4686(99)00216-9
27. Orikasa, Y., Masese, T., Mori, T., Hattori, M., Yamamoto, K., Okado, T., et al. (2014). High energy density rechargeable magnesium battery using earth-abundant and non-toxic elements. Sci. Rep. 4, 5622-5627. doi:10.1038/srep05622
28. 2 battery. Chem. Commun. 49, 9152-9154. doi:10.1039/c3cc43477j
29. Singh, N., Arthur, T. S., Ling, C., Matsui, M., and Mizuno, F. (2013). A high energy-density tin anode for rechargeable magnesium-ion batteries. Chem. Commun. 49, 149-151. doi:10.1039/c2cc34673g
30. Tarascon, J.-M., and Armand, M. (2001). Issues and challenges facing rechargeable lithium batteries. Nature 414, 359-367. doi:10.1038/35104644
31. Wang, F. F., Guo, Y. S., Yang, J., Nuli, Y., and Hirano, S. (2012). A novel electrolyte system without a Grignard reagent for rechargeable magnesium batteries. Chem. Commun. 48, 10763-10765. doi:10.1039/c2cc35857c
32. Yoo, H.-D., Shterenberg, I., Gofer, Y., Gershinsky, G., Pour, N., and Aurbach, D. (2013). Mg rechargeable batteries: an on-going challenge. Energy Environ. Sci. 6, 2265-2279. doi:10.1039/c3ee40871j
33. Yoshimoto, N., Yakushiji, S., Ishikawa, M., and Morita, M. (2003). Rechargeable magnesium batteries with polymer gel electrolytes containing magnesium salts. Electrochim. Acta 48, 2317-2322. doi:10.1016/S0013-4686(03)00221-4
34. 2 as a cathode material for rechargeable Mg batteries. Electrochem. Commun. 23, 110-113. doi:10.1016/j.elecom.2012.07.021
35. Zhao-Karger, Z., Zhao, X., Fuhr, O., and Fichtner, M. (2014). Bisamide based non-nucleophilic electrolytes for rechargeable magnesium batteries. RSC Adv. 3, 16330-16335. doi:10.1039/c3ra43206h