Structural patterns at all scales in a nonmetallic chiral Au133(SR)52 nanoparticle

Science Advances

Volumn 1, Issue 2, 2015, Pages

  Zeng, Chenjie ^a   Chen, Yuxiang ^a   Kirschbaum, Kristin ^b   Appavoo, Kannatassen ^c   Sfeir, Matthew Y ^c   Jin, Rongchao ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

^b UNIVERSITY OF TOLEDO   (United States)

^c BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; CRYSTALLOGRAPHY; GOLD; METAL NANOPARTICLES; MOLECULES; NANOPARTICLES; STEREOCHEMISTRY; TEXTILE PRINTING;

ELECTRON DYNAMICS; HIERARCHICAL PATTERNS; PATTERN STRUCTURE; SELF ORGANIZATIONS; STRUCTURAL ORDERING; STRUCTURAL PATTERN; SURFACE CHARACTERIZATION; THIOLATE LIGANDS;

X RAY CRYSTALLOGRAPHY;

EID: 85041451345     PISSN: None     EISSN: 23752548     Source Type: Journal    
DOI: 10.1126/sciadv.1500045     Document Type: Article

References (33)

1. M. Behrens, F. Studt, I. Kasatkin, S. Kuhl, M. Havecker, F. Abild-Pedersen, S. Zander, F. Girgsdies, P. Kurr, B. L. Kniep, M. Tovar, R. W. Fischer, J. K. Norskov, R. Schlogl, The active site of methanol synthesis over Cu/ZnO/AI203 industrial catalysts. Science 336, 893-897 (2012).
2. N. L. Rosi, D. A. Giljohann, C. S. Thaxton, A. K. Lytton-Jean, M. S. Han, C. A. Mirkin, Oligonucleotide-modified gold nanoparticles for intracellular gene regulation. Science 312, 1027-1030 (2006).
3. M. Zhu, C. M. Aikens, F. J. Hollander, G. C Schatz, R Jin, Correlating the crystal structure of a thiol-protected Au25 cluster and optical properties. 1 Am. Chem. Soc. 130, 5883-5885 (2008).
4. S. Billinge, I. Levin, The problem with determining atomic structure at the nanoscale. Science 316, 561-565 (2007).
5. H. Qian, M. Zhu, Z. Wu, R. Jin, Quantum sized gold nanoclusters with atomic precision. Acc. Chem. Res. 45, 1470-1479 (2012).
6. P. D. Jadzinsky, G. Calero, C. J. Ackerson, D. A. Bushnell, R. D. Kornberg, Structure of a thiol monolayer-protected gold nanoparticle at 1.1 A resolution. Science 318, 430-433 (2007).
7. H. Qian, Y. Zhu, R. Jin, Atomically precise gold nanocrystal molecules with surface plasmon resonance. Proc. Natl. Acad. Sci. USA. 109, 696-700 (2012).
8. C. A. Mirkin, R. L. Letsinger, R. C Mucic, J. J. Storhoff, A DNA-based method for rationally assembling nanoparticles into macroscopic materials. Nature 382, 607-609 (1996).
9. W. A. Lopes, H. M. Jaeger, Hierarchical self-assembly of metal nanostructures on diblock copolymer scaffolds. Nature 414, 735-738 (2001).
10. G. A. Devries, M. Brunnbauer, Y. Hu, A. M. Jackson, B. Long, B. T. Neltner, O. Uzun, B. H. Wunsch, F. Stellacci, Divalent metal nanoparticles. Science 315, 358-361 (2007).
11. F. Manea, F. B. Houillon, L. Pasquato, P. Scrimin, Nanozymes: Gold-nanoparticle-based transphosphorylation catalysts. Angew. Chem. Int. Ed. Engl. 43, 6165-6169 (2004).
12. R. B. Wyrwas, M. M. Alvarez, J. T. Khoury, R. C Price, T. G. Schaaff, R. L. Whetten, The colours of nanometric gold. Eur. Phys. J. D 43, 91-95 (2007).
13. N. K. Chaki, Y. Negishi, H. Tsunoyama, Y. Shichibu, T. Tsukuda, Ubiquitous 8 and 29 kDa goldtalkanethiolate cluster compounds: Mass-spectrometric determination of molecular formulas and structural implications. J. Am. Chem. Soc. 130, 8608-8610 (2008).
14. Y. Negishi, K. Nobusada, T. Tsukuda, Glutathione-protected gold clusters revisited: Bridging the gap between gold(l)-thiolate complexes and thiolate-protected gold nanocrystals. J. Am. Chem. Soc. 127, 5261-5270 (2005).
15. C. Zeng, Y. Chen, G. Li, R. Jin, Magic size Au64(S-c-C6Hii)32 nanocluster protected by cyclo-hexanethiolate. Chem. Mater. 26, 2635-2641 (2014).
16. Y. Song, J. Zhong, S. Yang, S. Wang, T. Cao, J. Zhang, P. Li, D. Hu, Y. Pei, M. Zhu, Crystal structure of Au25(SePh)18 nanoclusters and insights into their electronic, optical and catalytic properties. Nanoscale, 6, 13977-13985 (2013).
17. M. W. Heaven, A. Dass, P. S. White, K. M. Holt, R. W. Murray, Crystal structure of the gold nanoparticle [N(C8Hn7)4][Au25(SCH2CH2Ph)n8]. J. Am. Chem. Soc. 130, 3754-3755 (2008).
18. C. Zeng, C. Liu, Y. Chen, N. L. Rosi, R. Jin, Gold-thiolate ring as a protecting motif in the Au20(SR)16 nanocluster and implications. J. Am. Chem. Soc. 136, 11922-11925 (2014).
19. C. Zeng, H. Qian, T. Li, G. Li, N. L. Rosi, B. Yoon, R. N. Barnett, R. L. Whetten, U. Landman, R Jin, Total structure and electronic properties of the gold nanocrystal Au36(SR)24. Angew. Chem. Int. Ed. Engl. 51, 13114-13118 (2012).
20. R. L. Whetten, R. C. Price, Chemistry. Nano-golden order. Science 318, 407-408 (2007).
21. M. R. Langille, J. Zhang, M. L. Personick, S. Y. Li, C. A. Mirkin, Stepwise evolution of spherical seeds into 20-fold twinned icosahedra. Science 337, 954-957 (2012).
22. O. Voznyy, J. J. Dubowski, J. T. Yates, P. Maksymovych, The role of gold adatoms and stereochemistry in self-assembly of methylthiolate on Au(111). J. Am. Chem. Soc. 131, 12989-12993 (2009).
23. P. Ball, The Self-Made Tapestry: Pattern Formation in Nature (Oxford University Press, Oxford, 2001).
24. I. R. Bruss, G. M. Grason, Non-Euclidean geometry of twisted filament bundle packing. Proc. Natl. Acad. Sci. U.S.A. 109, 10781-10786 (2012).
25. J. M. Grimes, J. N. Burroughs, P. Gouet, J. M. Diprose, R. Malby, S. Zientara, P. P. Mertens, D. I. Stuart, The atomic structure of the bluetongue virus core. Nature 395, 470-478 (1998).
26. H. Qian, R. Jin, Controlling nanoparticles with atomic precision: The case of Au144(SCH2CH2Ph)60. Nana Lett. 9, 4083-4087 (2009).
27. A. Mackay, A dense non-crystallographic packing of equal spheres. Acta Cryst. 15, 916-918 (1962).
28. 6-Ein Goldcluster ungewöhnlicher Größe. Chem. Ber. 114, 3634-3642 (1981).
29. A M. Jackson, J. W. Myerson, F. Stellacci, Spontaneous assembly of subnanometre-ordered domains in the ligand shell of monolayer-protected nanoparticles. Nat. Mater. 3, 330-336 (2004).
30. C. L. Heinecke, T. W. Ni, S. Malola, V. Makinen, O. A. Wong, H. Hakkinen, C. J. Ackerson, Structural and theoretical basis for ligand exchange on thiolate monolayer protected gold nanoclusters. J. Am. Chem. Soc. 134, 13316-13322 (2012).
31. C. Yi, M. A. Tofanelli, C. J. Ackerson, K. L. Knappenberger, Optical properties and electronic energy relaxation of metallic Au144(SR)60 nanoclusters. J. Am. Chem. Soc. 135, 18222-18228 (2013).
32. S. Malola, L. Lehtovaara, J. Enkovaara, H. Hakkinen, Birth of the localized surface plasmon resonance in monolayer-protected gold nanoclusters. ACS Nano 7, 10263-10270 (2013).
33. J. H. Hodak, A. Henglein, G. V. Hartland, Electron-phonon coupling dynamics in very small (between 2 and 8 nm diameter) Au nanoparticles. J. Chem. Phys. 112, 5942 (2000).