Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges

Science Advances

Volumn 3, Issue 12, 2017, Pages

  Wu, Hao Bin ^a   Lou, Xiong Wen ^a,b  

^a ZHEJIANG UNIVERSITY   (China)

^b Nanyang Technological University   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLINE MATERIALS; ELECTROCATALYSTS; FUNCTIONAL MATERIALS; ORGANOMETALLICS;

ELECTROCHEMICAL APPLICATIONS; ELECTROCHEMICAL CAPACITOR; ELECTROCHEMICAL DEVICES; ELECTROCHEMICAL ENERGY STORAGE; EMERGING APPLICATIONS; INORGANIC MATERIALS; METAL ORGANIC FRAMEWORK; METALORGANIC FRAMEWORKS (MOFS);

ENERGY STORAGE;

EID: 85041167540     PISSN: None     EISSN: 23752548     Source Type: Journal    
DOI: 10.1126/sciadv.aap9252     Document Type: Review

References (131)

1. B. Dunn, H. Kamath, J.-M. Tarascon, Electrical energy storage for the grid: A battery of choices. Science 334, 928-935 (2011).
2. Z. W. Seh, J. Kibsgaard, C. F. Dickens, I. Chorkendorff, J. K. Nørskov, T. F. Jaramillo, Combining theory and experiment in electrocatalysis: Insights into materials design. Science 355, eaad4998 (2017).
3. M. Winter, R. J. Brodd, What are batteries, fuel cells, and supercapacitors? Chem. Rev. 104, 4245-4270 (2004).
4. H. Furukawa, K. E. Cordova, M. O'Keeffe, O. M. Yaghi, The chemistry and applications of metal-organic frameworks. Science 341, 1230444 (2013).
5. H.-C. Zhou, J. R. Long, O. M. Yaghi, Introduction to metal-organic frameworks. Chem. Rev. 112, 673-674 (2012).
6. J. Liang, Z. Liang, R. Zou, Y. Zhao, Heterogeneous catalysis in zeolites, mesoporous silica, and metal-organic frameworks. Adv. Mater. 29, 1701139 (2017).
7. H. Zhang, J. Nai, L. Yu, X. W. Lou, Metal-organic-framework-based materials as platforms for renewable energy and environmental applications. Joule 1, 77-107 (2017).
8. A. Mahmood, W. Guo, H. Tabassum, R. Zou, Metal-organic framework-based nanomaterials for electrocatalysis. Adv. Energy Mater. 6, 1600423 (2016).
9. H. Wang, Q.-L. Zhu, R. Zou, Q. Xu, Metal-organic frameworks for energy applications. Chem 2, 52-80 (2017).
10. L. Wang, Y. Han, X. Feng, J. Zhou, P. Qi, B. Wang, Metal-organic frameworks for energy storage: Batteries and supercapacitors. Coord. Chem. Rev. 307, 361-381 (2016).
11. B. Y. Guan, X. Y. Yu, H. B. Wu, X. W. Lou, Complex nanostructures from materials based on metal-organic frameworks for electrochemical energy storage and conversion. Adv. Mater. 2017, 1703614 (2017).
12. J.-K. Sun, Q. Xu, Functional materials derived from open framework templates/ precursors: Synthesis and applications. Energy Environ. Sci. 7, 2071-2100 (2014).
13. X. Cao, C. Tan, M. Sindoro, H. Zhang, Hybrid micro-/nano-structures derived from metal-organic frameworks: Preparation and applications in energy storage and conversion. Chem. Soc. Rev. 46, 2660-2677 (2017).
14. Y. V. Kaneti, J. Tang, R. R. Salunkhe, X. Jiang, A. Yu, K. C.-W. Wu, Y. Yamauchi, Nanoarchitectured design of porous materials and nanocomposites from metal-organic frameworks. Adv. Mater. 29, 1604898 (2017).
15. J. Liu, D. Zhu, C. Guo, A. Vasileff, S.-Z. Qiao, Design strategies toward advanced MOF-derived electrocatalysts for energy-conversion reactions. Adv. Energy Mater. 2017, 1700518 (2017).
16. W. Wang, X. Xu, W. Zhou, Z. Shao, Recent progress in metal-organic frameworks for applications in electrocatalytic and photocatalytic water splitting. Adv. Sci. 4, 1600371 (2017).
17. Z. Xie, W. Xu, X. Cui, Y. Wang, Recent progress in metal-organic frameworks and their derived nanostructures for energy and environmental applications. ChemSusChem 10, 1645-1663 (2017).
18. W. Xia, A. Mahmood, R. Zou, Q. Xu, Metal-organic frameworks and their derived nanostructures for electrochemical energy storage and conversion. Energy Environ. Sci. 8, 1837-1866 (2015).
19. S. Zheng, X. Li, B. Yan, Q. Hu, Y. Xu, X. Xiao, H. Xue, H. Pang, Transition-metal (Fe, Co, Ni) based metal-organic frameworks for electrochemical energy storage. Adv. Energy Mater. 7, 1602733 (2017).
20. P. Simon, Y. Gogotsi, B. Dunn, Where do batteries end and supercapacitors begin? Science 343, 1210-1211 (2014).
21. G. Férey, F. Millange, M. Morcrette, C. Serre, M.-L. Doublet, J.-M. Grenèche, J.-M. Tarascon, Mixed-valence Li/Fe-based metal-organic frameworks with both reversible redox and sorption properties. Angew. Chem. Int. Ed. 46, 3259-3263 (2007).
22. J. Shin, M. Kim, J. Cirera, S. Chen, G. J. Halder, T. A. Yersak, F. Paesani, S. M. Cohen, Y. S. Meng, MIL-101(Fe) as a lithium-ion battery electrode material: A relaxation and intercalation mechanism during lithium insertion. J. Mater. Chem. A 3, 4738-4744 (2015).
23. K. Saravanan, M. Nagarathinam, P. Balaya, J. J. Vittal, Lithium storage in a metal organic framework with diamondoid topology - A case study on metal formates. J. Mater. Chem. 20, 8329-8335 (2010).
24. Y. Jin, C. Zhao, Z. Sun, Y. Lin, L. Chen, D. Wang, C. Shen, Facile synthesis of Fe-MOF/RGO and its application as a high performance anode in lithium-ion batteries. RSC Adv. 6, 30763-30768 (2016).
25. Z. Zhang, H. Yoshikawa, K. Awaga, Monitoring the solid-state electrochemistry of Cu(2, 7-AQDC) (AQDC = anthraquinone dicarboxylate) in a lithium battery: Coexistence of metal and ligand redox activities in a metal-organic framework. J. Am. Chem. Soc. 136, 16112-16115 (2014).
26. C. Fang, Y. Huang, L. Yuan, Y. Liu, W. Chen, Y. Huang, K. Chen, J. Han, Q. Liu, Y. Huang, A metal-organic compound as cathode material with superhigh capacity achieved by reversible cationic and anionic redox chemistry for high-energy sodium-ion batteries. Angew. Chem. Int. Ed. 56, 6793-6797 (2017).
27. H.-W. Lee, R. Y. Wang, M. Pasta, S. Woo Lee, N. Liu, Y. Cui, Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries. Nat. Commun. 5, 5280 (2014).
28. Y. You, X.-L. Wu, Y.-X. Yin, Y.-G. Guo, High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries. Energy Environ. Sci. 7, 1643-1647 (2014).
29. L. Xue, Y. Li, H. Gao, W. Zhou, X. Lü, W. Kaveevivitchai, A. Manthiram, J. B. Goodenough, Low-cost high-energy potassium cathode. J. Am. Chem. Soc. 139, 2164-2167 (2017).
30. P.Nie, L. Shen, H. Luo, B.Ding, G. Xu, J.Wang, X. Zhang, Prussian blue analogues: A new class of anode materials for lithium ion batteries. J. Mater. Chem. A 2, 5852-5857 (2014).
31. Y. You, H.-R. Yao, S. Xin, Y.-X. Yin, T.-T. Zuo, C.-P. Yang, Y.-G. Guo, Y. Cui, L.-J. Wan, J. B. Goodenough, Subzero-temperature cathode for a sodium-ion battery. Adv. Mater. 28, 7243-7248 (2016).
32. R. Y. Wang, B. Shyam, K. H. Stone, J. N. Weker, M. Pasta, H.-W. Lee, M. F. Toney, Y. Cui, Reversible multivalent (monovalent, divalent, trivalent) ion insertion in open framework materials. Adv. Energy Mater. 5, 1401869 (2015).
33. M. L. Aubrey, J. R. Long, A dual-ion battery cathode via oxidative insertion of anions in a metal-organic framework. J. Am. Chem. Soc. 137, 13594-13602 (2015).
34. K. M. Choi, H. M. Jeong, J. H. Park, Y. B. Zhang, J. K. Kang, O. M. Yaghi, Supercapacitors of nanocrystalline metal-organic frameworks. ACS Nano 8, 7451-7457 (2014).
35. L. Sun, M. G. Campbell, M. Dinca, Electrically conductive porous metal-organic frameworks. Angew. Chem. Int. Ed. 55, 3566-3579 (2016).
36. D. Sheberla, J. C. Bachman, J. S. Elias, C.-J. Sun, Y. Shao-Horn, M. Dinca, Conductive MOF electrodes for stable supercapacitors with high areal capacitance. Nat. Mater. 16, 220-224 (2017).
37. D. Wu, Z. Guo, X. Yin, Q. Pang, B. Tu, L. Zhang, Y.-G. Wang, Q. Li, Metal-organic frameworks as cathode materials for Li-O2 batteries. Adv. Mater. 26, 3258-3262 (2014).
38. J. Zheng, J. Tian, D. Wu, M. Gu, W. Xu, C. Wang, F. Gao, M. H. Engelhard, J.-G. Zhang, J. Liu, J. Xiao, Lewis Acid-base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries. Nano Lett. 14, 2345-2352 (2014).
39. H. Park, D. J. Siegel, Tuning the adsorption of polysulfides in lithium-sulfur batteries with metal-organic frameworks. Chem. Mater. 29, 4932-4939 (2017).
40. J. Zhou, R. Li, X. Fan, Y. Chen, R. Han, W. Li, J. Zheng, B. Wang, X. Li, Rational design of a metal-organic framework host for sulfur storage in fast, long-cycle Li-S batteries. Energy Environ. Sci. 7, 2715-2724 (2014).
41. Y. P. Zhu, C. Guo, Y. Zheng, S.-Z. Qiao, Surface and interface engineering of noble-metalfree electrocatalysts for efficient energy conversion processes. Acc. Chem. Res. 50, 915-923 (2017).
42. P. M. Usov, B. Huffman, C. C. Epley, M. C. Kessinger, J. Zhu, W. A. Maza, A. J. Morris, Study of electrocatalytic properties of metal-organic framework PCN-223 for the oxygen reduction reaction. ACS Appl. Mater. Interfaces 9, 33539-33543 (2017).
43. N. Kornienko, Y. Zhao, C. S. Kley, C. Zhu, D. Kim, S. Lin, C. J. Chang, O. M. Yaghi, P. Yang, Metal-organic frameworks for electrocatalytic reduction of carbon dioxide. J. Am. Chem. Soc. 137, 14129-14135 (2015).
44. A. J. Clough, J. W. Yoo, M. H. Mecklenburg, S. C. Marinescu, Two-dimensional metal-organic surfaces for efficient hydrogen evolution from water. J. Am. Chem. Soc. 137, 118-121 (2015).
45. E. M. Miner, T. Fukushima, D. Sheberla, L. Sun, Y. Surendranath, M. Dinca, Electrochemical oxygen reduction catalysed by Ni3(hexaiminotriphenylene)2. Nat. Commun. 7, 10942 (2016).
46. S. Zhao, Y. Wang, J. Dong, C.-T. He, H. Yin, P. An, K. Zhao, X. Zhang, C. Gao, L. Zhang, J. Lv, J. Wang, J. Zhang, A. M. Khattak, N. A. Khan, Z. Wei, J. Zhang, S. Liu, H. Zhao, Z. Tang, Ultrathin metal-organic framework nanosheets for electrocatalytic oxygen evolution. Nat. Energy 1, 16184 (2016).
47. A. Zitolo, V. Goellner, V. Armel, M.-T. Sougrati, T. Mineva, L. Stievano, E. Fonda, F. Jaouen, Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials. Nat. Mater. 14, 937-942 (2015).
48. C. A. Downes, S. C. Marinescu, Efficient electrochemical and photoelectrochemical H2 production from water by a cobalt dithiolene one-dimensional metal-organic surface. J. Am. Chem. Soc. 137, 13740-13743 (2015).
49. A. J. Clough, J. M. Skelton, C. A. Downes, A. A. de la Rosa, J. W. Yoo, A. Walsh, B. C. Melot, S. C. Marinescu, Metallic conductivity in a two-dimensional cobalt dithiolene metal-organic framework. J. Am. Chem. Soc. 139, 10863-10867 (2017).
50. J.-Q. Shen, P.-Q. Liao, D.-D. Zhou, C.-T. He, J.-X. Wu, W.-X. Zhang, J.-P. Zhang, X.-M. Chen, Modular and stepwise synthesis of a hybrid metal-organic framework for efficient electrocatalytic oxygen evolution. J. Am. Chem. Soc. 139, 1778-1781 (2017).
51. P. Manna, J. Debgupta, S. Bose, S. K. Das, A mononuclear CoII coordination complex locked in a confined space and acting as an electrochemical water-oxidation catalyst: A "ship-in-a-bottle" approach. Angew. Chem. Int. Ed. 55, 2425-2430 (2016).
52. A. J. Howarth, Y. Liu, P. Li, Z. Li, T. C. Wang, J. T. Hupp, O. K. Farha, Chemical, thermal and mechanical stabilities of metal-organic frameworks. Nat. Rev. Mater. 1, 15018 (2016).
53. X.-F. Lu, P.-Q. Liao, J.-W. Wang, J.-X. Wu, X.-W. Chen, C.-T. He, J.-P. Zhang, G.-R. Li, X.-M. Chen, An alkaline-stable, metal hydroxide mimicking metal-organic framework for efficient electrocatalytic oxygen evolution. J. Am. Chem. Soc. 138, 8336-8339 (2016).
54. I. Hod, P. Deria, W. Bury, J. E. Mondloch, C.-W. Kung, M. So, M. D. Sampson, A. W. Peters, C. P. Kubiak, O. K. Farha, J. T. Hupp, A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution. Nat. Commun. 6, 8304 (2015).
55. S. Horike, D. Umeyama, S. Kitagawa, Ion conductivity and transport by porous coordination polymers and metal-organic frameworks. Acc. Chem. Res. 46, 2376-2384 (2013).
56. P. Ramaswamy, N. E. Wong, G. K. H. Shimizu, MOFs as proton conductors-Challenges and opportunities. Chem. Soc. Rev. 43, 5913-5932 (2014).
57. A.-L. Li, Q. Gao, J. Xu, X.-H. Bu, Proton-conductive metal-organic frameworks: Recent advances and perspectives. Coord. Chem. Rev. 344, 54-82 (2017).
58. W. J. Phang, H. Jo, W. R. Lee, J. H. Song, K. Yoo, B. Kim, C. S. Hong, Superprotonic conductivity of a UiO-66 framework functionalized with sulfonic acid groups by facile postsynthetic oxidation. Angew. Chem. Int. Ed. 54, 5142-5146 (2015).
59. S. Pili, S. P. Argent, C. G. Morris, P. Rought, V. García-Sakai, I. P. Silverwood, T. L. Easun, M. Li, M. R. Warren, C. A. Murray, C. C. Tang, S. Yang, M. Schröder, Proton conduction in a phosphonate-based metal-organic framework mediated by intrinsic "free diffusion inside a sphere". J. Am. Chem. Soc. 138, 6352-6355 (2016).
60. J. M. Taylor, K. W. Dawson, G. K. H. Shimizu, A water-stable metal-organic framework with highly acidic pores for proton-conducting applications. J. Am. Chem. Soc. 135, 1193-1196 (2013).
61. J. A. Hurd, R. Vaidhyanathan, V. Thangadurai, C. I. Ratcliffe, I. L. Moudrakovski, G. K. H. Shimizu, Anhydrous proton conduction at 150°C in a crystalline metal-organic framework. Nat. Chem. 1, 705-710 (2009).
62. S. S. Nagarkar, S. M. Unni, A. Sharma, S. Kurungot, S. K. Ghosh, Two-in-one: Inherent anhydrous and water-assisted high proton conduction in a 3D metal-organic framework. Angew. Chem. Int. Ed. 53, 2638-2642 (2014).
63. D. Umeyama, S. Horike, M. Inukai, Y. Hijikata, S. Kitagawa, Confinement of mobile histamine in coordination nanochannels for fast proton transfer. Angew. Chem. Int. Ed. 50, 11706-11709 (2011).
64. V. G. Ponomareva, K. A. Kovalenko, A. P. Chupakhin, D. N. Dybtsev, E. S. Shutova, V. P. Fedin, Imparting high proton conductivity to a metal-organic framework material by controlled acid impregnation. J. Am. Chem. Soc. 134, 15640-15643 (2012).
65. F.-M. Zhang, L.-Z. Dong, J.-S. Qin, W. Guan, J. Liu, S.-L. Li, M. Lu, Y.-Q. Lan, Z.-M. Su, H.-C. Zhou, Effect of imidazole arrangements on proton-conductivity in metal-organic frameworks. J. Am. Chem. Soc. 139, 6183-6189 (2017).
66. Y.-S. Wei, X.-P. Hu, Z. Han, X.-Y. Dong, S.-Q. Zang, T. C. W. Mak, Unique proton dynamics in an efficient MOF-based proton conductor. J. Am. Chem. Soc. 139, 3505-3512 (2017).
67. B. Joarder, J.-B. Lin, Z. Romero, G. K. H. Shimizu, Single crystal proton conduction study of a metal organic framework of modest water stability. J. Am. Chem. Soc. 139, 7176-7179 (2017).
68. M. Inukai, S. Horike, T. Itakura, R. Shinozaki, N. Ogiwara, D. Umeyama, S. Nagarkar, Y. Nishiyama, M. Malon, A. Hayashi, T. Ohhara, R. Kiyanagi, S. Kitagawa, Encapsulating mobile proton carriers into structural defects in coordination polymer crystals: High anhydrous proton conduction and fuel cell application. J. Am. Chem. Soc. 138, 8505-8511 (2016).
69. K. Fujie, R. Ikeda, K. Otsubo, T. Yamada, H. Kitagawa, Lithium ion diffusion in a metal-organic framework mediated by an ionic liquid. Chem. Mater. 27, 7355-7361 (2015).
70. R. Ameloot, M. Aubrey, B. M. Wiers, A. P. Gómora-Figueroa, S. N. Patel, N. P. Balsara, J. R. Long, Ionic conductivity in the metal-organic framework UiO-66 by dehydration and insertion of lithium tert-butoxide. Chem. Eur. J. 19, 5533-5536 (2013).
71. B. M. Wiers, M.-L. Foo, N. P. Balsara, J. R. Long, A solid lithium electrolyte via addition of lithium isopropoxide to a metal-organic framework with open metal sites. J. Am. Chem. Soc. 133, 14522-14525 (2011).
72. M. L. Aubrey, R. Ameloot, B. M. Wiers, J. R. Long, Metal-organic frameworks as solid magnesium electrolytes. Energy Environ. Sci. 7, 667-671 (2014).
73. M. Hu, J. Reboul, S. Furukawa, N. L. Torad, Q. Ji, P. Srinivasu, K. Ariga, S. Kitagawa, Y. Yamauchi, Direct carbonization of Al-based porous coordination polymer for synthesis of nanoporous carbon. J. Am. Chem. Soc. 134, 2864-2867 (2012).
74. H.-L. Jiang, B. Liu, Y.-Q. Lan, K. Kuratani, T. Akita, H. Shioyama, F. Zong, Q. Xu, From metal-organic framework to nanoporous carbon: Toward a very high surface area and hydrogen uptake. J. Am. Chem. Soc. 133, 11854-11857 (2011).
75. P. Pachfule, D. Shinde, M. Majumder, Q. Xu, Fabrication of carbon nanorods and graphene nanoribbons from a metal-organic framework. Nat. Chem. 8, 718-724 (2016).
76. F. Zheng, Y. Yang, Q. Chen, High lithium anodic performance of highly nitrogen-doped porous carbon prepared from a metal-organic framework. Nat. Commun. 5, 5261 (2014).
77. S. Gadipelli, T. Zhao, S. A. Shevlin, Z. Guo, Switching effective oxygen reduction and evolution performance by controlled graphitization of a cobalt-nitrogen-carbon framework system. Energy Environ. Sci. 9, 1661-1667 (2016).
78. J. Tang, R. R. Salunkhe, J. Liu, N. L. Torad, M. Imura, S. Furukawa, Y. Yamauchi, Thermal conversion of core-shell metal-organic frameworks: A new method for selectively functionalized nanoporous hybrid carbon. J. Am. Chem. Soc. 137, 1572-1580 (2015).
79. R. R. Salunkhe, J. Tang, Y. Kamachi, T. Nakato, J. H. Kim, Y. Yamauchi, Asymmetric supercapacitors using 3D nanoporous carbon and cobalt oxide electrodes synthesized from a single metal-organic framework. ACS Nano 9, 6288-6296 (2015).
80. L. Zhang, H. B. Wu, S. Madhavi, H. H. Hng, X. W. Lou, Formation of Fe2O3 microboxes with hierarchical shell structures from metal-organic frameworks and their lithium storage properties. J. Am. Chem. Soc. 134, 17388-17391 (2012).
81. W. Cho, S. Park, M. Oh, Coordination polymer nanorods of Fe-MIL-88B and their utilization for selective preparation of hematite and magnetite nanorods. Chem. Commun. 47, 4138-4140 (2011).
82. B. Y. Xia, Y. Yan, N. Li, H. B. Wu, X. W. Lou, X. Wang, A metal-organic framework-derived bifunctional oxygen electrocatalyst. Nat. Energy 1, 15006 (2016).
83. A. Aijaz, J. Masa, C. Rösler, W. Xia, P. Weide, A. J. R. Botz, R. A. Fischer, W. Schuhmann, M. Muhler, Co@Co3O4 encapsulated in carbon nanotube-grafted nitrogen-doped carbon polyhedra as an advanced bifunctional oxygen electrode. Angew. Chem. Int. Ed. 55, 4087-4091 (2016).
84. B. Y. Guan, L. Yu, X. W. Lou, A dual-metal-organic-framework derived electrocatalyst for oxygen reduction. Energy Environ. Sci. 9, 3092-3096 (2016).
85. F. Zou, X. Hu, Z. Li, L. Qie, C. Hu, R. Zeng, Y. Jiang, Y. Huang, MOF-derived porous ZnO/ ZnFe2O4/C octahedra with hollow interiors for high-rate lithium-ion batteries. Adv. Mater. 26, 6622-6628 (2014).
86. S. J. Yang, S. Nam, T. Kim, J. H. Im, H. Jung, J. H. Kang, S. Wi, B. Park, C. R. Park, Preparation and exceptional lithium anodic performance of porous carbon-coated ZnO quantum dots derived from a metal-organic framework. J. Am. Chem. Soc. 135, 7394-7397 (2013).
87. P. Yin, T. Yao, Y. Wu, L. Zheng, Y. Lin, W. Liu, H. Ju, J. Zhu, X. Hong, Z. Deng, G. Zhou, S. Wei, Y. Li, Single cobalt atoms with precise N-coordination as superior oxygen reduction reaction catalysts. Angew. Chem. Int. Ed. 55, 10800-10805 (2016).
88. H. Zhang, T. Wang, J. Wang, H. Liu, T. D. Dao, M. Li, G. Liu, X. Meng, K. Chang, L. Shi, T. Nagao, J. Ye, Surface-plasmon-enhanced photodriven CO2 reduction catalyzed by metal-organic-framework-derived iron nanoparticles encapsulated by ultrathin carbon layers. Adv. Mater. 28, 3703-3710 (2016).
89. Y. Hou, Z. Wen, S. Cui, S. Ci, S. Mao, J. Chen, An advanced nitrogen-doped graphene/ cobalt-embedded porous carbon polyhedron hybrid for efficient catalysis of oxygen reduction and water splitting. Adv. Funct. Mater. 25, 872-882 (2015).
90. L. Zhang, H. B. Wu, X. W. Lou, Metal-organic-frameworks-derived general formation of hollow structures with high complexity. J. Am. Chem. Soc. 135, 10664-10672 (2013).
91. J. Zhang, H. Hu, Z. Li, X. W. Lou, Double-shelled nanocages with cobalt hydroxide inner shell and layered double hydroxides outer shell as high-efficiency polysulfide mediator for lithium-sulfur batteries. Angew. Chem. Int. Ed. 55, 3982-3986 (2016).
92. X.-Y. Yu, L. Yu, H. B. Wu, X. W. Lou, Formation of nickel sulfide nanoframes from metal-organic frameworks with enhanced pseudocapacitive and electrocatalytic properties. Angew. Chem. Int. Ed. 54, 5331-5335 (2015).
93. P. Zhang, B. Y. Guan, L. Yu, X. W. Lou, Formation of double-shelled zinc-cobalt sulfide dodecahedral cages from bimetallic zeolitic imidazolate frameworks for hybrid supercapacitors. Angew. Chem. Int. Ed. 56, 7141-7145 (2017).
94. K. Cho, S.-H. Han, M. P. Suh, Copper-organic framework fabricated with CuS nanoparticles: Synthesis, electrical conductivity, and electrocatalytic activities for oxygen reduction reaction. Angew. Chem. Int. Ed. 55, 15301-15305 (2016).
95. H. Hu, J. Zhang, B. Guan, X. W. Lou, Unusual formation of CoSe@carbon nanoboxes, which have an inhomogeneous shell, for efficient lithium storage. Angew. Chem. Int. Ed. 55, 9514-9518 (2016).
96. X.-Y. Yu, Y. Feng, B. Guan, X. W. Lou, U. Paik, Carbon coated porous nickel phosphides nanoplates for highly efficient oxygen evolution reaction. Energy Environ. Sci. 9, 1246-1250 (2016).
97. P. He, X.-Y. Yu, X. W. Lou, Carbon-incorporated nickel-cobalt mixed metal phosphide nanoboxes with enhanced electrocatalytic activity for oxygen evolution. Angew. Chem. Int. Ed. 56, 3897-3900 (2017).
98. R. Bendi, V. Kumar, V. Bhavanasi, K. Parida, P. S. Lee, Metal organic framework-derived metal phosphates as electrode materials for supercapacitors. Adv. Energy Mater. 6, 1501833 (2016).
99. W. Guo, W. Xia, K. Cai, Y. Wu, B. Qiu, Z. Liang, C. Qu, R. Zou, Kinetic-controlled formation of bimetallic metal-organic framework hybrid structures. Small 2017, 1702049 (2017).
100. X. Song, T. K. Kim, H. Kim, D. Kim, S. Jeong, H. R. Moon, M. S. Lah, Post-synthetic modifications of framework metal ions in isostructural metal-organic frameworks: Core-shell heterostructures via selective transmetalations. Chem. Mater. 24, 3065-3073 (2012).
101. C. R. Wade, M. Dinca, Investigation of the synthesis, activation, and isosteric heats of CO2 adsorption of the isostructural series of metal-organic frameworks M3(BTC)2 (M = Cr, Fe, Ni, Cu, Mo, Ru). Dalton Trans. 41, 7931-7938 (2012).
102. H. B. Wu, B. Y. Xia, L. Yu, X.-Y. Yu, X. W. Lou, Porous molybdenum carbide nano-octahedrons synthesized via confined carburization in metal-organic frameworks for efficient hydrogen production. Nat. Commun. 6, 6512 (2015).
103. Y.-J. Tang, M.-R. Gao, C.-H. Liu, S.-L. Li, H.-L. Jiang, Y.-Q. Lan, M. Han, S.-H. Yu, Porous molybdenum-based hybrid catalysts for highly efficient hydrogen evolution. Angew. Chem. Int. Ed. 54, 12928-12932 (2015).
104. Y. Chen, S. Ji, Y. Wang, J. Dong, W. Chen, Z. Li, R. Shen, L. Zheng, Z. Zhuang, D. Wang, Y. Li, Isolated single iron atoms anchored on N-doped porous carbon as an efficient electrocatalyst for the oxygen reduction reaction. Angew. Chem. Int. Ed. 56, 6937-6941 (2017).
105. Q. Li, P. Xu, W. Gao, S. Ma, G. Zhang, R. Cao, J. Cho, H.-L. Wang, G. Wu, Graphene/ graphene-tube nanocomposites templated from cage-containing metal-organic frameworks for oxygen reduction in Li-O2 batteries. Adv. Mater. 26, 1378-1386 (2014).
106. K. Strickland, E. Miner, Q. Jia, U. Tylus, N. Ramaswamy, W. Liang, M.-T. Sougrati, F. Jaouen, S. Mukerjee, Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal-nitrogen coordination. Nat. Commun. 6, 7343 (2015).
107. G. Lu, S. Li, Z. Guo, O. K. Farha, B. G. Hauser, X. Qi, Y. Wang, X. Wang, S. Han, X. Liu, J. S. DuChene, H. Zhang, Q. Zhang, X. Chen, J. Ma, S. C. J. Loo, W. D. Wei, Y. Yang, J. T. Hupp, F. Huo, Imparting functionality to a metal-organic framework material by controlled nanoparticle encapsulation. Nat. Chem. 4, 310-316 (2012).
108. Y. V. Kaneti, S. Dutta, S. A. Hossain, M. J. A. Shiddiky, K.-L. Tung, F.-K. Shieh, C.-K. Tsung, K. C.-W. Wu, Y. Yamauchi, Strategies for improving the functionality of zeolitic imidazolate frameworks: Tailoring nanoarchitectures for functional applications. Adv. Mater. 29, 1700213 (2017).
109. X. Xu, R. Cao, S. Jeong, J. Cho, Spindle-like Mesoporous a-Fe2O3 Anode Material Prepared from MOF Template for High-rate Lithium Batteries. Nano Lett. 12, 4988-4991 (2012).
110. Y. Yang, Z. Lun, G. Xia, F. Zheng, M. He, Q. Chen, Non-precious alloy encapsulated in nitrogen-doped graphene layers derived from MOFs as an active and durable hydrogen evolution reaction catalyst. Energy Environ. Sci. 8, 3563-3571 (2015).
111. L. Han, X.-Y. Yu, X. W. Lou, Formation of Prussian-blue-analog nanocages via a direct etching method and their conversion into Ni-Co-mixed oxide for enhanced oxygen evolution. Adv. Mater. 28, 4601-4605 (2016).
112. H. Hu, B. Guan, B. Xia, X. W. Lou, Designed formation of Co3O4/NiCo2O4 double-shelled nanocages with enhanced pseudocapacitive and electrocatalytic properties. J. Am. Chem. Soc. 137, 5590-5595 (2015).
113. W. Xia, R. Zou, L. An, D. Xia, S. Guo, A metal-organic framework route to in situ encapsulation of Co@Co3O4@C core@bishell nanoparticles into a highly ordered porous carbon matrix for oxygen reduction. Energy Environ. Sci. 8, 568-576 (2015).
114. H.-x. Zhong, J. Wang, Y.-w. Zhang, W.-l. Xu, W. Xing, D. Xu, Y.-f. Zhang, X.-b. Zhang, ZIF-8 derived graphene-based nitrogen-doped porous carbon sheets as highly efficient and durable oxygen reduction electrocatalysts. Angew. Chem. Int. Ed. 53, 14235-14239 (2014).
115. Z. Li, M. Shao, L. Zhou, R. Zhang, C. Zhang, M. Wei, D. G. Evans, X. Duan, Directed growth of metal-organic frameworks and their derived carbon-based network for efficient electrocatalytic oxygen reduction. Adv. Mater. 28, 2337-2344 (2016).
116. Y. M. Chen, L. Yu, X. W. Lou, Hierarchical tubular structures composed of Co3O4 hollow nanoparticles and carbon nanotubes for lithium storage. Angew. Chem. Int. Ed. 55, 5990-5993 (2016).
117. X. Cao, B. Zheng, X. Rui, W. Shi, Q. Yan, H. Zhang, Metal oxide-coated three-dimensional graphene prepared by the use of metal-organic frameworks as precursors. Angew. Chem. Int. Ed. 53, 1404-1409 (2014).
118. T. Y. Ma, S. Dai, M. Jaroniec, S. Z. Qiao, Metal-organic framework derived hybrid Co3O4-carbon porous nanowire arrays as reversible oxygen evolution electrodes. J. Am. Chem. Soc. 136, 13925-13931 (2014).
119. G. Zhang, S. Hou, H. Zhang, W. Zeng, F. Yan, C. C. Li, H. Duan, High-performance and ultra-stable lithium-ion batteries based on MOF-derived ZnO@ZnO quantum dots/C core-shell nanorod arrays on a carbon cloth anode. Adv. Mater. 27, 2400-2405 (2015).
120. W. Xia, C. Qu, Z. Liang, B. Zhao, S. Dai, B. Qiu, Y. Jiao, Q. Zhang, X. Huang, W. Guo, D. Dang, R. Zou, D. Xia, Q. Xu, M. Liu, High-performance Energy Storage and Conversion Materials Derived from A Single Metal-organic Framework/graphene Aerogel Composite. Nano Lett. 17, 2788-2795 (2017).
121. W. Xia, B. Qiu, D. Xia, R. Zou, Facile preparation of hierarchically porous carbons from metal-organic gels and their application in energy storage. Sci. Rep. 3, 1935 (2013).
122. A. J. Amali, J.-K. Sun, Q. Xu, From assembled metal-organic framework nanoparticles to hierarchically porous carbon for electrochemical energy storage. Chem. Commun. 50, 1519-1522 (2014).
123. L. Yu, H. B. Wu, X. W. Lou, Self-templated formation of hollow structures for electrochemical energy applications. Acc. Chem. Res. 50, 293-301 (2017).
124. B. Y. Guan, A. Kushima, L. Yu, S. Li, J. Li, X. W. Lou, Coordination polymers derived general synthesis of multishelled mixed metal-oxide particles for hybrid supercapacitors. Adv. Mater. 29, 1605902 (2017).
125. B. Y. Guan, L. Yu, X. Wang, S. Song, X. W. Lou, Formation of onion-like NiCo2S4 particles via sequential ion-exchange for hybrid supercapacitors. Adv. Mater. 29, 1605051 (2017).
126. K. Xi, S. Cao, X. Peng, C. Ducati, R. V. Kumar, A. K. Cheetham, Carbon with hierarchical pores from carbonized metal-organic frameworks for lithium sulphur batteries. Chem. Commun. 49, 2192-2194 (2013).
127. H. B. Wu, S. Wei, L. Zhang, R. Xu, H. H. Hng, X. W. Lou, Embedding sulfur in MOF-derived microporous carbon polyhedrons for lithium-sulfur batteries. Chem. Eur. J. 19, 10804-10808 (2013).
128. Z. Li, H. B. Wu, X. W. Lou, Rational designs and engineering of hollow micro-/nanostructures as sulfur hosts for advanced lithium-sulfur batteries. Energy Environ. Sci. 9, 3061-3070 (2016).
129. Z.-F. Huang, J. Song, K. Li, M. Tahir, Y.-T. Wang, L. Pan, L. Wang, X. Zhang, J.-J. Zou, Hollow cobalt-based bimetallic sulfide polyhedra for efficient all-pH-value electrochemical and photocatalytic hydrogen evolution. J. Am. Chem. Soc. 138, 1359-1365 (2016).
130. D. Zhao, J.-L. Shui, L. R. Grabstanowicz, C. Chen, S. M. Commet, T. Xu, J. Lu, D.-J. Liu, Highly efficient non-precious metal electrocatalysts prepared from one-pot synthesized zeolitic imidazolate frameworks. Adv. Mater. 26, 1093-1097 (2014).
131. M. Gaab, N. Trukhan, S. Maurer, R. Gummaraju, U. Müller, The progression of Al-based metal-organic frameworks-From academic research to industrial production and applications. Microporous Mesoporous Mater. 157, 131-136 (2012).