Cyclic voltammetry and XPS analyses of graphite felt derivatized by non-Kolbe reactions in aqueous media

New Journal of Chemistry

Volumn , Issue , 2002, Pages 1261-1266

  Geneste, Florence ^a   Maël, Cadoret ^a   Moinet, Claude ^a   Jezequel, Guy ^b  

^a UMR 6509 Organometalliques et Catalyse Chimie et Electrochimie Moleculaires   (France)

^b UNIVERSITÉ DE RENNES 1   (France)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 85034796943     PISSN: 11440546     EISSN: 13699261     Source Type: Journal    
DOI: 10.1039/b203542a     Document Type: Article

References (42)

1. J. Simonet, G. Le Guillanton Bull. Soc. Chim. Fr., 1985, 180.
2. E. Steckhan Angew. Chem., Int. Ed. Engl., 1986, 25, 683.
3. S. Torii Synthesis, 1986, 873.
4. See for examples W. Roman, E. Steckhan Electrochim. Acta, 1997, 42, 2027.
5. G. Cauquis, S. Cosnier, A. Deronzier, B. Galland, D. Limosin, J.-C. Moutet, J. Bizot, D. Deprez, J.-P. Pulicani J. Electroanal. Chem., 1993, 352, 181.
6. E. Simon, E. Sablé, H. Handel, M. L’Her Electrochim. Acta, 1999, 45, 855.
7. A. Deronzier, D. Eloy, P. Jardon, A. Martre, J.-C. Moutet J. Electroanal. Chem., 1998, 453, 179.
8. T. Osa, Y. Kashiwagi, K. Mukai, A. Oshawa, J. Bobbitt Chem. Lett., 1990, 75.
9. Y. Kashiwagi, A. Oshawa, T. Osa, Z. Ma, J. M. Bobbitt Chem. Lett., 1991, 581.
10. Y. Kashiwagi, H. Ono, T. Osa Chem. Lett., 1993, 257.
11. T. Osa, Y. Kashiwagi, Y. Yanagisawa, J. Bobbitt Chem. Commun., 1994, 2535.
12. Y. Yanagisawa, Y. Kashiwagi, F. Kurashima, J.-I. Anzai, T. Osa, J. Bobbitt Chem. Lett., 1996, 1043.
13. Y. Kashiwagi, Y. Yanagisawa, F. Kurashima, J.-I. Anzai, T. Osa, J. M. Bobbitt Chem. Commun., 1996, 2745.
14. E. M. Belgsir, H. Schäfer Electrochem. Commun., 2001, 3, 32.
15. Y. Kashiwagi, Y. Yanagisawa, N. Shibayama, K. Nakahara, F. Kurashima, J. Anzai, T. Osa Electrochim. Acta, 1997, 42, 2267.
16. E. M. Belgsir, H. Schäfer Chem. Commun., 1999, 435.
17. P. Jego-Evanno, C. Moinet, G. Simonneaux C. R. Acad. Sci., Ser. IIc: Chim., 2000, 711.
18. F. Beck, H. Junge, H. Krohn Electrochim. Acta, 1981, 26, 799.
19. D. C. Alsmeyer, R. L. McCreery Anal. Chem., 1992, 64, 1528.
20. B. F. Watkins, J. R. Behling, E. Kariv, L. L. Miller J. Am. Chem Soc., 1975, 97, 3549.
21. J. C. Lennox, R. W. Murray J. Electroanal. Chem., 1977, 78, 395.
22. A. J. Downard J. Electroanal., 2000, 12, 1085.
23. E. Coulon, J. Pinson, J.-D. Bourzat, A. Commerçon, J. P. Pulicani Langmuir, 2001, 17, 7102.
24. C. P. Andrieux, F. Gonzalez, J.-M. Savéant J. Am. Chem. Soc., 1997, 119, 4292.
25. H. Hofer, M. Moest Ann. Chem. Pharm., 1902, 323, 284.
26. J. K. Lindsay, C. R. Hauser J. Org. Chem., 1958, 23, 653.
27. C. Moinet J. Phys. IV, 1994, 4, C1-175.
28. C. Lamoureux, C. Moinet, A. Tallec Electrochim. Acta, 1986, 31, 1.
29. P. Jego-Evanno, J.-P. Hurvois, C. Moinet J. Electroanal. Chem., 2001, 507, 270.
30. P. Chen, R. L. McCreery Anal. Chem., 1996, 68, 3958.
31. F. Regisser, M.-A. Lavoie, G. Y. Champagne, D. Bélanger J. Electroanal. Chem., 1996, 415, 47.
32. M. Baizer, and H. Lund, Organic Electrochemistry, Marcel Decker, NY, 1991, p. 411.
33. -When the nitro group is partially reduced into arylhydroxylamine (Ar-NHOH), the interconversion between Ar-NHOH and Ar-NO can occur
34. The volume concentrations are defined as the number of moles of electroactive grafted molecules per volume of felt. This term was preferred to the typically used surface concentration because it did not depend on the real surface area of the felt and directly accounted for the possibility of using the grafted three-dimensional electrode in indirect electrolysis
35. The introduction of anelectroactive compound on the alcohol groups of the felt was realized by heating the felt at 40 °C during 3 hours with 4-nitrobenzoyl chloride and triethylamine in toluene. The felt was then successively rinsed with toluene, water, acetone and soxhlet extracted in chloroform for 24 h. The grafting process was achieved with benzeneacetic acid instead of 4-nitrobenzeneacetic acid to measure the volume concentrations with the best accuracy
36. dl(double layer capacity).The resulting current is called capacitive current and is responsible for the capacitive envelope on cyclic voltammograms
37. W. G. Pell, B. E. Conway J. Electroanal. Chem., 2001, 500, 121.
38. K. W. Hathcock, J. C. Brumfield, C. A. Goss, E. A. Irene, R. W. Murray Anal. Chem., 1995, 67, 2201.
39. H. Maeda, Y. Yamauchi, M. Hosoe, T.-X. Li, E. Yamagushi, M. Kasamatsu, H. Ohmori Chem. Pharm. Bull., 1994, 42, 1870.
40. H. Maeda, M. Hosoe, T.-X. Li, M. Itami, Y. Yamauchi, H. Ohmori Chem. Pharm. Bull., 1996, 44, 559.
41. H. Maeda, T.-X. Li, M. Hosoe, M. Itami Anal. Sci., 1994, 10, 963.
42. H. Maeda, M. Itami, Y. Yamauchi, H. Ohmori Chem. Pharm. Bull., 1996, 44, 2294.