Controllable Location of Inorganic Nanoparticles on Block Copolymer Self-Assembled Scaffolds by Tailoring the Entropy and Enthalpy Contributions

Macromolecules

Volumn 50, Issue 17, 2017, Pages 6771-6778

  Yan, Nan ^a   Zhang, Yan ^a   He, Yun ^a   Zhu, Yutian ^a   Jiang, Wei ^a  

^a CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK COPOLYMERS; EMULSIFICATION; EMULSIONS; ENTROPY; LIGANDS; LOCATION; NANOPARTICLES; NANOSTRUCTURES; POLYMERS;

CONFORMATIONAL ENTROPY; ENTHALPIC INTERACTIONS; ENTROPY AND ENTHALPIES; FUNCTIONAL NANOPARTICLES; HYBRID NANOMATERIALS; INORGANIC NANOPARTICLE; OIL/WATER INTERFACES; PRECISE POSITIONING;

SCAFFOLDS (BIOLOGY);

EID: 85029144023     PISSN: 00249297     EISSN: 15205835     Source Type: Journal    
DOI: 10.1021/acs.macromol.7b01076     Document Type: Article

References (50)

1. Balazs, A. C.; Emrick, T.; Russell, T. P. Nanoparticle Polymer Composites: Where Two Small Worlds Meet Science 2006, 314, 1107-1110 10.1126/science.1130557
2. Kao, J.; Bai, P.; Lucas, J. M.; Alivisatos, A. P.; Xu, T. Size-Dependent Assemblies of Nanoparticle Mixtures in Thin Films J. Am. Chem. Soc. 2013, 135, 1680-1683 10.1021/ja3107912
3. Deng, R.; Liang, F.; Qu, X.; Wang, Q.; Zhu, J.; Yang, Z. Diblock Copolymer Based Janus Nanoparticles Macromolecules 2015, 48, 750-755 10.1021/ma502339s
4. Sarkar, B.; Alexandridis, P. Block Copolymer-Nanoparticle Composites: Structure, Functional Properties, and Processing Prog. Polym. Sci. 2015, 40, 33-62 10.1016/j.progpolymsci.2014.10.009
5. He, J.; Huang, X.; Li, Y.-C.; Liu, Y.; Babu, T.; Aronova, M. A.; Wang, S.; Lu, Z.; Chen, X.; Nie, Z. Self-Assembly of Amphiphilic Plasmonic Micelle-Like Nanoparticles in Selective Solvents J. Am. Chem. Soc. 2013, 135, 7974-7984 10.1021/ja402015s
6. Onses, M. S.; Wan, L.; Liu, X.; Kiremitler, N. B.; Yilmaz, H.; Nealey, P. F. Self-Assembled Nanoparticle Arrays on Chemical Nanopatterns Prepared Using Block Copolymer Lithography ACS Macro Lett. 2015, 4, 1356-1361 10.1021/acsmacrolett.5b00644
7. Zhang, L.; Chen, Y.; Li, Z.; Li, L.; Saint-Cricq, P.; Li, C.; Lin, J.; Wang, C.; Su, Z.; Zink, J. I. Tailored Synthesis of Octopus-type Janus Nanoparticles for Synergistic Actively-Targeted and Chemo-Photothermal Therapy Angew. Chem., Int. Ed. 2016, 55, 2118-2121 10.1002/anie.201510409
8. Liu, Y.; Yang, X.; Huang, Z.; Huang, P.; Zhang, Y.; Deng, L.; Wang, Z.; Zhou, Z.; Liu, Y.; Kalish, H.; Khachab, N. M.; Chen, X.; Nie, Z. Magneto-Plasmonic Janus Vesicles for Magnetic Field-Enhanced Photoacoustic and Magnetic Resonance Imaging of Tumors Angew. Chem., Int. Ed. 2016, 55, 15297-15300 10.1002/anie.201608338
9. Wang, L.; Liu, Y.; He, J.; Hourwitz, M. J.; Yang, Y.; Fourkas, J. T.; Han, X.; Nie, Z. Continuous Microfluidic Self-Assembly of Hybrid Janus-Like Vesicular Motors: Autonomous Propulsion and Controlled Release Small 2015, 11, 3762-3767 10.1002/smll.201500527
10. Yap, F. L.; Thoniyot, P.; Krishnan, S.; Krishnamoorthy, S. Nanoparticle Cluster Arrays for High-Performance SERS through Directed Self-Assembly on Flat Substrates and on Optical Fibers ACS Nano 2012, 6, 2056-2070 10.1021/nn203661n
11. Kao, J.; Bai, P.; Chuang, V. P.; Jiang, Z.; Ercius, P.; Xu, T. Nanoparticle Assemblies in Thin Films of Supramolecular Nanocomposites Nano Lett. 2012, 12, 2610-2618 10.1021/nl300999u
12. Nakano, T.; Kawaguchi, D.; Matsushita, Y. Anisotropic Self-Assembly of Gold Nanoparticle Grafted with Polyisoprene and Polystyrene Having Symmetric Polymer Composition J. Am. Chem. Soc. 2013, 135, 6798-6801 10.1021/ja402412q
13. Liang, R. J.; Xu, J. P.; Li, W. K.; Liao, Y. G.; Wang, K.; You, J. C.; Zhu, J. T.; Jiang, W. Precise Localization of Inorganic Nanoparticles in Block Copolymer Micellar Aggregates: From Center to Interface Macromolecules 2015, 48, 256-263 10.1021/ma501835r
14. Liu, Y.; He, J.; Yang, K.; Yi, C.; Liu, Y.; Nie, L.; Khashab, N. M.; Chen, X.; Nie, Z. Folding Up of Gold Nanoparticle Strings into Plasmonic Vesicles for Enhanced Photoacoustic Imaging Angew. Chem., Int. Ed. 2015, 54, 15809-15812 10.1002/anie.201508616
15. Liu, Z.; Guo, R.; Xu, G.; Huang, Z.; Yan, L.-T. Entropy-Mediated Mechanical Response of the Interfacial Nanoparticle Patterning Nano Lett. 2014, 14, 6910-6916 10.1021/nl5029396
16. Ma, C.; Wu, H.; Huang, Z.-H.; Guo, R.-H.; Hu, M.-B.; Kuebel, C.; Yan, L.-T.; Wang, W. A Filled-Honeycomb-Structured Crystal Formed by Self-Assembly of a Janus Polyoxometalate-Silsesquioxane (POM-POSS) Co-Cluster Angew. Chem., Int. Ed. 2015, 54, 15699-15704 10.1002/anie.201507237
17. Chen, P.; Yang, Y.; Dong, B.; Huang, Z.; Zhu, G.; Cao, Y.; Yan, L.-T. Polymerization-Induced Interfacial Self-Assembly of Janus Nanoparticles in Block Copolymers: Reaction-Mediated Entropy Effects, Diffusion Dynamics, and Tailorable Micromechanical Behaviors Macromolecules 2017, 50, 2078-2091 10.1021/acs.macromol.7b00012
18. Wang, H.; Levin, C. S.; Halas, N. J. Nanosphere Arrays with Controlled Sub-10-nm Gaps as Surface-Enhanced Raman Spectroscopy Substrates J. Am. Chem. Soc. 2005, 127, 14992-14993 10.1021/ja055633y
19. Quinten, M.; Leitner, A.; Krenn, J. R.; Aussenegg, F. R. Electromagnetic Energy Transport via Linear Chains of Silver Nanoparticles Opt. Lett. 1998, 23, 1331-1333 10.1364/OL.23.001331
20. Yan, N.; Liu, H.; Zhu, Y.; Jiang, W.; Dong, Z. Entropy-Driven Hierarchical Nanostructures from Cooperative Self-Assembly of Gold Nanoparticles/Block Copolymers under Three-Dimensional Confinement Macromolecules 2015, 48, 5980-5987 10.1021/acs.macromol.5b01219
21. Ku, K. H.; Shin, J. M.; Kim, M. P.; Lee, C.-H.; Seo, M.-K.; Yi, G.-R.; Jang, S. G.; Kim, B. J. Size-Controlled Nanoparticle-Guided Assembly of Block Copolymers for Convex Lens-Shaped Particles J. Am. Chem. Soc. 2014, 136, 9982-9989 10.1021/ja502075f
22. Deng, R. H.; Liang, F. X.; Li, W. K.; Yang, Z. Z.; Zhu, J. T. Reversible Transformation of Nanostructured Polymer Particles Macromolecules 2013, 46, 7012-7017 10.1021/ma401398h
23. Kim, M. P.; Ku, K. H.; Kim, H. J.; Jang, S. G.; Yi, G.-R.; Kim, B. J. Surface Intaglio Nanostructures on Microspheres of Gold-Cored Block Copolymer Spheres Chem. Mater. 2013, 25, 4416-4422 10.1021/cm402868q
24. Klinger, D.; Wang, C. X.; Connal, L. A.; Audus, D. J.; Jang, S. G.; Kraemer, S.; Killops, K. L.; Fredrickson, G. H.; Kramer, E. J.; Hawker, C. J. A Facile Synthesis of Dynamic, Shape-Changing Polymer Particles Angew. Chem., Int. Ed. 2014, 53, 7018-7022 10.1002/anie.201400183
25. Jang, S. G.; Audus, D. J.; Klinger, D.; Krogstad, D. V.; Kim, B. J.; Cameron, A.; Kim, S.-W.; Delaney, K. T.; Hur, S.-M.; Killops, K. L.; Fredrickson, G. H.; Kramer, E. J.; Hawker, C. J. Striped, Ellipsoidal Particles by Controlled Assembly of Diblock Copolymers J. Am. Chem. Soc. 2013, 135, 6649-6657 10.1021/ja4019447
26. Ku, K. H.; Kim, Y.; Yi, G.-R.; Jung, Y. S.; Kim, B. J. Soft Patchy Particles of Block Copolymers from Interface-Engineered Emulsions ACS Nano 2015, 9, 11333-11341 10.1021/acsnano.5b05058
27. Xu, J.; Li, J.; Yang, Y.; Wang, K.; Xu, N.; Li, J.; Liang, R.; Shen, L.; Xie, X.; Tao, J.; Zhu, J. Block Copolymer Capsules with Structure-Dependent Release Behavior Angew. Chem., Int. Ed. 2016, 55, 14633-14637 10.1002/anie.201607982
28. Deng, R. H.; Liang, F. X.; Zhou, P.; Zhang, C. L.; Qu, X. Z.; Wang, Q.; Li, J. L.; Zhu, J. T.; Yang, Z. Z. Janus Nanodisc of Diblock Copolymers Adv. Mater. 2014, 26, 4469-4472 10.1002/adma.201305849
29. Shin, J. M.; Kim, Y.; Yun, H.; Yi, G.-R.; Kim, B. J. Morphological Evolution of Block Copolymer Particles: Effect of Solvent Evaporation Rate on Particle Shape and Morphology ACS Nano 2017, 11, 2133-2142 10.1021/acsnano.6b08342
30. Deng, R.; Liang, F.; Li, W.; Liu, S.; Liang, R.; Cai, M.; Yang, Z.; Zhu, J. Shaping Functional Nano-objects by 3D Confined Supramolecular Assembly Small 2013, 9, 4099-4103 10.1002/smll.201300271
31. Huang, J.; Xiao, Y.; Xu, T. Achieving 3-D Nanoparticle Assembly in Nanocomposite Thin Films via Kinetic Control Macromolecules 2017, 50, 2183-2188 10.1021/acs.macromol.7b00063
32. Thorkelsson, K.; Nelson, J. H.; Alivisatos, A. P.; Xu, T. End-to-End Alignrnent of Nanorods in Thin Films Nano Lett. 2013, 13, 4908-4913 10.1021/nl402862b
33. Kao, J.; Thorkelsson, K.; Bai, P.; Rancatore, B. J.; Xu, T. Toward Functional Nanocomposites: Taking the Best of Nanoparticles, Polymers, and Small Molecules Chem. Soc. Rev. 2013, 42, 2654-2678 10.1039/C2CS35375J
34. Liu, Y.; Li, Y.; He, J.; Duelge, K. J.; Lu, Z.; Nie, Z. Entropy-Driven Pattern Formation of Hybrid Vesicular Assemblies Made from Molecular and Nanoparticle Amphiphiles J. Am. Chem. Soc. 2014, 136, 2602-2610 10.1021/ja412172f
35. Xu, J. P.; Han, Y. Y.; Cui, J.; Jiang, W. Size Selective Incorporation of Gold Nanoparticles in Diblock Copolymer Vesicle Wall Langmuir 2013, 29, 10383-10392 10.1021/la402132x
36. Wang, J.; Li, W.; Zhu, J. Encapsulation of Inorganic Nanoparticles into Block Copolymer Micellar Aggregates: Strategies and Precise Localization of Nanoparticles Polymer 2014, 55, 1079-1096 10.1016/j.polymer.2014.01.027
37. Mackay, M. E.; Tuteja, A.; Duxbury, P. M.; Hawker, C. J.; Van Horn, B.; Guan, Z.; Chen, G.; Krishnan, R. S. General Strategies for Nanoparticle Dispersion Science 2006, 311, 1740-1743 10.1126/science.1122225
38. Mai, Y.; Eisenberg, A. Selective Localization of Preformed Nanoparticles in Morphologically Controllable Block Copolymer Aggregates in Solution Acc. Chem. Res. 2012, 45, 1657-1666 10.1021/ar2003144
39. Mai, Y.; Eisenberg, A. Controlled Incorporation of Particles into the Central Portion of Vesicle Walls J. Am. Chem. Soc. 2010, 132, 10078-10084 10.1021/ja1024063
40. Thompson, R. B.; Ginzburg, V. V.; Matsen, M. W.; Balazs, A. C. Predicting the Mesophases of Copolymer-Nanoparticle Composites Science 2001, 292, 2469-2472 10.1126/science.1060585
41. Xu, J. P.; Zhu, Y. T.; Zhu, J. T.; Jiang, W. Ultralong Gold Nanoparticle/Block Copolymer Hybrid Cylindrical Micelles: A Strategy Combining Surface Templated Self-Assembly and Rayleigh Instability Nanoscale 2013, 5, 6344-6349 10.1039/c3nr01296d
42. Xu, J.; Wang, K.; Li, J.; Zhou, H.; Xie, X.; Zhu, J. ABC Triblock Copolymer Particles with Tunable Shape and Internal Structure through 3D Confined Assembly Macromolecules 2015, 48, 2628-2636 10.1021/acs.macromol.5b00335
43. Bockstaller, M. R.; Lapetnikov, Y.; Margel, S.; Thomas, E. L. Size-Selective Organization of Enthalpic Compatibilized Nanocrystals in Ternary Block Copolymer/Particle Mixtures J. Am. Chem. Soc. 2003, 125, 5276-5277 10.1021/ja034523t
44. Deng, R. H.; Li, H.; Zhu, J. T.; Li, B. H.; Liang, F. X.; Jia, F.; Qu, X. Z.; Yang, Z. Z. Janus Nanoparticles of Block Copolymers by Emulsion Solvent Evaporation Induced Assembly Macromolecules 2016, 49, 1362-1368 10.1021/acs.macromol.5b02507
45. Jeon, S.-J.; Yang, S.-M.; Kim, B. J.; Petrie, J. D.; Jang, S. G.; Kramer, E. J.; Pine, D. J.; Yi, G.-R. Hierarchically Structured Colloids of Diblock Copolymers and Au Nanoparticles Chem. Mater. 2009, 21, 3739-3741 10.1021/cm9011124
46. Bockstaller, M. R.; Lapetnikov, Y.; Margel, S.; Thomas, E. L. Size-Selective Organization of Enthalpic Compatibilized Nanocrystals in Ternary Block Copolymer/Particle Mixtures J. Am. Chem. Soc. 2003, 125, 5276-5277 10.1021/ja034523t
47. Kim, B. J.; Chiu, J. J.; Yi, G. R.; Pine, D. J.; Kramer, E. J. Nanoparticle-Induced Phase Transitions in Diblock-Copolymer Films Adv. Mater. 2005, 17, 2618-2622 10.1002/adma.200500502
48. Chiu, J. J.; Kim, B. J.; Kramer, E. J.; Pine, D. J. Control of Nanoparticle Location in Block Copolymers J. Am. Chem. Soc. 2005, 127, 5036-5037 10.1021/ja050376i
49. Yan, N.; Zhu, Y.; Jiang, W. Self-Assembly of AB Diblock Copolymer Confined in a Soft Nano-Droplet: A Combination Study by Monte Carlo Simulation and Experiment J. Phys. Chem. B 2016, 120, 12023-12029 10.1021/acs.jpcb.6b10170
50. Deng, R.; Li, H.; Liang, F.; Zhu, J.; Li, B.; Xie, X.; Yang, Z. Soft Colloidal Molecules with Tunable Geometry by 3D Confined Assembly of Block Copolymers Macromolecules 2015, 48, 5855-5860 10.1021/acs.macromol.5b01261