Effect of esterification reaction of citric acid and ethylene glycol on the formation of multi-shelled cobalt oxide powders with superior electrochemical properties

Nano Research

Volumn 7, Issue 12, 2014, Pages 1738-1748

  Park, Gi Dae ^a   Lee, Jong Heun ^a   Lee, Jung Kul ^b   Kang, Yun Chan ^a  

^a Korea University   (South Korea)

^b Konkuk University   (South Korea)

Author keywords

energy storage; lithium battery; spray drying; synthesis design; yolk shell

Indexed keywords

EID: 85027931367     PISSN: 19980124     EISSN: 19980000     Source Type: Journal    
DOI: 10.1007/s12274-014-0533-9     Document Type: Article

References (54)

1. 4 nanosheet-assembled multishelled hollow spheres. Adv. Funct. Mater.2010, 20, 1680–1686.
2. 3 multi-shelled hollow microspheres for lithium ion battery anodes with superior capacity and charge retention. Energy Environ. Sci.2014, 7, 632–637.
3. Liu, J.; Hartono, S. B.; Jin, Y. G.; Li, Z.; Lu, G. Q.; Qiao, S. Z. A facile vesicle template route to multi-shelled mesoporous silica hollow nanospheres. J. Mater. Chem.2010, 20, 4595–4601.
4. Sun, Z.; Xie, K. P.; Li, Z. A.; Sinev, I.; Ebbinghaus, P.; Erbe, A.; Farle, M.; Schuhmann, W. G.; Muhler, M.; Ventosa, E. Hollow and yolk-shell iron oxide nanostructures on few-layer graphene in Li-ion batteries. Chem. Eur. J.2014, 20, 2022–2030.
5. Tartaj, P.; Amarilla, J. M. Porous inorganic nanostructures with colloidal dimensions: Synthesis and applications in electrochemical energy devices. Chem. Commun.2014, 50, 2077–2088.
6. 4 microspheres as a 5 V cathode material for lithium-ion batteries. Mater. Chem. Phys.2014, 143, 867–872.
7. Ru, Y.; Evans, D. G.; Zhu, H.; Yang, W. S. Facile fabrication of yolk-shell structured porous Si-C microspheres as effective anode materials for Li-ion batteries. RSC Adv.2014, 4, 71–75.
8. Xie, Q. S.; Zhang, X. Q.; Wu, X. B.; Wu, H.; Liu, X.; Yue, G.; Yang, Y.; Peng, D. L. Yolk-shell ZnO-C microspheres with enhanced electrochemical performance as anode material for lithium ion batteries. Electrochim. Acta2014, 125, 659–665.
9. Lai, X. Y.; Li, J.; Korgel, B. A.; Dong, Z. H.; Li, Z. M.; Su, F.; Du, J.; Wang, D. General synthesis and gas-sensing properties of multiple-shell metal oxide hollow microspheres. Angew. Chem. Int. Ed.2011, 123, 2790–2793.
10. Dong, Z. H.; Lai, X. Y.; Halpert, J. E.; Yang, N.; Yi, L.; Zhai, J.; Wang, D.; Tang, Z.; Jiang, L. Accurate control of multishelled ZnO hollow microspheres for dye-sensitized solar cells with high efficiency. Adv. Mater.2012, 24, 1046–1049.
11. 4 hollow microspheres as high-performance anode materials in lithium-ion batteries. Angew. Chem. Int. Ed.2013, 52, 6417–6420.
12. 2 hollow microspheres with superior light scattering for high-performance dye-sensitized solar cells. Adv. Mater.2014, 26, 905–909.
13. Li, Z. M.; Lai, X. Y.; Wang, H.; Mao, D.; Xing, C. J.; Wang, D. General synthesis of homogeneous hollow core-shell ferrite microspheres. J. Phys. Chem. C2009, 113, 2792–2797.
14. 2 yolk-shell-structured powders by continuous process as anode materials for Li-ion batteries. Adv. Mater.2013, 25, 2279–2283.
15. 5 powders with low melting temperature for high performance Li-ion batteries. Nanoscale2013, 5, 8899–8903.
16. Choi, S. H.; Kang, Y. C. Ultrafast synthesis of yolk-shell and cubic NiO nanopowders and application in lithium ion batteries. ACS Appl. Mater. Interfaces2014, 26, 2312–2316.
17. Choi, S. H.; Kang, Y. C. Synthesis of yolk-shell-structured metal sulfide powders with excellent electrochemical performances for lithium-ion batteries. Small2014, 10, 474–478.
18. 4 systems with the optimum composition for superior electrochemical properties. Chem. Eur. J.2014, 20, 3014–3018.
19. 3 multi-shelled hollow spheres as high-performance anode materials for lithium ion batteries. Chem. Commun.2013, 49, 8695–8697.
20. 2 yolk-shell powders by a spray-drying process using dextrin as carbon source and drying additive. Chem. Eur. J.2014, 20, 5835–5839.
21. 4 mesoporous nanosheets prepared by a simple spray-drying process and their electrochemical properties as anode material for lithium secondary batteries. Electrochim. Acta2014, 116, 44–50.
22. Chen, J. S.; Zhu, T.; Hu, Q. H.; Gao, J. J.; Su, F.; Qiao, S. Z.; Lou, X. W. Shape-controlled synthesis of cobalt-based nanocubes, nanodiscs, and nanoflowers and their comparative lithium-storage properties. ACS Appl. Mater. Interfaces2010, 2, 3628–3625.
23. 4 nanowire arrays anode with high rate capability and excellent cycling stability for lithium-ion batteries. Electrochim. Acta2014, 135, 35–41.
24. 2O and their lithium-storage properties. Adv. Funct. Mater.2012, 22,861–871.
25. 4@carbon nanocomposites. ACS Nano2010, 4, 4753–4761.
26. 4 nanowire array electrodes. Nano Res.2010, 3, 895–901.
27. Zhang, M.; Uchaker, E.; Hu, S.; Zhang, Q.; Wang, T.; Cao, G. Z.; Li, J. CoO-carbon nanofiber networks prepared by electrospinning as binder-free anode materials for lithiumion batteries with enhanced properties. Nanoscale2013, 5, 12342–12349.
28. 4 yolk-shell powders with a filled core and multishells prepared by a one-pot spray pyrolysis. Chem. Commun.2013, 49, 5678–5680.
29. Zhang, M.; Yan, F.; Tang, X.; Li, Q. H.; Wang, T. H.; Cao, G. Z. Flexible CoO-graphene-carbon nanofiber mats as binder-free anodes for lithium-ion batteries with superior rate capacity and cyclic stability. J. Mater. Chem. A2014, 2, 5890–5897.
30. Peng, C. X.; Chen, B. D.; Qin, Y.; Yang, S.; Li, C. Z.; Zuo, Y. H.; Liu. S. Y.; Yang, J. H. Facile ultrasonic synthesis of CoO quantum dot/graphene nanosheet composites with high Lithium storage capacity. ACS Nano2012, 6, 1074–1081.
31. Yang, S. B.; Cui, G. L.; Pang, S. P.; Cao, Q.; Kolb, U.; Feng, X. L.; Maier, J.; Mullen, K. Fabrication of cobalt and cobalt oxide/graphene composites: Towards high-performance anode materials for Lithium ion batteries. ChemSusChem2010, 3, 236–239.
32. 4/carbon nanotube anodes for lithium ion battery applications. J. Mater. Chem. A2013, 1, 11121–11125.
33. Chen, C. H.; Hwang, B. J.; Do, J. S.; Weng, J. H.; Venkateswarlu, M.; Cheng, M. Y.; Santhanam, R.; Ragavendran, K.; Lee, J. F.; Chen, J. M. et al. An understanding of anomalous capacity of nano-sized CoO anode materials for advanced Li-ion battery. Electrochem. Commun.2010, 12, 496–498.
34. 4 nanostructures: Synthesis and characterization. J. Power Sources2012, 200, 53–58.
35. 4 nano-needles and their lithium storage properties. J. Mater. Chem.2008, 18, 4397–4401.
36. 4 anode with enhanced rate capability for lithium-ion batteries. ACS Appl. Mater. Interfaces2014, 6, 7236–7243.
37. Huang, X. L.; Wang, R. Z.; Xu, D.; Wang, Z. L.; Wang, H. G.; Xu, J. J.; Wu, Z.; Liu, Q. C.; Zhang, Y.; Zhang, X. B. Homogeneous CoO on graphene for binder-free and ultralong-life lithium ion batteries. Adv. Funct. Mater.2013, 23, 4345–4353.
38. 4 and CoO-carbon composite powders prepared by two-step spray drying process. Nanoscale2014, 6, 4789–4795.
39. 4/carbon composite nanowires and their electrochemical properties. J. Power Sources2011, 196, 6987–6991.
40. 4/graphene nanocomposite as an anode material for secondary lithium ion battery. Electrochim. Acta2013, 100, 63–71.
41. 2 cathode powders prepared by spray pyrolysis. Ceram. Inter.2009, 35, 1205–1210.
42. 12 anode powders prepared by spray pyrolysis. J. Alloys Compd.2010, 506, 913–916.
43. 2/citric acid/ethylene glycol system by solution state 87Sr nuclear magnetic resonance spectroscopy. J. Mater. Res.2000, 15, 2393–2399.
44. 3:Eu phosphor particles prepared by spray pyrolysis. Jpn. J. Appl. Phys.2006, 45, 9083–9087.
45. 3:Eu phosphor particles prepared from spray solution containing boric acid flux and polymeric precursor by spray pyrolysis. Optic. Mater.2006, 28, 530–535.
46. 3:Eu phosphor particles with cubic and monoclinic phases prepared by high-temperature spray pyrolysis. Jpn. J. Appl. Phys.2006, 45, 5018–5022.
47. Kang, Y. C.; Roh, H. S.; Park, S. B.; Jung, K. Y. Red-emitting phosphor particles with spherical shape, dense morphology, and high luminescent efficiency under ultraviolet. Jpn. J. Appl. Phys.2004, 43, 5302–5306.
48. Bujans, F. B.; Martinez, R.; Ortiz, P. Structural characterization of oligomers from the polycondensation of citric acid with ethylene glycol and long-chain aliphatic alcohols. J. Appl. Poly. Sci.2003, 88, 302–306.
49. Ko, Y. N.; Park, S. B.; Jung, K. Y.; Kang, Y. C. One-pot facile synthesis of ant-cave-structured metal oxide-carbon microballs by continuous process for use as anode materials in Li-ion batteries. Nano Lett.2013, 13, 5462–5466.
50. Li, G.; Xu, L.; Hao, Q.; Wang, M.; Qian, Y. Synthesis, characterization and application of carbon nanocages as anode materials for high-performance lithium-ion batteries. RSC Adv.2012, 2, 284–291.
51. 3/C microspheres. J. Mater. Chem.2012, 22, 5960–5969.
52. Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature2000, 407, 496–499.
53. 4 (A = Co, Ni, and Zn). J. Mater. Chem.2011, 21, 10206–10218.
54. 2 composites with low content of graphene as high-rate lithium storage materials. J. Mater. Chem. A2013, 1, 14548–14554.