Energetic evaluation of hydrogen storage in metal hydrides

International Journal of Energy Research

Volumn 40, Issue 13, 2016, Pages 1820-1831

  Adametz, Patrick ^a   Müller, Karsten ^a   Arlt, Wolfgang ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

efficiency; electricity storage; energy balance; hydrogen; metal hydride; storage; thermodynamic evaluation

Indexed keywords

EID: 85027927366     PISSN: 0363907X     EISSN: 1099114X     Source Type: Journal    
DOI: 10.1002/er.3563     Document Type: Article

References (50)

1. Huot J. Metal Hydrides. In Handbook of Hydrogen Storage: New Materials for Future Energy Storage. Wiley VCH: Weinheim, 2010; 81–116.
2. Sakintuna B, Lamari-Darkrim F, Hirscher M. Metal hydride materials for solid hydrogen storage: a review. International Journal of Hydrogen Energy 2007; 32:1121–1140. doi:10.1016/j.ijhydene.2006.11.022.
3. de Rango P, Chaise A, Charbonnier J, Fruchart D, Jehan M, Marty P, et al. Nanostructured magnesium hydride for pilot tank development. Journal of Alloys and Compounds 2007; 446:52–57. doi:10.1016/j.jallcom.2007.01.108.
4. Jehan M, Fruchart D. McPhy-Energy's proposal for solid state hydrogen storage materials and systems. Journal of Alloys and Compounds 2013; 580:S343–S348. doi:10.1016/j.jallcom.2013.03.266.
5. Liang G, Huot J, Boily S, Van Neste A, Schulz R. Catalytic effect of transition metals on hydrogen sorption in nanocrystalline ball milled MgH2-Tm (Tm = Ti, V, Mn, Fe and Ni) systems. Journal of Alloys and Compounds 1999; 292:247–252. doi:10.1016/S0925-8388(99)00442-9.
6. Zaluska A, Zaluski L, Strom-Olsen JO. Nanocrystalline magnesium for hydrogen storage. Journal of Alloys and Compounds 1999; 288:217–225. doi:10.1016/S0925-8388(99)00073-0.
7. Dehouche Z, Klassen T, Oelerich W, Goyette J, Bose TK, Schulz R. Cycling and thermal stability of nanostructured MgH2-Cr2O3 composite for hydrogen storage. Journal of Alloys and Compounds 2002; 347:319–323. doi:10.1016/S0925-8388(02)00784-3.
8. Bogdanovic B, Schwickardi M. Ti-doped alkali metal aluminium hydrides as potential novel reversible hydrogen storage materials. Journal of Alloys and Compounds 1997; 253:1–9. doi:10.1016/S0925-8388(96)03049-6.
9. Bogdanovic B, Brand RA, Marjanovic A, Schwickardi M, Tolle J. Metal-doped sodium aluminium hydrides as potential new hydrogen storage materials. Journal of Alloys and Compounds 2000; 302:36–58. doi:10.1016/S0925-8388(99)00663-5.
10. Sandrock G, Gross K, Thomas G. Effect of Ti-catalyst content on the reversible hydrogen storage properties of the sodium alanates. Journal of Alloys and Compounds 2002; 339:299–308. doi:10.1016/S0925-8388(01)02014-X.
11. Srinivasan SS, Brinks HW, Hauback BC, Sun DL, Jensen CM. Long term cycling behavior of titanium doped NaAlH4 prepared through solvent mediated milling of NaH and Al with titanium dopant precursors. Journal of Alloys and Compounds 2004; 377:283–289. doi:10.1016/j.jallcom.2004.01.044.
12. Bogdanovic B, Felderhoff M, Pommerin A, Schuth F, Spielkamp N, Stark A. Cycling properties of Sc- and Ce-doped NaAlH4 hydrogen storage materials prepared by the one-step direct synthesis method. Journal of Alloys and Compounds 2009; 471:383–386. doi:10.1016/j.jallcom.2008.03.106.
13. Dehouche Z, Djaozandry R, Huot J, Boily S, Goyette J, Bose TK, et al. Influence of cycling on the thermodynamic and structure properties of nanocrystalline magnesium based hydride. Journal of Alloys and Compounds 2000; 305:264–271. doi:10.1016/S0925-8388(00)00718-0.
14. Reiser A, Bogdanovic B, Schlichte K. The application of Mg-based metal-hydrides as heat energy storage systems. International Journal of Hydrogen Energy 2000; 25:425–430. doi:10.1016/S0360-3199(99)00057-9.
15. Satyapal S, Petrovic J, Read C, Thomas G, Ordaz G. The US Department of Energy's National Hydrogen Storage Project: progress towards meeting hydrogen-powered vehicle requirements. Catalysis Today 2007; 120:246–256. doi:10.1016/j.cattod.2006.09.022.
16. Klebanoff LE, Keller JO. 5 years of hydrogen storage research in the U.S. DOE Metal Hydride Center of Excellence (MHCoE). International Journal of Hydrogen Energy 2013; 38:8022–8022. doi:10.1016/j.ijhydene.2013.04.105.
17. O'Malley K, Ordaz G, Adams J, Randolph K, Ahn CC, Stetson NT. Applied hydrogen storage research and development: a perspective from the US Department of Energy. Journal of Alloys and Compounds 2015; 645:S419–S422. doi:10.1016/j.jallcom.2014.12.090.
18. Ahluwalia RK, Hua TQ, Peng JK. On-board and off-board performance of hydrogen storage options for light-duty vehicles. International Journal of Hydrogen Energy 2012; 37:2891–2910. doi:10.1016/j.ijhydene.2011.05.040.
19. Lototskyy M, Yartys VA. Comparative analysis of the efficiencies of hydrogen storage systems utilising solid state H storage materials. Journal of Alloys and Compounds 2015; 645:S365–S373. doi:10.1016/j.jallcom.2014.12.107.
20. Huot J, Liang G, Boily S, Van Neste A, Schulz R. Structural study and hydrogen sorption kinetics of ball-milled magnesium hydride. Journal of Alloys and Compounds 1999; 293:495–500. doi:10.1016/S0925-8388(99)00474-0.
21. Baehr HD, Kabelac S. Thermodynamik—Grundlagen und technische Anwendungen. Springer-Verlag: Berlin, 2012.
22. Andreasen A. Predicting formation enthalpies of metal hydrides, Risø National Laboratory. Roskilde, 2004.
23. Luo WF, Gross KJ. A kinetics model of hydrogen absorption and desorption in Ti-doped NaAlH4. Journal of Alloys and Compounds 2004; 385:224–231. doi:10.1016/j.jallcom.2004.05.004.
24. Utz I, Schmidt N, Wörner A, Hu JJ, Zabara O, Fichtner M. Experimental results of an air-cooled lab-scale H-2 storage tank based on sodium alanate. International Journal of Hydrogen Energy 2011; 36:3556–3565. doi:10.1016/j.ijhydene.2010.12.057.
25. Ahluwalia RK. Sodium alanate hydrogen storage system for automotive fuel cells. International Journal of Hydrogen Energy 2007; 32:1251–1261. doi:10.1016/j.ijhydene.2006.07.027.
26. Barbir F. PEM electrolysis for production of hydrogen from renewable energy sources. Solar Energy 2005; 78:661–669. doi:10.1016/j.solener.2004.09.003.
27. Heinzel A. Position of polymer-electrolyte-membrane-fuel cells—a review. Chemie Ingenieur Technik 2009; 81:567–571. doi:10.1002/cite.200900032.
28. Barbir F, Gomez T. Efficiency and economics of proton exchange membrane (PEM) fuel cells. International Journal of Hydrogen Energy 1997; 22:1027–1037. doi:10.1016/S0360-3199(96)00175-9.
29. American Petroleum Institute. Standard 681. Reciprocating Compressors for Petroleum, Chemical, and Gas Industry Services. Washington, 2013.
30. Delhomme B, de Rango P, Marty P, Bacia M, Zawilski B, Raufast C, et al. Large scale magnesium hydride tank coupled with an external heat source. International Journal of Hydrogen Energy 2012; 37:9103–9111. doi:10.1016/j.ijhydene.2012.03.018.
31. Chaise A, de Rango P, Marty P, Fruchart D. Experimental and numerical study of a magnesium hydride tank. International Journal of Hydrogen Energy 2010; 35:6311–6322. doi:10.1016/j.ijhydene.2010.03.057.
32. Garrier S, Chaise A, de Rango P, Marty P, Delhomme B, Fruchart D, et al. MgH2 intermediate scale tank tests under various experimental conditions. International Journal of Hydrogen Energy 2011; 36:9719–9726. doi:10.1016/j.ijhydene.2011.05.017.
33. Müller K, Geng J, Völkl J, Arlt W. Energetische Betrachtung der Wasserstoffeinspeisung ins Erdgasnetz. Chemie Ingenieur Technik 2012; 84:1513–1519. doi:10.1002/cite.201200023.
34. Chase MW, Davies CA, Downey JR, Frurip DJ, Mcdonald RA, Syverud AN. Janaf Thermochemical Tables—3rd Edition. Journal of Physical and Chemical Reference Data 1985; 14:1–1856.
35. Dornheim M, Doppiu S, Barkhordarian G, Boesenberg U, Klassen T, Gutfleisch O, et al. Hydrogen storage in magnesium-based hydrides and hydride composites. Scripta Materialia 2007; 56:841–846. doi:10.1016/j.scriptamat.2007.01.003.
36. Reiser A. Untersuchung der Systeme Mg/MgH2und Mg-Fe/Mg2FeH6als Wärmespeichermaterialien in einem Temperaturbereich um 500 °C. Ph.D. Thesis, University Erlangen-Nuremberg, 1998.
37. Yiotis AG, Kainourgiakis ME, Kosmidis LI, Charalambopoulou GC, Stubos AK. Thermal coupling potential of solid oxide fuel cells with metal hydride tanks: thermodynamic and design considerations towards integrated systems. Journal of Power Sources 2014; 269:440–450. doi:10.1016/j.jpowsour.2014.07.023.
38. Qiu CA, Opalka SM, Olson GB, Anton DL. Thermodynamic modeling of the sodium alanates and the Na-Al-H system. International Journal of Materials Research 2006; 97:1484–1494. doi:10.1016/j.calphad.2008.08.005.
39. Bonnetot B, Chahine G, Claudy P, Diot M, Letoffe JM. Sodium tetrahydridoaluminate NaAlH4 and hexahydridoaluminate Na3AlH6 molar heat-capacity and thermodynamic properties from 10 to 300-K. Journal of Chemical Thermodynamics 1980; 12:249–254. doi:10.1016/0021-9614(80)90043-9.
40. Haynes WM. Handbook of Chemistry and Physics. Taylor & Francis Ltd: New York, 2012.
41. Mendelsohn MH, Gruen DM, Dwight AE. LaNi5-xAlx is a versatile alloy system for metal hydride applications. Nature 1977; 269:45–47. doi:10.1038/269045a0.
42. Yiotis AG, Kainourgiakis ME, Charalambopoulou GC, Stubos AK. A generic physical model for a thermally integrated high-temperature PEM fuel cell and sodium alanate tank system. International Journal of Hydrogen Energy 2015; 40:14551–14561. doi:10.1016/j.ijhydene.2015.05.186.
43. Delhomme B, Lanzini A, Ortigoza-Villalba GA, Nachev S, de Rango P, Santarelli M, et al. Coupling and thermal integration of a solid oxide fuel cell with a magnesium hydride tank. International Journal of Hydrogen Energy 2013; 38:4740–4747. doi:10.1016/j.ijhydene.2013.01.140.
44. Verhelst S, Wallner T. Hydrogen-fueled internal combustion engines. Progress in Energy and Combustion Science 2009; 35:490–527. doi:10.1016/j.pecs.2009.08.001.
45. Zalba B, Marin JM, Cabeza LF, Mehling H. Review on thermal energy storage with phase change: materials, heat transfer analysis and applications. Applied Thermal Engineering 2003; 23:251–283. doi:10.1016/S1359-4311(02)00192-8.
46. Eberle U, Felderhoff M, Schuth F. Chemical and physical solutions for hydrogen storage. Angewandte Chemie-International Edition 2009; 48:6608–6630. doi:10.1002/anie.200806293.
47. Klell M. Storage of Hydrogen in the Pure Form. In Handbook of Hydrogen Storage: New Materials for Future Energy Storage. Wiley VCH: Weinheim, 2010; 1–37.
48. Jensen JO, Vestbo AP, Li Q, Bjerrum NJ. The energy efficiency of onboard hydrogen storage. Journal of Alloys and Compounds 2007; 446:723–728. doi:10.1016/j.jallcom.2007.04.051.
49. Adametz P, Müller K, Arlt W. Efficiency of low-temperature adsorptive hydrogen storage systems. International Journal of Hydrogen Energy 2014; 39:15604–15613. doi:10.1016/j.ijhydene.2014.07.157.
50. Müller K, Geng J, Arlt W. Reversible vs. irreversible conversion of hydrogen: how to store energy efficiently? Energy Technology 2013; 1:42–47. doi:10.1002/ente.201200022.