MnM2O4 microspheres (M = Co, Cu, Ni) for selective catalytic reduction of NO with NH3: Comparative study on catalytic activity and reaction mechanism via in-situ diffuse reflectance infrared Fourier transform spectroscopy

Chemical Engineering Journal

Volumn 325, Issue , 2017, Pages 91-100

  Gao, Ge ^a   Shi, Jian Wen ^a   Fan, Zhaoyang ^a   Gao, Chen ^a   Niu, Chunming ^a  

^a XI'AN JIAOTONG UNIVERSITY   (China)

Author keywords

Ammonia; Low temperature; MnOx; NOx; Selective catalytic reduction

Indexed keywords

AMMONIA; BROMINE COMPOUNDS; CATALYST ACTIVITY; COBALT METALLOGRAPHY; COPPER COMPOUNDS; COPPER METALLOGRAPHY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; INDIUM COMPOUNDS; MANGANESE COMPOUNDS; MICROSPHERES; NICKEL COMPOUNDS; NICKEL METALLOGRAPHY; NITROGEN OXIDES; REDUCTION; REFLECTION; TEMPERATURE;

COMPARATIVE STUDIES; GAS HOURLY SPACE VELOCITIES; HYDROTHERMAL METHODS; LANGMUIR-HINSHELWOOD; LOW TEMPERATURES; MNOX; SELECTIVE CATALYTIC REDUCTION OF NO; SITU DIFFUSE REFLECTANCE INFRARED FOURIER TRANSFORM SPECTROSCOPY;

SELECTIVE CATALYTIC REDUCTION;

EID: 85019204241     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2017.05.059     Document Type: Article

References (49)

1. [1] Topsøe, N.Y., Mechanism of the selective catalytic reduction of nitric oxide by ammonia elucidated by in situ on-line Fourier transform infrared spectroscopy. Science 265 (1994), 1217–1219.
2. [2] Mou, X., Zhang, B., Li, Y., Yao, L., Wei, X., Su, D.S., Shen, W., Rod-shaped Fe2O3 as an efficient catalyst for the selective reduction of nitrogen oxide by ammonia. Angew. Chem. Int. Ed. 51 (2012), 2989–2993.
3. [3] Yang, S., Li, J., Wang, C., Chen, J., Ma, L., Chang, H., Chen, L., Peng, Y., Yan, N., Fe-Ti spinel for the selective catalytic reduction of NO with NH3: mechanism and structure-activity relationship. Appl. Catal. B 117–118 (2012), 73–80.
4. [4] Thirupathi, B., Smirniotis, P.G., Nickel-doped Mn/TiO2 as an efficient catalyst for the low-temperature SCR of NO with NH3: catalytic evaluation and characterizations. J. Catal. 288 (2012), 74–83.
5. [5] Peña, D.A., Uphade, B.S., Reddy, E.P., Smirniotis, P.G., Identification of surface species on titania-supported manganese, chromium, and copper oxide low-temperature SCR catalysts. J. Phys. Chem. B 108 (2004), 9927–9936.
6. [6] Yang, S., Fu, Y., Liao, Y., Xiong, S., Qu, Z., Yan, N., Competition of selective catalytic reduction and non selective catalytic reduction over MnOx/TiO2 for NO removal: the relationship between gaseous NO concentration and N2O selectivity. Catal. Sci. Technol., 4, 2014, 224.
7. [7] Ettireddy, P.R., Ettireddy, N., Mamedov, S., Boolchand, P., Smirniotis, P.G., Surface characterization studies of TiO2 supported manganese oxide catalysts for low temperature SCR of NO with NH3. Appl. Catal. B 76 (2007), 123–134.
8. [8] Thirupathi, B., Smirniotis, P.G., Co-doping a metal (Cr, Fe Co, Ni, Cu, Zn, Ce, and Zr) on Mn/TiO2 catalyst and its effect on the selective reduction of NO with NH3 at low-temperatures. Appl. Catal. B 110 (2011), 195–206.
9. [9] Meng, B., Zhao, Z., Chen, Y., Wang, X., Li, Y., Qiu, J., Low-temperature synthesis of Mn-based mixed metal oxides with novel fluffy structures as efficient catalysts for selective reduction of nitrogen oxides by ammonia. Chem. Commun. 50 (2014), 12396–12399.
10. [10] Kang, M., Park, E.D., Kim, J.M., Yie, J.E., Cu-Mn mixed oxides for low temperature NO reduction with NH3. Catal. Today 111 (2006), 236–241.
11. [11] Hu, H., Cai, S., Li, H., Huang, L., Shi, L., Zhang, D., Mechanistic aspects of deNOx processing over TiO2 supported Co–Mn oxide catalysts: structure–activity relationships and in situ DRIFTs analysis. ACS Catal. 5 (2015), 6069–6077.
12. [12] Chen, Y., Wang, J., Yan, Z., Liu, L., Zhang, Z., Wang, X., Promoting effect of Nd on the reduction of NO with NH3 over CeO2 supported by activated semi-coke: an in situ DRIFTS study. Catal. Sci. Technol. 5 (2015), 2251–2259.
13. [13] Gao, G., Shi, J., Liu, C., Gao, C., Fan, Z., Niu, C., Mn/CeO2 catalysts for SCR of NOx with NH3: comparative study on the effect of supports on low-temperature catalytic activity. Appl. Surf. Sci. 411 (2017), 338–346.
14. [14] Grossale, A., Nova, I., Tronconi, E., Chatterjee, D., Weibel, M., The chemistry of the NO/NO2-NH3 “fast” SCR reaction over Fe-ZSM5 investigated by transient reaction analysis. J. Catal. 256 (2008), 312–322.
15. [15] Kijlstra, W.S., Brands, D.S., Poels, E.K., Bliek, A., Kinetics of the selective catalytic reduction of NO with NH3 over MnOx/Al2O3 catalysts at low temperature. Catal. Today 50 (1999), 133–140.
16. [16] Long, R.Q., Yang, R.T., Chang, R., Low temperature selective catalytic reduction (SCR) of NO with NH3 over Fe-Mn based catalysts. Chem. Commun., 2002, 452–453.
17. [17] Liu, C., Shi, J., Gao, C., Niu, C., Manganese oxide-based catalysts for low-temperature selective catalytic reduction of NOx with NH3: a review. Appl. Catal. A 522 (2016), 54–69.
18. [18] Kruk, M., Jaroniec, M., Gas adsorption characterization of ordered organic-inorganic nanocomposite materials. Chem. Mater. 13 (2001), 3169–3183.
19. [19] Kapteijn, F., Singoredjo, L., Andreini, A., Moulijn, J.A., Activity and selectivity of pure manganese oxides in the selective catalytic reduction of nitric oxide with ammonia. Appl. Catal. B 3 (1994), 173–189.
20. [20] Meng, D., Zhan, W., Guo, Y., Guo, Y., Wang, L., Lu, G., A highly effective catalyst of Sm-MnOx for the NH3-SCR of NOx at low temperature: promotional role of Sm and its catalytic performance. ACS Catal. 5 (2015), 5973–5983.
21. [21] Machocki, A., Ioannides, T., Stasinska, B., Gac, W., Avgouropoulos, G., Delimaris, D., Grzegorczyk, W., Pasieczna, S., Manganese–lanthanum oxides modified with silver for the catalytic combustion of methane. J. Catal. 227 (2004), 282–296.
22. [22] Tang, X., Li, Y., Huang, X., Xu, Y., Zhu, H., Wang, J., Shen, W., MnOx-CeO2 mixed oxide catalysts for complete oxidation of formaldehyde: Effect of preparation method and calcination temperature. Appl. Catal. B 62 (2006), 265–273.
23. [23] Kang, M., Park, E.D., Kim, J.M., Yie, J.E., Manganese oxide catalysts for NOx reduction with NH3 at low temperatures. Appl. Catal. A 327 (2007), 261–269.
24. [24] Wallin, M., Karlsson, C., Skoglundh, M., Palmqvist, A., Selective catalytic reduction of NOx with NH3 over zeolite H-ZSM-5: influence of transient ammonia supply. J. Catal. 218 (2003), 354–364.
25. [25] Qi, G., Yang, R.T., Chang, R., MnOx-CeO2 mixed oxides prepared by co-precipitation for selective catalytic reduction of NO with NH3 at low temperatures. Appl. Catal. B 51 (2004), 93–106.
26. [26] Zhang, L., Zhang, D., Zhang, J., Cai, S., Fang, C., Huang, L., Li, H., Gao, R., Shi, L., Design of meso-TiO2@MnOx–CeOx/CNTs with a core–shell structure as DeNOx catalysts: promotion of activity, stability and SO2-tolerance. Nanoscale, 5, 2013, 9821.
27. [27] Liu, F., Asakura, K., He, H., Shan, W., Shi, X., Zhang, C., Influence of sulfation on iron titanate catalyst for the selective catalytic reduction of NOx with NH3. Appl. Catal. B 103 (2011), 369–377.
28. [28] Wu, Z., Jiang, B., Liu, Y., Wang, H., Jin, R., DRIFT study of manganese/titania-based catalysts for low-temperature selective catalytic reduction of NO with NH3. Environ. Sci. Technol. 41 (2007), 5812–5817.
29. [29] Zhang, L., Li, L., Cao, Y., Xiong, Y., Wu, S., Sun, J., Tang, C., Gao, F., Dong, L., Promotional effect of doping SnO2 into TiO2 over a CeO2/TiO2 catalyst for selective catalytic reduction of NO by NH3. Catal. Sci. Technol., 5, 2015, 2188.
30. [30] Chen, L., Li, J., Ge, M., DRIFT study on cerium-tungsten/titiania catalyst for selective catalytic reduction of NOx with NH3. Sci. Technol. 44 (2010), 9590–9596.
31. [31] Zhan, S., Zhang, H., Zhang, Y., Shi, Q., Li, Y., Li, X., Efficient NH3-SCR removal of NOx with highly ordered mesoporous WO3(χ)-CeO2 at low temperatures. Appl. Catal. B 203 (2017), 199–209.
32. [32] Zhan, S., Qiu, M., Yang, S., Zhu, D., Yu, H., Li, Y., Facile preparation of MnO2 doped Fe2O3 hollow nanofibers for low temperature SCR of NO with NH3. J. Mater. Chem. A 2 (2014), 20486–20493.
33. [33] Yang, S., Wang, C., Li, J., Yan, N., Ma, L., Chang, H., Low temperature selective catalytic reduction of NO with NH3 over Mn-Fe spinel: performance, mechanism and kinetic study. Appl. Catal. B 110 (2011), 71–80.
34. [34] Yang, N., Guo, R., Pan, W., Chen, Q., Wang, Q., Lu, C., The promotion effect of Sb on the Na resistance of Mn/TiO2 catalyst for selective catalytic reduction of NO with NH3. Fuel 169 (2016), 87–92.
35. [35] Liu, J., Li, X., Zhao, Q., Ke, J., Xiao, H., Lv, X., Liu, S., Tadé, M., Wang, S., Mechanistic investigation of the enhanced NH3-SCR on cobalt-decorated Ce-Ti mixed oxide: in situ FTIR analysis for structure-activity correlation. Appl. Catal. B 200 (2017), 297–308.
36. [36] Qi, G., Yang, R.T., Characterization and FTIR studies of MnOx-CeO2 catalyst for low-temperature selective catalytic reduction of NO with NH3. J. Phys. Chem. B 108 (2004), 15738–15747.
37. [37] Gu, T., Jin, R., Liu, Y., Liu, H., Weng, X., Wu, Z., Promoting effect of calcium doping on the performances of MnOx/TiO2 catalysts for NO reduction with NH3 at low temperature. Appl. Catal. B 129 (2013), 30–38.
38. [38] Li, Y., Wan, Y., Li, Y., Zhan, S., Guan, Q., Tian, Y., Low-temperature selective catalytic reduction of NO with NH3 over Mn2O3-doped Fe2O3 hexagonal microsheets. ACS Appl. Mater. Interface 8 (2016), 5224–5233.
39. [39] Zhang, L., Shi, L., Huang, L., Zhang, J., Gao, R., Zhang, D., Rational design of high-performance deNOx catalysts based on MnxCo3–xO4 nanocages derived from metal–organic frameworks. ACS Catal. 4 (2014), 1753–1763.
40. [40] Gao, R., Zhang, D., Liu, X., Shi, L., Maitarad, P., Li, H., Zhang, J., Cao, W., Enhanced catalytic performance of V2O5-WO3/Fe2O3/TiO2 microspheres for selective catalytic reduction of NO by NH3. Catal. Sci. Technol. 3 (2013), 191–199.
41. [41] Cao, F., Xiang, J., Su, S., Wang, P., Hu, S., Sun, L., Ag modified Mn–Ce/γ-Al2O3 catalyst for selective catalytic reduction of NO with NH3 at low-temperature. Fuel Process. Technol. 135 (2015), 66–72.
42. [42] Klingenberg, B., Vannice, M.A., NO adsorption and decomposition on La2O3 studied by DRIFTS. Appl. Catal. B 21 (1999), 19–33.
43. [43] Hadjiivanov, K., Knözinger, H., Species formed after NO adsorption and NO + O2 co-adsorption on TiO2: an FTIR spectroscopic study. Phys. Chem. Chem. Phys. 2 (2000), 2803–2806.
44. [44] Zhou, G., Zhong, B., Wang, W., Guan, X., Huang, B., Ye, D., Wu, H., In situ DRIFTS study of NO reduction by NH3 over Fe-Ce-Mn/ZSM-5 catalysts. Catal. Today 175 (2011), 157–163.
45. [45] Liu, Y., Gu, T., Weng, X., Wang, Y., Wu, Z., Wang, H., DRIFT studies on the selectivity promotion mechanism of Ca-modified Ce-Mn/TiO2 catalysts for low-temperature NO reduction with NH3. J. Phys. Chem. C 116 (2012), 16582–16592.
46. [46] Liu, C., Gao, G., Shi, J., He, C., Li, G., Bai, N., Niu, C., MnOx-CeO2 shell-in-shell microspheres for NH3-SCR de-NOx at low temperature. Catal. Commun. 86 (2016), 36–40.
47. [47] Kijlstra, W.S., Brands, D.S., Poels, E.K., Bliek, A., Mechanism of the selective catalytic reduction of NO by NH3 over MnOx/Al2O3. J. Catal. 171 (1997), 208–218.
48. [48] Marbán, G., Fuertes, A.B., Kinetics of the low-temperature selective catalytic reduction of NO with NH3 over activated carbon fiber composite-supported iron oxides. Catal. Lett. 1–2 (2002), 13–19.
49. [49] Jiang, B., Li, Z., Lee, S., Mechanism study of the promotional effect of O2 on low-temperature SCR reaction on Fe-Mn/TiO2 by DRIFT. Chem. Eng. J. 225 (2013), 52–58.