In-situ FTIR and SSNMR study of photocatalytic degradation of 2-CEES and DMMP on zirconium-doped TiO2

Journal of Molecular Catalysis

Volumn 30, Issue 3, 2016, Pages 260-268

  Shen, Zhong ^a,b   Zhong, Jin Yi ^a,c   Wang, Ling Yun ^a   Zheng, Yong Chao ^a   Cui, Yan ^a,c   Chen, Li Kun ^a  

^a RESEARCH INSTITUTE OF CHEMICAL DEFENSE   (China)

^b NORTHWEST INSTITUTE OF NUCLEAR TECHNOLOGY   (China)

^c STATE KEY LABORATORY OF NBC PROTECTION FOR CIVILIAN   (China)

Author keywords

Chemical Warfare Agents; Decontamination; In situ FTIR; SSNMR; Titanium dioxide

Indexed keywords

EID: 85013994861     PISSN: 10013555     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (29)

1. Bizzigotti G O Rhoads R P, Lee S J, et al. Zhong Jin-yi, Guo Nan, Cui Yan, et al. Handbook of Chemical and Biological Warfareagent Decontamination[M]. Beijing: Yi Wen Publishing Military, 2014, 55/58: 161-174.
2. Sato K, Hirakawa T, Komano A, et al. Titanium dioxide photocatalysis to decompos-eisopropylmethylphosphonofluoridate (GB) in gas phase[J]. Appl Catal B: Envir, 2011, 106(3/4): 316-322.
3. Zhao San-ping, Xi Hai-ling, Zuo Yan-jun, et al. Oxidation kinetics and products of methyl phenyl sulfide, a sulfur mustard simulant by sodium molybdate catalyzed hydrogen peroxide solution [J]. J Mol Catal (China), 2015, 29(1): 45-51.
4. Zhou Wei, Hu Xiao-long, Zhao Xiao-rong, et al. Preparation of graphene-BiOBr composite and the enhanced photocatalytic activity under visible-light irradiation[J]. J Mol Catal (China), 2014, 28(4): 367-375.
5. Wagner G W, Chen Q, Wu Y. Reactions of VX, GD, and HD with nanotubular tita-nia[J]. J Phys Chem C, 2008, 112(31): 11901-11906.
6. Ma Lin, Kang Xiao-xue, Hu Shao-zheng, et al. Preparation of Fe-P Co-doped graphitic carbon nitride with enhanced isible-light photocatalytic activity[J]. J Mol Catal (China), 2015, 29(4): 359-368.
7. 2/BiOBr composite prepared at different calcination temperatures [J]. J Mol Catal (China), 2016, 30(2): 159-168.
8. Komano A, Hirakawa T, Sato K, et al. Titanium dioxide photocatalytic decompositionof ethyl-S-dimethylaminoethyl methylphosph-onothiolate (VX) in aqueous phase[J].Appl Catal B Envir, 2013, 134/135(9): 19-25.
9. Lu Guang, Zhang Shuang, Hou Guan-yu, et al. Effect of pH regulators on structural performance and photocatalytic degradation of Rh bover BiOCl samples [J]. J Mol Catal (China), 2016, 30(2): 169-176.
10. 2: adsorbate reactions with lattice oxygen as studied by infra-red spectroscopy[J]. J Phys Chem C, 2009, 113(35): 15684-15691.
11. Song Han, Zhou Xiao-ping. An insitu FTIR investigation of acetone photodegradation[J]. J Mol Catal(China), 2008, 22(5): 454-460.
12. 2: an in situ DRIFTS study[J]. Catal Lett, 2010, 137(3/4): 239-246.
13. 40 salts andtheir cataly-tic activity in the isomerization of n-butane[J]. Chin J Catal, 2011, 32(4): 521-524.
14. 2 nanoparticles prepared by homogeneous hydrolysis[J]. Appl Catal B: Envir, 2009, 88(1): 194-203.
15. 2 photocatalyst by a sol-gel-solvothermal method[J]. J Photochem Photobio A, 2006, 184(3): 282-288.
16. Lowell S, Shields J E. Powder Surface of Porous Materials[M]. Chapman & Hall, London. 1998.
17. Stengl V, Bludska J, Oplustil F, et al. Mesoporous titanium manganese dioxide for sulphur mustard and soman decontamination[J]. Mater Res Bull, 2011, 46(11): 2050-2056.
18. 2 for stoichiometric degradation of warfare agents[J]. J Hazar Mater, 2012, 227/228(16): 62-67.
19. 2 [J]. J Photo Chem & Photobio A Chem, 2006, 184(1): 125-134.
20. 2[J]. J Phys Chem B, 2005, 109(46): 21884-21892.
21. Mattsson A, Lejon C, Stengl V, et al. Photodegradation of DMMP and CEES on zirconium doped titania nanoparticles[J]. Appl Catal B: Envir, 2009, 92(3/4): 401-410.
22. 2 powder[J]. J Phys Chem B, 2000, 104(51): 12299-12305.
23. 2 ru-tile (110) surface[J]. J Phys Chem B, 2004, 108: 500-504.
24. Brownson J R S, Tejedor-Tejedor M I, Anderson M A. Photoreactive anatase consolidation ch-aracterized by FTIR spectroscopy[J]. Chem Mater, 2005, 18(25): 6304-6310.
25. 2 nano-particles: Role of surface intermediates[J]. J Catal, 2007, 251(1): 131-144.
26. 2 surfaces[J]. J Phys Chem B, 2004, 108(43): 16825-16833.
27. 2[J]. Appl Catal B: Envir, 2005, 61(1): 159-163.
28. Vorontsov A V, Lion C, Savinov E N, et al. Pathways of photocatalytic gas phasedestruction of HD stimulant 2-chloroethyl ethyl sulfide[J]. J Catal, 2003, 220(2): 414-423.
29. 2[J]. Appl Catal B: Envir, 2001, 32(1/2): 11-24.