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It is known that red shift is usually observed when the dielectric constant, e, of solvents increase; see
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CH2C12 and THF have dielectric constants of 8.93 (T = 298.0) and 7.52 (T = 295.2), respectively; see, 75th ed., CRC Press, Boca Raton, FL
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CH2C12 and THF have dielectric constants of 8.93 (T = 298.0) and 7.52 (T = 295.2), respectively; see Lide, D. R. (Ed) CRC Handbook of Chemistry and Physics, 75th ed., CRC Press, Boca Raton, FL, 1994, pp 6-157, 6-161.
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Seep. 207inRef 2
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85013607986
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See p, in Ref 2
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See p. 220 in Ref 2.
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27
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85013613650
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It is surprising that 8 showed a very large y value of 1.2 x 10 esu in THF under a concentration range of 9.3 x 10"4-1.2 x 10"3M. It is about 4 times larger than the y value obtained in CH2C12. The value was reproducible but further investigation may be required to obtain a more accurate value
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It is surprising that 8 showed a very large y value of 1.2 x 10 esu in THF under a concentration range of 9.3 x 10"4-1.2 x 10"3M. It is about 4 times larger than the y value obtained in CH2C12. The value was reproducible but further investigation may be required to obtain a more accurate value.
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It is reported that even a very weak absorption (a a 0.02 cm-1) can enhance the nonlinearity; see
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It is reported that even a very weak absorption (a a 0.02 cm-1) can enhance the nonlinearity; see Burzynski, R.; Singh, B. P.; Prasad, P. N.; Zanoni, R.; Stegeman, G. I. Appl. Phys. Lett. 1988, 53, 2011.
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Chapter 8 in Ref 2.
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