Thermal-Treatment-Induced Deformations and Modifications of Halloysite

Developments in Clay Science

Volumn 7, Issue , 2016, Pages 137-166

  Yuan, P ^a  

^a GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

Author keywords

Dehydration; Dehydroxylation; Halloysite; Phase transformation; Porosity; Surface reactivity; Thermal treatment

Indexed keywords

EID: 85013001592     PISSN: 15724352     EISSN: None     Source Type: Book Series    
DOI: 10.1016/B978-0-08-100293-3.00007-8     Document Type: Chapter

References (88)

1. Abdullayev, E., Lvov, Y., Clay nanotubes for corrosion inhibitor encapsulation: release control with end stoppers. J. Mater. Chem. 20 (2010), 6681–6687.
2. Alhuthali, A., Low, I.M., Water absorption, mechanical, and thermal properties of halloysite nanotube reinforced vinyl-ester nanocomposites. J. Mater. Sci. 48 (2013), 4260–4273.
3. Antill, S.J., Halloysite: a low-cost alternative nanotube. Aust. J. Chem., 56, 2003, 723.
4. Belkassa, K., Bessaha, F., Marouf-Khelifa, K., Batonneau-Gener, I., Comparot, J.D., Khelifa, A., Physicochemical and adsorptive properties of a heat-treated and acid-leached Algerian halloysite. Colloids Surf. A 421 (2013), 26–33.
5. Bergaya, F., Dion, P., Alcover, J.F., Clinard, C., Tchoubar, D., TEM study of kaolinite thermal decomposition by controlled-rate thermal analysis. J. Mater. Sci. 31 (1996), 5069–5075.
6. Bradley, W., Grim, R., High temperature thermal effects of clay and related materials. Am. Mineral. 36 (1951), 182–201.
7. Brindley, G.W., Goodyear, J., X-ray studies of halloysite and metahalloysite. Part II. The transition of halloysite to metahalloysite in relation to relative humidity. Mineral. Mag. 28 (1948), 407–422.
8. Brindley, G.W., Lemaitre, J., Thermal, oxidation and reduction reactions of clay minerals. Newman, A.C.D., (eds.) Chemistry of Clays and Clay Minerals, 1987, Mineralogical Society, London, 319–370.
9. Brindley, G.W., Nakahira, M., The kaolinite-mullite reaction series: I, A survey of outstanding problems. J. Am. Ceram. Soc. 42 (1959), 311–314.
10. Brown, I.W.M., Mackenzie, K.J.D., Bowden, M.E., Meinhold, R.H., Outstanding problems in the kaolinite-mullite reaction sequence investigated by Si-29 and Al-27 solid-state nuclear magnetic resonance: II, High-temperature transformations of metakaolinite. J. Am. Ceram. Soc. 68 (1985), 298–301.
11. Brown, I.W.M., Mackenzie, K.J.D., Meinhold, R.H., The thermal-reactions of montmorillonite studied by high-resolution solid-state Si-29 and Al-27 NMR. J. Mater. Sci. 22 (1987), 3265–3275.
12. Bunker, B.C., Kirkpatrick, R.J., Brow, R.K., Turner, G.L., Nelson, C., Local structure of alkaline earth boroaluminate crystals and glasses: II, B-11 and Al-27 MAS NMR spectroscopy of alkaline-earth boroaluminate glasses. J. Am. Ceram. Soc. 74 (1991), 1430–1438.
13. Bushell, S.W., Chinese Pottery and Porcelain. 1977, Oxford University Press, Kuala Lumpur.
14. Cases, J.M., Grillet, Y., Francois, M., Michot, L., Villieras, F., Yvon, J., Evolution of the porous structure and surface area of palygorskite under vacuum thermal treatment. Clay Clay Miner. 39 (1991), 191–201.
15. Churchman, G.J., Relevance of different intercalation tests for distinguishing halloysite from kaolinite in soils. Clay Clay Miner. 38 (1990), 591–599.
16. Churchman, G.J., Theng, B.K.G., Interactions of halloysites with amides: mineralogical factors affecting complex formation. Clay Miner. 19 (1984), 161–175.
17. Churchman, G.J., Davy, T.J., Aylmore, L.A.G., Gilkes, R.J., Self, P.G., Characteristics of fine pores in some halloysites. Clay Miner. 30 (1995), 89–98.
18. Costanzo, P.M., Giese, R.F., Dehydration of synthetic hydrated kaolinites: a model for the dehydration of halloysite(10 Å). Clay Clay Miner. 33 (1985), 415–423.
19. Costanzo, P.M., Giese, R.F., Lipsicas, M., Straley, C., Synthesis of a quasi-stable hydrated kaolinite and heat capacity of interlayer water. Nature 296 (1982), 549–551.
20. Costanzo, P.M., Giese, R.F., Lipsicas, M., Static and dynamic structure of water in hydrated kaolinites: I, The static structure. Clay Clay Miner. 32 (1984), 419–428.
21. Dion, P., Alcover, J.F., Bergaya, F., Ortega, A., Llewellyn, P.L., Rouquerol, F., Kinetic study by controlled-transformation rate thermal analysis of the dehydroxylation of kaolinite. Clay Miner. 33 (1998), 269–276.
22. Djemai, A., Balan, E., Morin, G., Hernandez, G., Labbe, J.C., Muller, J.P., Behavior of paramagnetic iron during the thermal transformations of kaolinite. J. Am. Ceram. Soc. 84 (2001), 1017–1024.
23. Drago, R.S., Physical Methods for Chemists. second ed., 1992, Saunders College Publishing, Mexico.
24. Farmer, V.C., Differing effects of particle size and shape in the infrared and Raman spectra of kaolinite. Clay Miner. 33 (1998), 601–604.
25. Finlay, R., The Pilgrim Art: Cultures of Porcelain in World History. 2010, University of California Press, California.
26. Forsgren, J., Jamstorp, E., Bredenberg, S., Engqvist, H., Stromme, M., A ceramic drug delivery vehicle for oral administration of highly potent opioids. J. Pharm. Sci. 99 (2010), 219–226.
27. Frost, R.L., Johansson, U., Combination bands in the infrared spectroscopy of kaolins—a DRIFT spectroscopic study. Clay Clay Miner. 46 (1998), 466–477.
28. Frost, R.L., Vassallo, A.M., The dehydroxylation of the kaolinite clay minerals using infrared emission spectroscopy. Clay Clay Miner. 44 (1996), 635–651.
29. Giese, R.F., Kaolin minerals: structures and stabilities. Bailey, S.W., (eds.) Hydrous Phyllosilicates (Exclusive of Micas) Reviews in Mineralogy, vol. 19, 1988, Mineralogical Society of America, Washington, DC, 29–66.
30. Gregg, S.J., Sing, K.S.W., Adsorption, Surface Area and Porosity. second ed., 1982, Academic Press, New York.
31. Groen, J.C., Peffer, L.A.A., Perez-Ramirez, J., Pore size determination in modified micro- and mesoporous materials. Pitfalls and limitations in gas adsorption data analysis. Microporous Mesoporous Mater. 60 (2003), 1–17.
32. Hampel, B.F., Cutler, I.B., Some ceramic properties of halloysite. J. Am. Ceram. Soc. 36 (1953), 30–34.
33. Hayashi, H., Otsuka, R., Imai, N., Infrared study of sepiolite and palygorskite on heating. Am. Mineral. 53 (1969), 1613–1624.
34. He, H.P., Guo, J.G., Zhu, J.X., Yuan, P., Hu, C., Si-29 and Al-27 MAS NMR spectra of mullites from different kaolinites. Spectrochim. Acta A Mol. Biomol. Spectrosc. 60 (2004), 1061–1064.
35. Hillier, S., Ryan, P.C., Identification of halloysite (7 Å) by ethylene glycol solvation: the ‘MacEwan effect’. Clay Miner. 37 (2002), 487–496.
36. Hughes, I.R., Mineral changes of halloysite on drying. New Zeal. J. Sci. 9 (1966), 103–113.
37. Joussein, E., Petit, S., Churchman, J., Theng, B., Righi, D., Delvaux, B., Halloysite clay minerals—a review. Clay Miner. 40 (2005), 383–426.
38. Joussein, E., Petit, S., Fialips, C.I., Vieillard, P., Righi, D., Differences in the dehydration-rehydration behavior of halloysites: new evidence and interpretations. Clay Clay Miner. 54 (2006), 473–484.
39. Kadi, S., Lellou, S., Marouf-Khelifa, K., Schott, J., Gener-Batonneau, I., Khelifa, A., Preparation, characterisation and application of thermally treated Algerian halloysite. Microporous Mesoporous Mater. 158 (2012), 47–54.
40. Kakalia, G., Perrakib, T., Tsivilis, S., Badogiannisa, E., Thermal treatment of kaolin: the effect of mineralogy on the pozzolanic activity. Appl. Clay Sci. 20 (2001), 73–80.
41. Kirkman, J.H., Possible structure of halloysite disks and cylinders observed in some New Zealand rhyolitic tephras. Clay Miner. 12 (1977), 199–215.
42. Kohyama, N., Fukushima, K., Fukami, A., Observation of the hydrated form of tubular halloysite by an electron microscope equipped with an environmental cell. Clay Clay Miner. 26 (1978), 25–40.
43. Koretsky, C.M., Sverjensky, D.A., Salisbury, J.W., DAria, D.M., Detection of surface hydroxyl species on quartz, γ-alumina, and feldspars using diffuse reflectance infrared spectroscopy. Geochim. Cosmochim. Acta 61 (1997), 2193–2210.
44. Kristof, J., Frost, R.L., Horvath, E., Kocsis, L., Inczedy, J., Thermoanalytical investigations on intercalated kaolinites. J. Therm. Anal. Calorim. 53 (1998), 467–475.
45. Kristof, J., Frost, R.L., Kloprogge, J.T., Horvath, E., Mako, E., Detection of four different OH-groups in ground kaolinite with controlled-rate thermal analysis. J. Therm. Anal. Calorim. 69 (2002), 77–83.
46. Lecouvet, B., Horion, J., D'Haese, C., Bailly, C., Nysten, B., Elastic modulus of halloysite nanotubes. Nanotechnology, 24, 2013, 8.
47. Lee, G., Cutler, I.B., Sinterable sialon powder by reaction of clay with carbon and nitrogen. Am. Ceram. Soc. Bull. 58 (1979), 869–871.
48. Lee, S., Kim, Y.J., Moon, H.S., Phase transformation sequence from kaolinite to mullite investigated by an energy-filtering transmission electron microscope. J. Am. Ceram. Soc. 82 (1999), 2841–2848.
49. Lipsicas, M., Straley, C., Costanzo, P.M., Giese, R.F., Static and dynamic structure of water in hydrated kaolinites: II, The dynamic structure. J. Colloid Interface Sci. 107 (1985), 221–230.
50. Liu, M.X., Guo, B.C., Du, M.L., Cai, X.J., Jia, D.M., Properties of halloysite nanotube-epoxy resin hybrids and the interfacial reactions in the systems. Nanotechnology 18 (2007), 455–703.
51. Lu, D., Chen, H.B., Wu, J.S., Chan, C.M., Direct measurements of the Young's Modulus of a single halloysite nanotube using a transmission electron microscope with a bending stage. J. Nanosci. Nanotechnol. 11 (2010), 7789–7793.
52. Lvov, Y.M., Shchukin, D.G., Mohwald, H., Price, R.R., Halloysite clay nanotubes for controlled release of protective agents. ACS Nano 2 (2008), 814–820.
53. Mackenzie, K.J.D., Brown, I.W.M., Meinhold, R.H., Bowden, M.E., Outstanding problems in the kaolinite-mullite reaction sequence investigated by Si-29 and Al-27 solid-state nuclear magnetic-resonance: I, Metakaolinite. J. Am. Ceram. Soc. 68 (1985), 293–297.
54. Madejová, J., Komadel, P., Baseline studies of the clay minerals society source clays: infrared methods. Clay Clay Miner. 49 (2001), 410–432.
55. Massiot, D., Dion, P., Alcover, J.F., Bergaya, F., Al-27 and Si-29 MAS NMR study of kaolinite thermal decomposition by controlled rate thermal analysis. J. Am. Ceram. Soc. 78 (1995), 2940–2944.
56. Melo, J.D.D., Costa, T.C.D., de Medeiros, A.M., Paskocimas, C.A., Effects of thermal and chemical treatments on physical properties of kaolinite. Ceram. Int. 36 (2010), 33–38.
57. Morrow, B.A., Mcfarlan, A.J., Surface vibrational modes of silanol groups on silica. J. Phys. Chem. 96 (1992), 1395–1400.
58. Morterra, C., Magnacca, G., A case study: surface chemistry and surface structure of catalytic aluminas, as studied by vibrational spectroscopy of adsorbed species. Catal. Today 27 (1996), 497–532.
59. Neal, G.S., Smith, M.E., Trigg, M.B., Drennan, J., Solid-state NMR examination of the formation of β-sialon by carbothermal reduction and nitridation of halloysite clay. J. Mater. Chem. 4 (1994), 245–251.
60. Noyan, H., Oenal, M., Sarikaya, Y., The effect of heating on the surface area, porosity and surface acidity of a bentonite. Clay Clay Miner. 54 (2006), 375–381.
61. Okada, K., Otsuka, N., Ossaka, J., Characterization of spinel phase formed in the kaolin-mullite thermal sequence. J. Am. Ceram. Soc. 69 (1986), C251–C253.
62. Ouyang, J., Zhou, Z., Zhang, Y., Yang, H., High morphological stability and structural transition of halloysite (Hunan, China) in heat treatment. Appl. Clay Sci. 101 (2014), 16–22.
63. Percival, H., Duncan, J., Foster, P., Interpretation of the kaolinite-mullite reaction sequence from infrared absorption spectra. J. Am. Ceram. Soc. 57 (1974), 57–61.
64. Rocha, J., Klinowski, J., Si-29 and Al-27 magic-angle-spinning NMR studies of the thermal transformation of kaolinite. Phys. Chem. Miner. 17 (1990), 179–186.
65. Ross, C.S., Kerr, P.F., Halloysite and allophane: US Geol. Survey Prof. Paper 185-G., 1934, 135–148.
66. Sarikaya, Y., Onal, M., Baran, B., Alemdaroglu, T., The effect of thermal treatment on some of the physicochemical properties of a bentonite. Clay Clay Miner. 48 (2000), 557–562.
67. 3 glasses. J. Phys. Chem. 95 (1991), 4483–4489.
68. Shoval, S., Champagnon, B., Panczer, G., The quartz-cristobalite transformation in heated chert rock composed of micro and crypto-quartz by micro-Raman and FT-IR spectroscopy methods. J. Therm. Anal. 50 (1997), 203–213.
69. Shoval, S., Boudeulle, M., Yariv, S., Lapides, I., Panczer, G., Micro-Raman and FT-IR spectroscopy study of the thermal transformations of St. Claire dickite. Opt. Mater. 16 (2001), 319–327.
70. Shu, Z., Chen, Y., Zhou, J., Li, T., Yu, D., Wang, Y., Nanoporous-walled silica and alumina nanotubes derived from halloysite: controllable preparation and their dye adsorption applications. Appl. Clay Sci. 112–113 (2015), 17–24.
71. Sing, K.S.W., Williams, R.T., Review: the use of molecular probes for the characterization of nanoporous adsorbents. Part. Part. Syst. Charact. 21 (2004), 71–79.
72. Slansky, E., Halloysite in a weathered profile at Port Macquarie, New South Wales. Trans. R. Soc. South Aust. 107 (1983), 177–185.
73. Smith, M.E., Neal, G., Trigg, M.B., Drennan, J., Structural characterization of the thermal transformation of halloysite by solid-state NMR. Appl. Magn. Reson. 4 (1993), 157–170.
74. Sonuparlak, B., Sarikaya, M., Aksay, I.A., Spinel phase formation during the 980°C exothermic reaction in the kaolinite-to-mullite reaction series. J. Am. Ceram. Soc. 70 (1987), 837–842.
75. Theng, B.K.G., Churchman, G.J., Whitton, J.S., Claridge, G.G.C., Comparison of intercalation methods for differentiating halloysite from kaolinite. Clay Clay Miner. 32 (1984), 249–258.
76. Tonle, I.K., Diaco, T., Ngameni, E., Detellier, C., Nanohybrid kaolinite-based materials obtained from the interlayer grafting of 3-aminopropyltriethoxysilane and their potential use as electrochemical sensors. Chem. Mater. 19 (2007), 6629–6636.
77. Vandiver, P.B., Soffer, O., Klima, B., Svoboda, J., The origins of ceramic technology at Dolní Věstonice, Czechoslovakia. Science 246 (1989), 1002–1008.
78. Vassallo, A.M., Coleclarke, P.A., Pang, L.S.K., Palmisano, A.J., Infrared emission spectroscopy of coal minerals and their thermal transformations. Appl. Spectrosc. 46 (1992), 73–78.
79. Voll, D., Lengauer, C., Beran, A., Schneider, H., Infrared band assignment and structural refinement of Al-Si, Al-Ge, and Ga-Ge mullites. Eur. J. Mineral. 13 (2001), 591–604.
80. Voll, D., Angerer, P., Beran, A., Schneider, H., A new assignment of IR vibrational modes in mullite. Vib. Spectrosc. 30 (2002), 237–243.
81. Wang, Q., Zhang, J.P., Zheng, Y., Wang, A.Q., Adsorption and release of ofloxacin from acid- and heat-treated halloysite. Colloids Surf. B 113 (2014), 51–58.
82. White, R., The upper paleolithic: a human revolution. Calhoun, D., Britannica, E., (eds.) 1989 Yearbook of Science and the Future, 1988, Encyclopaedia Britannica, Inc., Chicago, 30–49.
83. Wu, X.H., Zhang, C., Goldberg, P., Cohen, D., Pan, Y., Arpin, T., Bar-Yosef, O., Early pottery at 20,000 years ago in Xianrendong Cave, China. Science 336 (2012), 1696–1700.
84. Yuan, P., Wu, D.Q., He, H.P., Lin, Z.Y., The hydroxyl species and acid sites on diatomite surface: a combined IR and Raman study. Appl. Surf. Sci. 227 (2004), 30–39.
85. Yuan, P., Southon, P.D., Liu, Z., Green, M.E.R., Hook, J.M., Antill, S.J., Kepert, C.J., Functionalization of halloysite clay nanotubes by grafting with γ-aminopropyltriethoxysilane. J. Phys. Chem. C 112 (2008), 15742–15751.
86. Yuan, P., Tan, D., Annabi-Bergaya, F., Yan, W., Fan, M., Liu, D., He, H., Changes in structure, morphology, porosity, and surface activity of mesoporous halloysite nanotubes under heating. Clay Clay Miner. 60 (2012), 561–573.
87. Zhang, C., Komeya, K., Tatami, J., Meguro, T., Cheng, Y.B., Synthesis of Mg-α SiAlON powders from talc and halloysite clay minerals. J. Eur. Ceram. Soc. 20 (2000), 1809–1814.
88. Zhuravlev, L.T., Surface characterization of amorphous silica—a review of work from the former USSR. Colloids Surf. A 74 (1993), 71–90.