Dilution of highly concentrated libf4/propylene carbonate electrolyte solution with fluoroalkyl ethers for 5-V LiNi0.5Mn 1.5O4 positive electrodes

Journal of the Electrochemical Society

Volumn 164, Issue 1, 2017, Pages A6412-A6416

  Doi, Takayuki ^a   Shimizu, Yusuke ^a   Hashinokuchi, Michihiro ^a   Inaba, Minoru ^a  

^a DOSHISHA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRODES; ELECTROLYTES; ETHERS; VISCOSITY;

CARBONATE ELECTROLYTES; ELECTROLYTE SOLUTIONS; HIGH CHARGES; HIGH SOLUBILITY; HIGH VISCOSITIES; IRREVERSIBLE CAPACITY; LOW VISCOSITY; POSITIVE ELECTRODES;

MANGANESE;

EID: 85012902762     PISSN: 00134651     EISSN: 19457111     Source Type: Journal    
DOI: 10.1149/2.0611701jes     Document Type: Conference Paper

References (15)

1. K. Xu, "Electrolytes and Interphases in Li-Ion Batteries and Beyond, " Chem Rev., 114, 11503 (2014).
2. J. R. Croy, A. Abouimrane, and Z. Zhang, "Next-generation lithium-ion batteries: The promise of near-Term advancements, " MRS Bulletin, 39, 407 (2014).
3. J. -M. Tarascon and M. Armand, "Issues and challenges facing rechargeable lithium batteries, " Nature, 414, 359 (2001).
4. S. Malmgrena, K. Cioseka, M. Hahlina, T. Gustafssona, M. Gorgoic, H. Rensmob, and K. Edstroma, "Comparing anode and cathode electrode/electrolyte interface composition andmorphology using soft and hard X-ray photoelectron spectroscopy, " Electrochim. Acta, 97, 23 (2013).
5. N. Yabuuchi, Y.Makimura, and T. Ohzuku, "Solid-State Chemistry and Electrochemistry of LiCo1/3Ni1/3Mn1/3O2 for Advanced Lithium-Ion Batteries III. Rechargeable Capacity and Cycleability, " J. Electrochem. Soc., 154, A314 (2007).
6. K. Amine, H.Yasuda, and M.Yamachi, "Olivine LiCoPO4 as 4.8Velectrode material for lithium batteries, " Electrochem. Solid State Lett., 3, 178 (2000).
7. K. Ariyoshi, Y. Iwakoshi, N. Nakayama, and T. Ohzuku, "Topotactic two-phase reactions of Li[Ni1/2Mn3/2]O4(P4332) in nonaqueous lithium cells, " J. Electrochem. Soc., 151, A296 (2004).
8. T. M. Pappenfus, W. A. Henderson, B. B. Owens, K. R. Mann, and W. H. Smyrl, "Complexes of lithium imide salts with tetraglyme and their polyelectrolyte composite materials, " J. Electrochem. Soc., 151, A209 (2004).
9. K. Yoshida, M. Nakamura, Y. Kazue, N. Tachikawa, S. Tsuzuki, S. Seki, K. Dokko, and M.Watanabe, "Oxidative-stability enhancement and charge transportmechanism in glyme-lithium salt equimolar complexes, " J. Am. Chem. Soc., 133, 13121 (2011).
10. T. Doi, R. Masuhara, M. Hashinokuchi, Y. Shimizu, and M. Inaba, "Concentrated LiPF6/PC electrolyte solutions for 5-V LiNi0.5Mn1.5O4 positive electrode in lithiumion batteries, " Electrochim. Acta, 209, 219 (2016).
11. T. Doi, Y. Shimizu, M. Hashinokuchi, and M. Inaba, "LiBF4-Based Concentrated Electrolyte Solutions for Suppression of Electrolyte Decomposition and Rapid Lithium-Ion Transfer at LiNi0.5Mn1.5O4/Electrolyte Interface, " J. Electrochem. Soc., 163, A2211 (2016).
12. K. Dokko, N. Tachikawa, K. Yamauchi, M. Tsuchiya, A. Yamazaki, E. Takashima, J.-W. Park, K. Ueno, S. Seki, N. Serizawa, and M. Watanabe, "Solvate Ionic Liquid Electrolyte for Li-S Batteries, " J. Electrochem. Soc., 160, A1304 (2013).
13. H. Tsunekawa, A. Narumi, M. Sano, A. Hiwara, M. Fujita, and H. Yokoyama, "Solvation and Ion Association Studies of LiBF4-Propylenecarbonate and LiBF4- Propylenecarbonate-Trimethyl Phosphate Solutions, " J. Phys. Chem. B, 107, 10962 (2003).
14. D. M. Seo, O. Borodin, S. -D. Han, Q. Ly, P. D. Boyle, and W. A. Henderson, "Electrolyte solvation and ionic association I. Acetonitrile-lithium salt mixtures: Intermediate and highly associated salts, " J. Electrochem. Soc., 159, 553 (2012).
15. S.-K. Jeong, M. Inaba, Y. Iriyama, T. Abe, and Z. Ogumi, "Surface film formation on a graphite negative electrode in lithium-ion batteries: AFM study on the effects of co-solvents in ethylene carbonate-based solutions, " Electrochim. Acta, 47, 1975 (2002).