Site- and State-Selective Dissociation of Core-Excited Organic Molecules: Deuterium-Labeled Methyl Acetate

Journal of Nuclear Science and Technology

Volumn 45, Issue , 2008, Pages 19-23

  Kawasaki, Rié ^a   Yamanaka, Takeshi ^a   Tabayashi, Kiyohiko ^a   Yoshida, Hiroaki ^a  

^a HIROSHIMA UNIVERSITY   (Japan)

Author keywords

Core level excitation; Methyl acetate; Oxygen K edge; PEPICO; Photochemistry; Site and state selective dissociation; TOF fragment mass spectroscopy

Indexed keywords

EID: 85010609012     PISSN: 00223131     EISSN: None     Source Type: Journal    
DOI: 10.1080/00223131.2008.10875971     Document Type: Article

References (13)

1. W. Eberhardt, T. K. Sham, R. Carr et al., “Site-specific fragmentation of small molecules following soft-X-ray excitation,” Phys. Rev. Lett., 50[14], 1038 (1983).
2. M. C. K. Tinone, K. Tanaka, J. Maruyama et al., “Inner-shell excitation and site specific fragmentation of poly(methyl-methacrylate) thin film,” J. Chem. Phys., 100[8], 5988 (1994).
3. K. Tanaka ed., Report of the Grant-in-Aid on Research for Future ‘Photoscience’ (JSPS-RFTF-98P01202), (2003), p. 53 [in Japanese].
4. K. Tabayashi, K. Yasunaga, J. Aoyama et al., “Construction of a cluster beam-reactive scattering apparatus for studying SR photochemistry of molecular-complexes and clusters,'' Proc. 4th Hiroshima Int. Symp. on Synchrotron Radiation, Higashi-Hiroshima (HSRC), Japan, Mar. 16-17, 2000, p. 333 (2000).
5. K. Tabayashi, T. Maruyama, K. Tanaka et al., “Coincidence measurements of core-excited molecules and clusters using TOF fragment-mass spectroscopy,” AIP Conference Proceedings, 879, 1788 (2007).
6. I. Ishii, A. P. Hitchcock, “The oscillator strengths for C1s and O1s excitation of some saturated and unsaturated organic alcohols, acids and esters,” J. Electron Spectrosc. Relat. Phenom., 46, 55 (1988).
7. + transfer from the a carbonyl,” J. Chem. Phys., 123[12], 124309 (2005).
8. T. D. Smith, T. D. Thomas, “Acidities and basicities of carboxylic acid. Correlations between core-ionization energies, proton affinities, and gas-phase acidities,” J. Am. Chem. Soc., 100[17], 5459 (1978).
9. K. Hermann, L. G. M. Pettersson, M. E. Casida et al., StoBe-deMon version 1.0, Stobe Software, 2002.
10. J. H. Vajda, A. G. Harrison, A. Hirota et al., “Unimolecular reactions of ionized methyl acetate and its enol: Mechanism for the enol to keto isomerization,” J. Am. Chem. Soc., 103[1], 36 (1981).
11. T. Sekitani, E. Ikenaga, K. Fujii et al., “Control of chemical bond scission by using site-specific photochemical surface reactions,” J. Electron Spectrosc. Relat. Phenom., 101-103, 135 (1999).
12. D. Ji, T. D. Thomas, “Deexcitation spectroscopy of core-excited methyl formate,” J. Electron Spectrosc. Relat. Phenom., 67[2], 233 (1994).
13. rd Nabit Symposium on Chemistry, Higashi-Hiroshima, Japan, Dec. 16-17, 2006.