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Pfaltz, A.1
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For previous uses of oxazoline-derived ligands, see: (a) Brunner, H.; Obermann, U. Chem. Ber. 1989, 122, 499–507.
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Nishiyama, H.; Sakaguchi, H.; Nakamura, T.; Horihata, M.; Kondo, M.; Itoh, K. Organometallics 1989, 8, 846–848.
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Nishiyama, H.1
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Itoh, K.6
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84986366730
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With chiral diazoacetate esters, Pfaltz has obtained an 82:18 trans/cis mixture in up to 97% ee for trans, 95% ee for cis.
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Fritschi, H.; Leutenegger, U.; Pfaltz, A. Helv. Chim. Acta 1988, 71, 1553–1565. With chiral diazoacetate esters, Pfaltz has obtained an 82:18 trans/cis mixture in up to 97% ee for trans, 95% ee for cis.
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Fritschi, H.1
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3). The assignment of absolute stereochemistry was made by comparison with literature values: (a) Inoue, Y.; Sugita, T.; Walborsky, H. M. Tetrahedron 1964, 20, 1695–1699.
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Aratani, T.; Nakanishi, Y.; Nozaki, H. Tetrahedron 1970, 26, 1675–1684.
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Doyle, M. P.; Bagheri, V.; Wandless, T. J.; Harn, N. K.; Brinker, D. A.; Eagle, C. T.; Loh, K.-L. J. Am. Chem. Soc. 1990, 112, 1906–1912.
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(Walborsky, H. M.; Barash. I.; Young, A. E.; Impastato, F. J. J. Am. Chem. Soc. 1961, 83, 2517–2525).
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0022331887
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When the Aratani catalyst was used, the product was isolated in 92% ee.
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Aratani, T. Pure Appl. Chem. 1985, 57, 1839–1844. When the Aratani catalyst was used, the product was isolated in 92% ee.
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