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Volumn 39, Issue 9, 2000, Pages 1635-1637

Homoleptic Carbonyl Ni-Pd Clusters: Synthesis of [Ni16Pd16(CO)40]4- and [Ni26Pd20(CO)54]6- and Structural Characterization of [Nn Bu4]4[Ni16Pd16(CO)40]

Author keywords

Carbonyl complexes; Cluster compounds; Nickel; Palladium

Indexed keywords

CARBONYL DERIVATIVE; NICKEL COMPLEX; PALLADIUM COMPLEX; TETRABUTYLAMMONIUM;

EID: 85007629929     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000502)39:9<1635::AID-ANIE1635>3.0.CO;2-#     Document Type: Article
Times cited : (30)

References (28)
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    • 3. Crystallographic data (excluding structure factors) for the structure reported in this paper has been deposited with the Cambridge Crystallographic Data Centre us supplementary publication no. CCDC-134987. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+ 44) 1223-336-033; e-mail: deposit@ccdc.cam. ac.uk).
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    • 3, Z 2. Rapid intensity decay during data collection of all measured crystals was observed. Some terminal carbonyl groups showed anomalous thermal motion, while some n-butyl chains of the cations and the clathraled n-hexane molecules were partially disordered. The structure could only be refined to an unsatisfactory R and wR factor of 0.098 and 0.259, respectively.
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