Isopropanol Dehydration on Amorphous Silica–Alumina: Synergy of Brønsted and Lewis Acidities at Pseudo-Bridging Silanols

Angewandte Chemie - International Edition

Volumn 56, Issue 1, 2017, Pages 230-234

  Larmier, Kim ^a,b   Chizallet, Céline ^a   Maury, Sylvie ^a   Cadran, Nicolas ^a   Abboud, Johnny ^b   Lamic Humblot, Anne Félicie ^b   Marceau, Eric ^b   Lauron Pernot, Hélène ^b  

^a IFP ENERGIES NOUVELLES   (France)

^b SORBONNE UNIVERSITÉ   (France)

Author keywords

alcohols; aluminosilicates; amorphous materials; density functional calculations; reaction kinetics

Indexed keywords

ALCOHOLS; ALUMINA; ALUMINOSILICATES; ALUMINUM OXIDE; AMORPHOUS MATERIALS; DEHYDRATION; REACTION KINETICS; SILICA;

AMORPHOUS SILICA; DOPED ALUMINA; EXPERIMENTAL KINETICS; HYDROXY GROUPS; ISOPROPANOL DEHYDRATION; LEAVING GROUPS; LEWIS ACIDITY; THEORETICAL CALCULATIONS;

DENSITY FUNCTIONAL THEORY;

EID: 85006275008     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201609494     Document Type: Article

References (43)

1. G. W. Huber, R. D. Cortright, J. A. Dumesic, Angew. Chem. Int. Ed. 2004, 43, 1549–1551;
2. Angew. Chem. 2004, 116, 1575–1577.
3. A. Corma, Chem. Rev. 1995, 95, 559–614.
4. C. P. Bezoukhanova, Y. A. Kalvachev, Catal. Rev. 1994, 36, 125–143.
5. S. Pega, C. Boissière, D. Grosso, T. Azaïs, A. Chaumonnot, C. Sanchez, Angew. Chem. Int. Ed. 2009, 48, 2784–2787;
6. Angew. Chem. 2009, 121, 2822–2825.
7. J. F. Stebbins, Z. Xu, Nature 1997, 390, 1996–1998.
8. G. Busca, Chem. Rev. 2007, 107, 5366–5410.
9. E. J. M. Hensen, D. G. Poduval, V. Degirmenci, D. A. J. M. Ligthart, W. Chen, M. S. Rigutto, J. A. R. Van Veen, J. Phys. Chem. C 2012, 116, 21416–21429.
10. S. Sato, M. Toita, T. Sodesawa, F. Nozaki, Appl. Catal. 1990, 62, 73–84.
11. M. Caillot, A. Chaumonnot, M. Digne, J. A. Van Bokhoven, J. Catal. 2014, 316, 47–56.
12. G. E. Maciel, J. F. Haw, I. Chuang, B. L. Hawkins, T. A. Early, D. R. Mckay, L. Petrakist, J. Am. Chem. Soc. 1983, 105, 77–83.
13. N. Y. Topsoe, K. Pedersen, E. G. Derouane, J. Catal. 1981, 70, 41–52.
14. V. C. Holm, G. C. Bailey, A. Clark, J. Phys. Chem. 1959, 63, 129–133.
15. G. Crépeau, V. Montouillout, A. Vimont, L. Mariey, T. Cseri, F. Mauge, J. Phys. Chem. B 2006, 110, 15172–15185.
16. S. Handjani, S. Dzwigaj, J. Blanchard, E. Marceau, J.-M. Krafft, M. Che, Top. Catal. 2009, 52, 334–343.
17. C. Chizallet, P. Raybaud, ChemPhysChem 2010, 11, 105–108.
18. C. Chizallet, P. Raybaud, Angew. Chem. Int. Ed. 2009, 48, 2891–2893;
19. Angew. Chem. 2009, 121, 2935–2937.
20. M. Valla et al., J. Am. Chem. Soc. 2015, 137, 10710–10719.
21. H. Lauron-Pernot, Catal. Rev. 2006, 48, 315–361.
22. H. Vinek, J. A. Lercher, H. Noller, J. Mol. Catal. 1985, 30, 353–359.
23. P. Berteau, B. Delmon, Catal. Today 1989, 5, 121–137.
24. P. Berteau, M.-A. Kellens, B. Delmon, J. Chem. Soc. Faraday Trans. 1991, 87, 1425.
25. J. C. Yori, J. C. Luy, J. M. Parera, Appl. Catal. 1988, 41, 1–11.
26. T. K. Phung, G. Busca, Chem. Eng. J. 2015, 272, 92–101.
27. T. K. Phung, G. Busca, Catal. Commun. 2015, 68, 110–115.
28. F. Leydier, C. Chizallet, A. Chaumonnot, M. Digne, E. Soyer, A.-A. Quoineaud, D. Costa, P. Raybaud, J. Catal. 2011, 277, 1–15.
29. K. Larmier, C. Chizallet, N. Cadran, S. Maury, J. Abboud, A.-F. Lamic-Humblot, E. Marceau, H. Lauron-Pernot, ACS Catal. 2015, 5, 4423–4437.
30. K. Larmier, A. Nicolle, C. Chizallet, N. Cadran, S. Maury, A.-F. Lamic-Humblot, E. Marceau, H. Lauron-Pernot, ACS Catal. 2016, 6, 1905–1920.
31. M. John, K. Alexopoulos, M. Reyniers, G. B. Marin, J. Catal. 2015, 330, 28–45.
32. C. Amatore, A. Jutand, J. Organomet. Chem. 1999, 576, 254–278.
33. F. A. Carey, R. J. Sundberg, Advanced Organic Chemistry, 5th ed., Springer, USA, 2007.
34. F. Leydier, C. Chizallet, D. Costa, P. Raybaud, J. Catal. 2015, 325, 35–47.
35. X. Rozanska, R. van Santen, F. Hutschka, J. Hafner, J. Am. Chem. Soc. 2001, 123, 7655–7667.
36. S. S. M. Konda, S. Caratzoulas, D. G. Vlachos, ACS Catal. 2016, 6, 123–133.
37. J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865–3868.
38. G. Kresse, J. Hafner, Phys. Rev. B 1994, 49, 14251–14269.
39. G. Kresse, J. Furthmüller, Phys. Rev. B 1996, 54, 11169–11186.
40. G. Kresse, D. Joubert, Phys. Rev. B 1999, 59, 1758–1775.
41. S. Grimme, J. Comput. Chem. 2006, 27, 1787–1799.
42. G. Henkelman, B. P. Uberuaga, H. Jónsson, J. Chem. Phys. 2000, 113, 9901–9904.
43. G. Henkelman, H. Jónsson, J. Chem. Phys. 2000, 113, 9978–9985.