Versatile synthesis of high performance, crosslinked polymer microcapsules with encapsulated n-hexadecane as heat storage materials by utilizing microsuspension controlled/living radical polymerization (ms CLRP) of ethylene glycol dimethacrylate with the SaPSeP method

Polymer

Volumn 106, Issue , 2016, Pages 182-188

  Suzuki, Toyoko ^a   Mizowaki, Tsugumi ^a   Okubo, Masayoshi ^a  

^a KOBE UNIVERSITY   (Japan)

Author keywords

AGET ATRP; Controlled living radical polymerization (CLRP); Heat storage material; Microcapsule; Microsuspension polymerization

Indexed keywords

ACRYLIC MONOMERS; ENCAPSULATION; ETHYLENE; ETHYLENE GLYCOL; FREE RADICAL POLYMERIZATION; HEAT STORAGE; MICROSTRUCTURE; PARAFFINS; PARTICLE SIZE; POLYOLS; SELF ASSEMBLY; STORAGE (MATERIALS); SUPERCOOLING;

AGET ATRP; CONTROLLED/LIVING RADICAL POLYMERIZATION; ETHYLENE GLYCOL DIMETHACRYLATE; LARGER PARTICLE SIZES; MICROCAPSULES; MICROSUSPENSION; PHASE SEPARATED POLYMERS; POLY(ETHYLENE GLYCOL DIMETHACRYLATE);

ATOM TRANSFER RADICAL POLYMERIZATION;

EID: 84994879714     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymer.2016.08.109     Document Type: Article

References (42)

1. [1] Zhao, C.Y., Zhang, G.H., Review on microencapsulated phase change materials (MEPCMs): fabrication, characterization and applications. Renew. Sustain. Energy Rev. 15:8 (2011), 3813–3832.
2. [2] Farid, M.M., Khudhair, A.M., Razack, S.A.K., Al-Hallaj, S., A review on phase change energy storage: materials and applications. Energy Convers. Manag. 45:9–10 (2004), 1597–1615.
3. [3] Regin, A.F., Solanki, S.C., Saini, J.S., Heat transfer characteristics of thermal energy storage system using PCM capsules: a review. Renew. Sustain. Energy Rev. 12:9 (2008), 2438–2458.
4. [4] Su, J.F., Wang, L.X., Ren, L., Preparation and characterization of double-MF shell microPCMs used in building materials. J. Appl. Polym. Sci. 97:5 (2005), 1755–1762.
5. [5] Schossig, P., Henning, H.M., Gschwander, S., Haussmann, T., Micro-encapsulated phase-change materials integrated into construction materials. Sol. Energy Mater. Sol. Cells 89:2–3 (2005), 297–306.
6. [6] Yamagishi, Y., Sugeno, T., Ishige, T., Takeuchi, H., Pyatenko, A., An evaluation of microencapsulated PCM for use in cold energy transportation medium. Proceedings of the 31st IECEC, Washington, DC, USA, 1996, 2077–2083.
7. [7] Cho, J.S., Kwon, A., Cho, C.G., Microencapsulation of octadecane as a phase-change material by interfacial polymerization in an emulsion system. Colloid Polym. Sci. 280:3 (2002), 260–266.
8. [8] Shin, Y., Yoo, D.I., Son, K., Development of thermoregulating textile materials with microencapsulated phase change materials (PCM). II. Preparation and application of PCM microcapsules. J. Appl. Polym. Sci. 96:6 (2005), 2005–2010.
9. [9] Mondal, S., Phase change materials for smart textiles - an overview. Appl. Therm. Eng. 28:11–12 (2008), 1536–1550.
10. [10] Zhang, X.X., Fan, Y.F., Tao, X.M., Yick, K.L., Fabrication and properties of microcapsules and nanocapsules containing n-octadecane. Mater. Chem. Phys. 88:2–3 (2004), 300–307.
11. [11] You, M., Wang, X.C., Zhang, X.X., Zhang, L., Wang, J.P., Microencapsulated n-Octadecane with styrene-divinybenzene co-polymer shells. J. Polym. Res. 18:1 (2011), 49–58.
12. [12] Sari, A., Alkan, C., Karaipekli, A., Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage. Appl. Energy 87:5 (2010), 1529–1534.
13. [13] Chaiyasat, P., Noppalit, S., Okubo, M., Chaiyasat, A., Do encapsulated heat storage materials really retain their original thermal properties?. Phys. Chem. Chem. Phys. 17:2 (2015), 1053–1059.
14. [14] Chaiyasat, P., Noppalit, S., Okubo, M., Chaiyasat, A., Innovative synthesis of high performance poly(methyl methacrylate) microcapsules with encapsulated heat storage material by microsuspension iodine transfer polymerization (ms ITP). Sol. Energy Mater. Sol. Cells 157 (2016), 996–1003.
15. [15] Ogino, Y., Suzuki, T., Okubo, M., Preparation of poly (divinylbenzene) particles with encapsulated hexadecane for heat storage application. Kobunshi Ronbunshu 64:3 (2007), 171–176.
16. [16] Chaiyasat, P., Ogino, Y., Suzuki, T., Minami, H., Okubo, M., Preparation of divinylbenzene copolymer particles with encapsulated hexadecane for heat storage application. Colloid Polym. Sci. 286:2 (2008), 217–223.
17. [17] Chaiyasat, P., Ogino, Y., Suzuki, T., Okubo, M., Influence of water domain formed in hexadecane core inside cross-linked capsule particle on thermal properties for heat storage application. Colloid Polym. Sci. 286:6–7 (2008), 753–759.
18. [18] Okubo, M., Minami, H., Formation mechanism of micron-sized monodispersed polymer particles having a hollow structure. Colloid Polym. Sci. 275:10 (1997), 992–997.
19. [19] Okubo, M., Konishi, Y., Minami, H., Production of hollow polymer particles by suspension polymerization. Colloid Polym. Sci. 276:7 (1998), 638–642.
20. [20] Konishi, Y., Okubo, M., Minami, H., Phase separation in the formation of hollow particles by suspension polymerization for divinylbenzene/toluene droplets dissolving polystyrene. Colloid Polym. Sci. 281:2 (2003), 123–129.
21. [21] Okubo, M., Konishi, Y., Minami, H., Production of hollow particles by suspension polymerization of divinylbenzene with nonsolvent Progr. Colloid Polym. Sci. 124 (2003), 54–59.
22. [22] Okubo, M., Konishi, Y., Inohara, T., Minami, H., Size effect of monomer droplets on the production of hollow polymer particles by suspension polymerization. Colloid Polym. Sci. 281:4 (2003), 302–307.
23. [23] Zetterlund, P.B., Alam, M.N., Minami, H., Okubo, M., Nitroxide-mediated controlled/living free radical copolymerization of styrene and divinylbenzene in aqueous miniemulsion. Macromol. Rapid Commun. 26:12 (2005), 955–960.
24. [24] Saka, Y., Zetterlund, P.B., Okubo, M., Gel formation and primary chain lengths in nitroxide-mediated radical copolymerization of styrene and divinylbenzene in miniemulsion. Polymer 48:5 (2007), 1229–1236.
25. [25] Alam, M.N., Zetterlund, P.B., Okubo, M., Network formation in nitroxide-mediated radical copolymerization of styrene and divinylbenzene in miniemulsion: effect of macroinitiator hydrophilicity. Polymer 50:7 (2009), 1632–1636.
26. [26] Matyjaszewski, K., Advances in Controlled/Living Radical Polymerization. 2003, American Chemical Society, New York.
27. [27] Ide, N., Fukuda, T., Nitroxide-controlled free-radical copolymerization of vinyl and divinyl monomers. Evaluation of pendant-vinyl reactivity. Macromolecules 30:15 (1997), 4268–4271.
28. [28] Ide, N., Fukuda, T., Nitroxide-controlled free-radical copolymerization of vinyl and divinyl monomers. 2. Gelation. Macromolecules 32:1 (1999), 95–99.
29. [29] Tanaka, T., Suzuki, T., Saka, Y., Zetterlund, P.B., Okubo, M., Mechanical properties of cross-linked polymer particles prepared by nitroxide-mediated radical polymerization in aqueous micro-suspension. Polymer 48:13 (2007), 3836–3843.
30. [30] Zetterlund, P.B., Saka, Y., Okubo, M., Gelation and hollow particle formation in nitroxide-mediated radical copolymerization of styrene and divinylbenzene in miniemulsion. Macromol. Chem. Phys. 210:2 (2009), 140–149.
31. [31] Ali, M.M., Stover, H.D.H., Polymeric capsules prepared by in situ synthesis and cross-linking of amphiphilic copolymer by atom transfer radical polymerization. Macromolecules 36:6 (2003), 1793–1801.
32. [32] Ali, M.M., Stover, H.D.H., Interfacial living radical copolymerization of oil-and water-soluble comonomers to form composite polymer capsules. J. Polym. Sci. Part a Polym. Chem. 44:1 (2006), 156–171.
33. [33] Yu, Q., Zeng, F.Q., Zhu, S.P., Atom transfer radical polymerization of poly(ethylene glycol) dimethacrylate. Macromolecules 34:6 (2001), 1612–1618.
34. [34] Jiang, C.F., Shen, Y.Q., Zhu, S.P., Hunkeler, D., Gel formation in atom transfer radical polymerization of 2-(N,N-dimethylamino)ethyl methacrylate and ethylene glycol dimethacrylate. J. Polym. Sci. Part a Polym. Chem. 39:21 (2001), 3780–3788.
35. [35] Nagelsdiek, R., Mennicken, M., Maier, B., Keul, H., Hocker, H., Synthesis of polymers containing cross-linkable groups by atom transfer radical polymerization: poly(allyl methacrylate) and copolymers of allyl methacrylate and styrene. Macromolecules 37:24 (2004), 8923–8932.
36. [36] Wang, A.R., Zhu, S.P., Branching and gelation in atom transfer radical polymerization of methyl methacrylate and ethylene glycol dimethacrylate. Polym. Eng. Sci. 45:5 (2005), 720–727.
37. [37] Ward, J.H., Shahar, A., Peppas, N.A., Kinetics of 'living' radical polymerizations of multifunctional monomers. Polymer 43:6 (2002), 1745–1752.
38. [38] Min, K., Gao, H.F., Matyjaszewski, K., Preparation of homopolymers and block copolymers in miniemulsion by ATRP using activators generated by electron transfer (AGET). J. Am. Chem. Soc. 127:11 (2005), 3825–3830.
39. [39] Kitayama, Y., Yorizane, M., Kagawa, Y., Minami, H., Zetterlund, P.B., Okubo, M., Preparation of onion-like multilayered particles comprising mainly poly-(iso-butyl methacrylate)-block-polystyrene by two-step AGET ATRP. Polymer 50:14 (2009), 3182–3187.
40. [40] Hata, Y., Suzuki, T., Minami, H., Okubo, M., Preparation of hollow poly (divinyl benzene) particles with multiple holes in the shell by microsuspension polymerization with the SaPSeP method. Colloid Polym. Sci. 286:13 (2008), 1561–1567.
41. [41] Suzuki, T., Osumi, A., Minami, H., One-step synthesis of “rattle-like” polymer particles via suspension polymerization. Chem. Comm. 50:69 (2014), 9921–9924.
42. [42] Suzuki, T., Osumi, A., Minami, H., Controlling the morphology of “rattle”-like particles prepared by one-step suspension polymerization. J. Adhes. Soc. Jpn. 51 (2015), 233–234 (english).