Reaction mechanism and kinetics for hydrolytic dehydrogenation of ammonia borane on a Pt/CNT catalyst

AIChE Journal

Volumn 63, Issue 1, 2017, Pages 60-65

  Chen, Wenyao ^a   Li, Dali ^a   Wang, Zijun ^a   Qian, Gang ^a   Sui, Zhijun ^a   Duan, Xuezhi ^a   Zhou, Xinggui ^a   Yeboah, Isaac ^b   Chen, De ^b  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b NORWEGIAN UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Norway)

Author keywords

hydrolytic dehydrogenation of ammonia borane; kinetics; Pt CNT catalyst; reaction mechanism

Indexed keywords

AMMONIA; BYPRODUCTS; CATALYSTS; CHEMICAL BONDS; DEHYDROGENATION; ENZYME KINETICS; KINETICS; PLATINUM; THERMOANALYSIS;

AMERICAN INSTITUTE OF CHEMICAL ENGINEERS; AMMONIA BORANE; FTIR MEASUREMENTS; RATE DETERMINING STEP; REACTION ATMOSPHERES; REACTION MECHANISM; REACTION PATHWAYS; THERMO DYNAMIC ANALYSIS;

REACTION KINETICS;

EID: 84994135569     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.15389     Document Type: Article

References (38)

1. Marder TB. Will we soon be fueling our automobiles with ammonia-borane? Angew Chem Int Ed. 2007;46:8116–8118.
2. 2 yield and process characteristics. AIChE J. 2013;59:3359–3364.
3. Diwan M, Hwang HT, Al-Kukhun A, Varma A. Hydrogen generation from noncatalytic hydrothermolysis of ammonia borane for vehicle applications. AIChE J. 2011;57:259–264.
4. Chandra M, Xu Q. A high-performance hydrogen generation system: transition metal-catalyzed dissociation and hydrolysis of ammonia-borane. J Power Sources. 2006;156:190–194.
5. Metin O, Mazumder V, Ozkar S, Sun SH. Monodisperse nickel nanoparticles and their catalysis in hydrolytic dehydrogenation of ammonia borane. J Am Chem Soc. 2010;132:1468–1469.
6. Chen WY, Ji J, Duan XZ, Qian G, Li P, Zhou XG, Chen D, Yuan WK. Unique reactivity in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane. Chem Commun. 2014;50:2142–2144.
7. Zhu J, Holmen A, Chen D. Carbon nanomaterials in catalysis: proton affinity, chemical and electronic properties, and their catalytic consequences. ChemCatChem. 2013;5:378–401.
8. Chen WY, Ji J, Feng X, Duan XZ, Qian G, Li P, Zhou XG, Chen D, Yuan WK. Mechanistic insight into size-dependent activity and durability in Pt/CNT catalyzed hydrolytic dehydrogenation of ammonia borane. J Am Chem Soc. 2014;136:16736–16739.
9. Chen WY, Duan XZ, Qian G, Chen D, Zhou XG. Carbon nanotubes as support in the platinum-catalyzed hydrolytic dehydrogenation of ammonia borane. ChemSusChem. 2015;8:2927–2931.
10. Jiang HL, Xu Q. Catalytic hydrolysis of ammonia borane for chemical hydrogen storage. Catal Today. 2011;170:56–63.
11. Metin O, Ozkar S. Hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydride using water-soluble polymer-stabilized cobalt (0) nanoclusters catalyst. Energy Fuel. 2009;23:3517–3526.
12. Sanyal U, Demirci UB, Jagirdar BR, Miele P. Hydrolysis of ammonia borane as a hydrogen source: fundamental issues and potential solutions towards implementation. ChemSusChem. 2011;4:1731–1739.
13. Sutton AD, Burrell AK, Dixon DA, Garner EB, Gordon JC, Nakagawa T, Ott KC, Robinson JP, Vasiliu M. Regeneration of ammonia borane spent fuel by direct reaction with hydrazine and liquid ammonia. Science. 2011;331:1426–1429.
14. Davis BL, Dixon DA, Garner EB, Gordon JC, Matus MH, Scott B, Stephens FH. Efficient regeneration of partially spent ammonia borane fuel. Angew Chem Int Ed. 2009;48:6812–6816.
15. Hausdorf S, Baitalow F, Wolf G, Mertens FO. A procedure for the regeneration of ammonia borane from BNH-waste products. Int J Hydrogen Energy. 2008;33:608–614.
16. 3. A comparative study of their activity in hydrolysis of ammonia-borane. Int J Hydrogen Energy. 2011;36:7051–7065.
17. 3 for hydrolytic dehydrogenation of ammonia borane. Catal Today. 2011;170:85–92.
18. Liu CH, Wu YC, Chou CC, Chen BH, Hsueh CL, Ku JR, Tsau FH. Hydrogen generated from hydrolysis of ammonia borane using cobalt and ruthenium based catalysts. Int J Hydrogen Energy. 2012;37:2950–2959.
19. Mohajeri N, Ali T, Adebiyi O. Hydrolytic cleavage of ammonia-borane complex for hydrogen production. J Power Sources. 2007;167:482–485.
20. Patel N, Fernandes R, Guella G, Miotello A. Nanoparticle-assembled Co-B thin film for the hydrolysis of ammonia borane: a highly active catalyst for hydrogen production. Appl Catal B Environ. 2010;95:37–43.
21. Xu Q, Chandra M. Catalytic activities of non-noble metals for hydrogen generation from aqueous ammonia-borane at room temperature. J Power Sources. 2006;163:364–370.
22. Yang X, Cheng F, Tao Z, Chen J. Hydrolytic dehydrogenation of ammonia borane catalyzed by carbon supported Co core-Pt shell nanoparticles. J Power Sources. 2011;196:2785–2789.
23. 2P as a robust catalyst for the hydrolytic dehydrogenation of ammonia-borane. Angew Chem Int Ed. 2015;54:15725–15729.
24. Ma H, Na C. Isokinetic temperature and size-controlled activation of ruthenium-catalyzed ammonia borane hydrolysis. ACS Catal. 2015;5:1726–1735.
25. Marrero-Alfonso EY, Gray JR, Davis TA, Matthews MA. Minimizing water utilization in hydrolysis of sodium borohydride: the role of sodium metaborate hydrates. Int J Hydrogen Energy. 2007;32:4723–4730.
26. Lide DR. CRC Handbook of Chemistry and Physics, 84th ed. Boca Raton, FL: CRC press, 2003–2004.
27. Li J, Xia SP, Gao SY. FT-IR and Raman spectroscopic study of hydrated borates. Spectrochim Acta. 1995;51:519–532.
28. Zawadzki J, Wisniewski M. In situ characterization of interaction of ammonia with carbon surface in oxygen atmosphere. Carbon. 2003;41:2257–2267.
29. 3. J Phys Chem A. 2007;111:679–690.
30. n, n = 0-6). J Phys Chem C. 2009;113:16553–16560.
31. Staubitz A, Robertson AP, Manners I. Ammonia-borane and related compounds as dihydrogen sources. Chem Rev. 2010;110:4079–4124.
32. 11B NMR measurements. J Phys Chem B. 2006;110:17024–17033.
33. 11B NMR measurements. J Phys Chem C. 2007;111:18744–18750.
34. Simmons EM, Hartwig JF. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes. Angew Chem Int Ed. 2012;51:3066–3072.
35. Chandra M, Xu Q. Room temperature hydrogen generation from aqueous ammonia-borane using noble metal nano-clusters as highly active catalysts. J Power Sources. 2007;168:135–142.
36. Phatak AA, Delgass WN, Ribeiro FH, Schneider WF. Density functional theory comparison of water dissociation steps on Cu, Au, Ni, Pd, and Pt. J Phys Chem C. 2009;113:7269–7276.
37. x (x = 0-0.12) hollow spheres as catalysts for hydrogen generation from ammonia borane. Inorg Chem. 2007;46:788–794.
38. Metin O, Sahin S, Ozkar S. Water-soluble poly (4-styrenesulfonic acid-co-maleic acid) stabilized ruthenium(0) and palladium(0) nanoclusters as highly active catalysts in hydrogen generation from the hydrolysis of ammonia-borane. Int J Hydrogen Energy. 2009;34:6304–6313.