Chemical state of chromium, sulfur, and iron in sewage sludge ash based phosphorus fertilizers

ACS Sustainable Chemistry and Engineering

Volumn 3, Issue 10, 2015, Pages 2376-2380

  Vogel, Christian ^a   Radtke, Martin ^a   Reinholz, Uwe ^a   Schäfers, Franz ^b   Adam, Christian ^a  

^a BAM FEDERAL INSTITUTE FOR MATERIALS RESEARCH AND TESTING   (Germany)

^b HAHN MEITNER INSTITUT   (Germany)

Author keywords

Chromium; Iron; Phosphorus recovery; Sewage sludge ash; Sulfur; X ray absorption near edge structure (xanes) spectroscopy

Indexed keywords

CHROMIUM; CHROMIUM METALLOGRAPHY; HEMATITE; IRON; IRON METALLOGRAPHY; MAGNETITE; METAL RECOVERY; PHOSPHATE FERTILIZERS; PHOSPHORUS; SEWAGE SLUDGE; SULFUR; SULFUR COMPOUNDS; WASTEWATER RECLAMATION; X RAY ABSORPTION; X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY;

OXIDATION OF CHROMIUM; OXIDIZING CONDITIONS; PHOSPHORUS FERTILIZER; PHOSPHORUS RECOVERY; REDUCING CONDITIONS; SEWAGE SLUDGE ASH; THERMO CHEMICAL PROCESS; X-RAY NEAR EDGE STRUCTURE SPECTROSCOPIES;

CHROMIUM COMPOUNDS;

EID: 84991497865     PISSN: None     EISSN: 21680485     Source Type: Journal    
DOI: 10.1021/acssuschemeng.5b00678     Document Type: Article

References (21)

1. Gilbert, N. The disappearing nutrient. Nature 2009, 461, 716- 718.
2. Adam, C.; Peplinski, B.; Michaelis, M.; Kley, G.; Simon, F. G. Thermochemical treatment of sewage sludge ashes for phosphorus recovery. Waste Manage. 2009, 29 (3), 1122-1128.
3. Vogel, C.; Adam, A. Heavy metal removal from sewage sludge ash by thermochemical treatment with gaseous hydrochloric acid. Environ. Sci. Technol. 2011, 45 (17), 7445-7450.
4. Stemann, J.; Peplinski, B.; Adam, C. Thermochemical treatment of sewage sludge ash with sodium salt additives for phosphorus fertilizer production - Analysis of underlying chemical reactions. Waste Manage. 2015 (in press), DOI:10.1016/j.wasman.2015.07.029.
5. Hermann, L.; Adam, C.; Stemann, J. Production of citrate soluble phosphates by calcination of secondary phosphate sources with a sodium-sulfuric compound calcined phosphates. German Patent DE 10 2014 108 199.4.
6. Vogel, C.; Krüger, O.; Adam, C. Thermochemical Treatment of Sewage Sludge Ash with Sodium Additives under Reducing Conditions analyzed by Thermogravimetry. J. Therm. Anal. Calorim. 2015 (in press), DOI:10.1007/s10973-015-5016-z.
7. Herzel, H.; Krüger, O.; Hermann, L.; Adam, C. Sewage sludge ash - A promising secondary phosphorus source for fertilizer production. Sci. Total Environ. 2015 (in press), DOI:10.1016/j.scitotenv.2015.08.059.
8. Vogel, C.; Adam, C.; Kappen, P.; Schiller, T.; Lipiec, E.; McNaughton, D. Chemical state of chromium in sewage sludge ash based phosphorus-fertilizers. Chemosphere 2014, 103, 250-255.
9. Arcon, I.; Mirtic, B.; Kodre, A. Determination of valence states of chromium in calcium chromates by using x-ray absorption near-edge structure (XANES) spectroscopy. J. Am. Ceram. Soc. 1998, 81 (1), 222-224.
10. Takaoka, M.; Yamamoto, T.; Fujiwara, S.; Oshita, K.; Takeda, N.; Tanaka, T.; Uruga, T. Chemical states of trace elements in sewage sludge incineration ash by using x-ray absorption fine structure. Water Sci. Technol. 2008, 57 (3), 411-417.
11. Budnikoff, P. P.; Sysojeff, A. N. Beitrag zum Studium der Reduktion des Natriumsulfats mit Kohle. Z. anorg. Allg. Chem. 1928, 170 (1), 225-232.
12. Metallgesellschaft Aktiengesellschaft. Improved alkali-Alkaline earth fertilizer and process of producing same. British Patent 473, 520, 1937.
13. Cotte, M.; Susini, J.; Metrich, N.; Moscato, A.; Gratziu, C.; Bertagnini, A.; Pagano, M. Pagano Blackening of pompeian cinnabar paintings: X-ray microspectroscopy analysis. Anal. Chem. 2006, 78, 7484-7492.
14. Prietzel, J.; Thieme, J.; Herre, A.; Salom, M.; Eichert, D. Differentiation between adsorbed and precipitated sulphate in soils and at micro-sites of soil aggregates by sulphur K-edge XANES. Eur. J. Soil Sci. 2008, 59, 730-743.
15. Peplinski, B.; Adam, C.; Michaelis, M.; Kley, G.; Emmerling, F.; Simon, F.-G. Reaction sequences in the thermochemical treatment of sewage sludge ashes revealed by X-ray powder diffraction - A contribution to the European project SUSAN. Z. Kristallogr. Suppl. 2009, 2009, 459-464.
16. Prietzel, J.; Thieme, J.; Eusterhues, K.; Eichert, D. Iron speciation in soils and soil aggregates by synchrotron-based X-ray microspectroscopy (XANES, m-XANES). Eur. J. Soil Sci. 2007, 58, 1027-1041.
17. Piquer, C.; Laguna-Marco, M. A.; Roca, A. G.; Boada, R.; Guglieri, C.; Chaboy, J. Fe K-edge x-ray absorption spectroscopy study of nanosized nominal magnetite. J. Phys. Chem. C 2014, 118, 1332- 1346.
18. 3. J. Chem. Phys. 1981, 74, 215.
19. Schäfers, F.; Mertin, M.; Gorgoi, M. KMC-1: A High Resolution and High Flux Soft x-Ray Beamline at BESSY. Rev. Sci. Instrum. 2007, 78, 123102.
20. Ravel, B.; Newville, M. ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J. Synchrotron Radiat. 2005, 12, 537-541.
21. Burke, I. T.; Mayes, M. M.; Peacock, C. L.; Brown, A. P.; Jarvis, A. P.; Gruiz, K. Speciation of arsenic, chromium and vanadium in red mud samples from the Ajka spill site, Hungary. Environ. Sci. Technol. 2012, 46 (6), 3085-3092.