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Volumn 28, Issue 7, 1989, Pages 898-900

Dimethyldioxasilirane

Author keywords

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Indexed keywords


EID: 84990137043     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.198908981     Document Type: Article
Times cited : (42)

References (29)
  • 14
    • 84990129008 scopus 로고    scopus 로고
    • Irradiations were carried out by using high‐pressure mercury arc lamps in combination with cutoff filters (50% transmission at the wavelength specified) or interference filters (band maximum at the wavelength specified).
  • 18
    • 84990129414 scopus 로고    scopus 로고
    • −1. For experimental details see [2b, c].
  • 19
    • 84990153459 scopus 로고    scopus 로고
    • The relative amounts of 4 and 6 depend on the pyrolysis temperature: see [7].
  • 23
    • 84990107646 scopus 로고    scopus 로고
    • Carbonyl O‐oxides are extremely labile towards long‐wavelength irradiation (λ > 600 nm) [2], whereas A is stable even towards UV irradiation.
  • 24
    • 84990129435 scopus 로고    scopus 로고
    • HF/6‐31G(d) and MP2/6‐31G(d) calculations have been carried out for dioxasilirane and the dimethyl derivative 10. For the latter molecule, the IR spectrum was only calculated at the HF/6–31G(d) level owing to calculational limitations.
  • 25
    • 84990153483 scopus 로고    scopus 로고
    • −1.
  • 27
    • 84990083909 scopus 로고    scopus 로고
    • MP2/6‐31 G(d) energies for silanone O‐oxide, the transition state leading to dioxasilirane, and dioxasilirane are −440.07176, −440.06145, and −440.17340 hartree, respectively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.