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Angewandte Chemie International Edition in English
Volumn 28, Issue 9, 1989, Pages 1235-1237
Sequence Dependence of Template‐Directed Syntheses of Hexadeoxynucleotide Derivatives with 3′–5′ Pyrophosphate Linkage
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EID: 84990101462     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.198912351     Document Type: Article
Times cited : (70)
References (14)
  • 5
    • 84990154973 scopus 로고    scopus 로고
    • The use of an MTM protecting group instead of the previously used methyl group has, in addition to logistical advantages in the synthesis of trimers. the effect that the kinetic measurements can be carried out more exactly by HPLC. Thus, 1f reacts with the 5′‐hydroxy trimer 2a to give a hexamer. which differs from the template used, 3a, only in the protecting group at the 5′ end, but which can be separated chromatographically from 3a. This obviates the necessity of following the reaction by calculating differences between HPLC integrals.
  • 6
    • 84990154976 scopus 로고    scopus 로고
    • b in [1], and α and β in [3].

* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.