Interfacial degradation of planar lead halide perovskite solar cells

ACS Nano

Volumn 10, Issue 1, 2016, Pages 218-224

  Guerrero, Antonio ^a   You, Jingbi ^b   Aranda, Clara ^a   Kang, Yong Soo ^c   Garcia Belmonte, Germá ^a   Zhou, Huanping ^b   Bisquert, Juan ^d   Yang, Yang ^b  

^a UNIVERSITAT JAUME I   (Spain)

^b Engineering IV   (United States)

^c Hanyang University   (South Korea)

^d KING ABDULAZIZ UNIVERSITY   (Saudi Arabia)

Author keywords

Capacitance voltage; Impedance spectroscopy; Interfacial degradation; Perovskite photovoltaics

Indexed keywords

CAPACITANCE; CATHODES; DEGRADATION; ELECTRODES; ELECTROMAGNETIC WAVE ABSORPTION; LIGHT ABSORPTION; PEROVSKITE; PHOTODEGRADATION; SOLAR CELLS; SPECTROSCOPY; X RAY DIFFRACTION;

CAPACITANCE VOLTAGE; CHEMICAL DEGRADATION; DEGRADATION MECHANISM; FLAT BAND POTENTIAL; IMPEDANCE SPECTROSCOPY; INTERFACIAL DEGRADATION; PHOTOVOLTAICS; POWER CONVERSION EFFICIENCIES;

PEROVSKITE SOLAR CELLS;

EID: 84989866264     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/acsnano.5b03687     Document Type: Article

References (23)

1. Burschka, J.; Pellet, N.; Moon, S.-J.; Humphry-Baker, R.; Gao, P.; Nazeeruddin, M. K.; Gratzel, M. Sequential Deposition as a Route to High-performance Perovskite-sensitized Solar Cells. Nature 2013, 499, 316-319.
2. Lee, M. M.; Teuscher, J.; Miyasaka, T.; Murakami, T. N.; Snaith, H. J. Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites. Science 2012, 338, 643-647.
3. Zhou, H.; Chen, Q.; Li, G.; Luo, S.; Song, T.-b.; Duan, H.-S.; Hong, Z.; You, J.; Liu, Y.; Yang, Y. Interface Engineering of Highly Efficient Perovskite Solar Cells. Science 2014, 345, 542-546.
4. Green, M. A.; Emery, K.; Hishikawa, Y.; Warta, W.; Dunlop, E. D. Solar Cell Efficiency Tables (Version 45). Prog. Photovoltaics 2015, 23, 1-9.
5. Kim, J. H.; Williams, S. T.; Cho, N.; Chueh, C.-C.; Jen, A. K. Y. Enhanced Environmental Stability of Planar Heterojunction Perovskite Solar Cells Based on Blade-Coating. Adv. Energy Mater. 2015, 5, 1401229.
6. Hwang, K.; Jung, Y.-S.; Heo, Y.-J.; Scholes, F. H.; Watkins, S. E.; Subbiah, J.; Jones, D. J.; Kim, D.-Y.; Vak, D. Toward Large Scale Rollto-Roll Production of Fully Printed Perovskite Solar Cells. Adv. Mater. 2015, 27, 1241-1247.
7. Mei, A.; Li, X.; Liu, L.; Ku, Z.; Liu, T.; Rong, Y.; Xu, M.; Hu, M.; Chen, J.; et al. A Hole-conductor-free, Fully Printable Mesoscopic Perovskite Solar Cell with High Stability. Science 2014, 345, 295-298.
8. Chen, Q.; Zhou, H.; Hong, Z.; Luo, S.; Duan, H.-S.; Wang, H.-H.; Liu, Y.; Li, G.; Yang, Y. Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process. J. Am. Chem. Soc. 2014, 136, 622-625.
9. Frost, J. M.; Butler, K. T.; Brivio, F.; Hendon, C. H.; van Schilfgaarde, M.; Walsh, A. Atomistic Origins of High-Performance in Hybrid Halide Perovskite Solar Cells. Nano Lett. 2014, 14, 2584-2590.
10. Leijtens, T.; Eperon, G. E.; Pathak, S.; Abate, A.; Lee, M. M.; Snaith, H. J. Overcoming Ultraviolet Light Instability of Sensitized TiO2 with Meso-Superstructured Organometal Tri-halide Perovskite Solar Cells. Nat. Commun. 2013, 4, 2885.
11. Kaltenbrunner, M.; Adam, G.; Glowacki, E. D.; Drack, M.; Schwodiauer, R.; Leonat, L.; Apaydin, D. H.; Groiss, H.; Scharber, M. C. Flexible High Power-per-weight Perovskite Solar Cells with Chromium Oxide-Metal Contacts for Improved Stability in Air. Nat. Mater. 2015, 14, 1032-1039.
12. Guerrero, A.; Juarez-Perez, E. J.; Bisquert, J.; Mora-Sero, I.; Garcia-Belmonte, G. Electrical Field Profile and Doping in Planar Lead Halide Perovskite Solar Cells. Appl. Phys. Lett. 2014, 105, 133902.
13. You, J.; Yang, Y.; Hong, Z.; Song, T.-B.; Meng, L.; Liu, Y.; Jiang, C.; Zhou, H.; Chang, W.-H.; Li, G. Moisture Assisted Perovskite Film Growth for High Performance Solar Cells. Appl. Phys. Lett. 2014, 105, 183902.
14. Guerrero, A.; Chambon, S.; Hirsch, L.; Garcia-Belmonte, G. Light-Modulated TiOx Interlayer Dipole and Contact Activation in Organic Solar Cell Cathodes. Adv. Funct. Mater. 2014, 24, 6234-6240.
15. Guerrero, A.; Dörling, B.; Ripolles-Sanchis, T.; Aghamohammadi, M.; Barrena, E.; Campoy-Quiles, M.; Garcia-Belmonte, G. Interplay between Fullerene Surface Coverage and Contact Selectivity of Cathode Interfaces in Organic Solar Cells. ACS Nano 2013, 7, 4637-4646.
16. Boix, P. P.; Garcia-Belmonte, G.; Munecas, U.; Neophytou, M.; Waldauf, C.; Pacios, R. Determination of Gap Defect States in Organic Bulk Heterojunction Solar Cells from Capacitance Measurements. Appl. Phys. Lett. 2009, 95, 233302.
17. Bisquert, J.; Garcia-Belmonte, G.; Munar, A.; Sessolo, M.; Soriano, A.; Bolink, H. J. Band Unpinning and Photovoltaic Model for P3HT:PCBM Organic Bulk Heterojunctions Under Illumination. Chem. Phys. Lett. 2008, 465, 57-62.
18. Guerrero, A.; Marchesi, L. F.; Boix, P. P.; Ruiz-Raga, S.; Ripolles-Sanchis, T.; Garcia-Belmonte, G.; Bisquert, J. How the Charge-Neutrality Level of Interface States Controls Energy Level Alignment in Cathode Contacts of Organic Bulk-Heterojunction Solar Cells. ACS Nano 2012, 6, 3453-3460.
19. Xiao, Z.; Yuan, Y.; Shao, Y.; Wang, Q.; Dong, Q.; Bi, C.; Sharma, P.; Gruverman, A.; Huang, J. Giant Switchable Photovoltaic Effect in Organometal Trihalide Perovskite Devices. Nat. Mater. 2015, 14, 193-198.
20. Yang, T.-Y.; Gregori, G.; Pellet, N.; Grätzel, M.; Maier, J. The Significance of Ion Conduction in a Hybrid Organic-Inorganic Lead-Iodide-Based Perovskite Photosensitizer. Angew. Chem., Int. Ed. 2015, 54, 7905-7910.
21. Almora, O.; Zarazua, I.; Mas-Marza, E.; Mora-Sero, I.; Bisquert, J.; Garcia-Belmonte, G. Capacitive Dark Currents, Hysteresis, and Electrode Polarization in Lead Halide Perovskite Solar Cells. J. Phys. Chem. Lett. 2015, 6, 1645-1652.
22. Azpiroz, J. M.; Mosconi, E.; Bisquert, J.; De Angelis, F. Defects Migration in Methylammonium Lead Iodide and their Role in Perovskite Solar Cells Operation. Energy Environ. Sci. 2015, 8, 2118.
23. Verdingovas, V.; Müller, L.; Jellesen, M. S.; Grumsen, F. B.; Ambat, R. Effect of Iodine on the Corrosion of Au-Al Wire Bonds. Corros. Sci. 2015, 97, 161-171.