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Volumn 27, Issue 11, 1988, Pages 1547-1550

Cyclobis(paraquat‐p‐phenylene). A Tetracationic Multipurpose Receptor

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Indexed keywords


EID: 84989504610     PISSN: 05700833     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.198815471     Document Type: Article
Times cited : (481)

References (31)
  • 7
    • 0010364078 scopus 로고
    • 21,24] tetra‐conta‐1(28),2,4,7,9,12,14,16,18,21,23,26,29,31,33,35,37,39‐octadecaene. The syntheses of the constitutionally isomeric derivatives containing (a) two ortho‐,(b) two meta‐, and (c) one ortho‐ and one meta‐phenylene ring(s) have already been reported
    • (1983) Angew. Chem. , vol.95 , pp. 501
    • Geuder, W.1    Hünig, S.2    Suchy, A.3
  • 9
    • 46149138728 scopus 로고
    • Although these tetracations were characterized as their tetrabromides and tetrakis(hexafluorophosphates), there is no report in these publications of them forming inclusion complexes. However, after our communication had been submitted for publication, we received from Professor Hünig a copy of a communication
    • (1986) Tetrahedron , vol.42 , pp. 1665
  • 11
    • 84990082136 scopus 로고
    • in which the ability of a number of different tetracationic macrocycles (containing two paraquat units connected in a phane‐like manner by means of bridges incorporating different aromatic residues) to form inclusion complexes with a range of neutral guests is described
    • (1988) Angew. Chem. Int. Ed. Engl. , vol.27 , pp. 1553
  • 12
    • 84990095429 scopus 로고    scopus 로고
    • 2O.
  • 13
    • 84990108750 scopus 로고    scopus 로고
    • κα radiation (graphite monochromator). The structure was solved by direct methods and refined anisotropically. Further details of the crystal structure investigation can be obtained from the Cambridge Crystallographic Data Centre, University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW (England). Any request should be accompanied by the full literature citation for this communication.
  • 14
    • 84990124527 scopus 로고    scopus 로고
    • 2O molecule lies within the channels in two centrosymmetrically‐related partial occupancy sites.
  • 16
    • 0842341771 scopus 로고
    • to encompass the residual charges required for modeling electrostatic interactions, predict a gross conformation for 4 that is in close accord (cyclophane dimensions, 10.3 → 7.2 Å, cf. 10.3 → 6.8 Å) with that observed by X‐ray crystallography. Furthermore, these studies have demonstrated that there are two regions within the cyclophane that constitute favorable binding sites for MeCN molecules in accord, once again, with the X‐ray structural observations
    • (1985) J. Am. Chem. Soc. , vol.107 , pp. 3902
    • Dewar, M.J.S.1    Zoebisch, E.G.2    Healy, E.F.3    Stewart, J.J.P.4
  • 18
    • 84990093896 scopus 로고    scopus 로고
    • max = 484 nm and is orange in color.
  • 19
    • 84990093903 scopus 로고    scopus 로고
    • 6·3c, Δδ = −0.54 (H‐3/6), −0.25 (H‐4/5), −0.13 (OMe).
  • 20
    • 84990093901 scopus 로고    scopus 로고
    • 2), +0.04 (H‐α), −0.15 (H‐β)
  • 26
    • 0242340169 scopus 로고
    • „In-out”-isomere Großhohlräume und ihre unterschiedliche Gastselektivität
    • 2O/DCl containing either a large macrobicyclic hexamine incorporating two triphenylethane bridgeheads
    • (1985) Angewandte Chemie , vol.97 , pp. 224
    • Franke, J.1    Vögtle, F.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.